Preparation method of standard substance for soil environment detection
A technology of environmental testing and reference materials, which is applied in the field of preparation of soil reference materials, can solve the problems of not meeting the needs of soil environmental pollution investigation, not being able to fully respond to soil pollution, and few soil reference materials, so as to eliminate the matrix effect and be able to Strong design and uniform effect of standard substance
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Embodiment 1
[0017] A method for preparing a hexavalent chromium standard substance for soil environment detection, comprising the following steps:
[0018] Collect neutral or alkaline soil;
[0019] Air-dry the collected soil and pass through a 2mm sieve to remove impurities;
[0020] Weigh 60kg of ground soil and spread it on an enamel tray;
[0021] Take potassium dichromate and dissolve it in water to prepare a 1000mg / L hexavalent chromium solution;
[0022] Take 2.4L of the potassium permanganate solution prepared above, spray evenly into the soil contained in the enamel tray, and age for 1 week, stirring regularly during the aging process;
[0023] Put the obtained soil containing hexavalent chromium into an oven and dry it at 105°C for 24 hours;
[0024] The dried soil was ground to 100 mesh using a ball mill with polyurethane-lined zirconia spheres;
[0025] Pour the soil samples in all enamel trays into a double cone mixer and mix for 48 hours;
[0026] Take 10kg of product f...
Embodiment 2
[0031] A preparation method of a petroleum hydrocarbon standard substance of a soil matrix, comprising the following steps:
[0032] Collect uncontaminated soil;
[0033] Air-dry the collected soil and pass through a 2mm sieve to remove impurities;
[0034] Weigh 100kg of ground soil, divide it into 20 parts on average, and spread them on enamel trays respectively; weigh 200g of mineral oil, and dissolve it in 10L of n-hexane;
[0035] The prepared above-mentioned solution was evenly sprayed into the soil contained in the above-mentioned enamel tray in stages, aged in a fume hood for 1 week, and stirred regularly during the aging process;
[0036] The soil containing mineral oil obtained above was put into an oven and dried at 105° C. for 24 hours;
[0037] The dried soil was ground to 100 mesh using a ball mill with polyurethane-lined zirconia spheres;
[0038] Pour the soil samples in all enamel trays into a double cone mixer and mix for 48 hours;
[0039] Take 10kg of p...
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