Novel pigment based on light discoloration, and preparation method thereof
A photosensitive color change, a new type of technology, applied in the field of pigment production, can solve the problems of reduced product life, prone to mildew, etc., to achieve the effects of preventing flocculation, increasing ionization, and good fluorescence intensity
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Embodiment 1
[0025] A new type of pigment based on light-changing color, including the following raw materials in parts by weight: 80 parts of photochromic material; 15 parts of modified sodium oleate; 12 parts of wetting agent; 4 parts of defoaming agent; 6 parts of adhesive; retention aid 7 parts; 40 parts of deionized water.
[0026] Wherein the preparation method of modified sodium oleate is:
[0027] Put 25 parts by weight of sodium oleate into the reaction kettle, heat and stir until it melts, the heating temperature is 235°C, add 6 parts by weight of catalyst nickel, and continuously feed hydrogen chloride gas into it for 30 minutes, and react to obtain intermediate Body I, the reaction process is as follows:
[0028]
[0029] 25 parts by weight of intermediate I, 30 parts by weight of potassium phenylacrylate and 10 parts by weight of initiator propylformyl peroxide were mixed, heated to 50°C, and a grafting reaction occurred for 3 hours to obtain modified sodium oleate. The re...
Embodiment 2
[0040] A new type of pigment based on light-changing color, including the following raw materials in parts by weight: 100 parts of photochromic material; 20 parts of modified sodium oleate; 15 parts of wetting agent; 6 parts of defoaming agent; 8 parts of adhesive; retention aid 9 parts; 60 parts of deionized water.
[0041] Wherein the preparation method of modified sodium oleate is:
[0042] Put 25 parts by weight of sodium oleate into the reaction kettle, heat and stir until it melts, the heating temperature is 235°C, add 6 parts by weight of catalyst nickel, and continuously feed hydrogen chloride gas into it for 30 minutes, and react to obtain intermediate Body I;
[0043] Mix 25 parts by weight of intermediate I, 30 parts by weight of potassium phenylacrylate and 10 parts by weight of propylformyl peroxide, heat to 50°C, and undergo a grafting reaction for 3 hours to obtain modified sodium oleate.
[0044] Wherein, the preparation method of photochromic material is:
...
Embodiment 3
[0050] A new type of pigment based on light-changing color, including the following raw materials in parts by weight: 85 parts of photochromic material; 18 parts of modified sodium oleate; 13 parts of wetting agent; 5 parts of defoaming agent; 7 parts of adhesive; retention aid 8 parts; 45 parts of deionized water.
[0051] Wherein the preparation method of modified sodium oleate is:
[0052] Put 25 parts by weight of sodium oleate into the reaction kettle, heat and stir until it melts, the heating temperature is 235°C, add 6 parts by weight of catalyst nickel, and continuously feed hydrogen chloride gas into it for 30 minutes, and react to obtain intermediate Body I;
[0053] Mix 25 parts by weight of intermediate I, 30 parts by weight of potassium phenylacrylate and 10 parts by weight of propylformyl peroxide, heat to 50°C, and undergo a grafting reaction for 3 hours to obtain modified sodium oleate.
[0054] Wherein, the preparation method of photochromic material is:
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