Hydrogenated petroleum resin and rubber composition comprising same
A technology of hydrogenated petroleum resin and content, applied in transportation and packaging, optimization of rolling resistance, special tires, etc., can solve problems such as weak road adhesion, achieve low fuel consumption, excellent compatibility, and improve the overall physical properties
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Embodiment 1 to Embodiment 11
[0140] Embodiment 1 to Embodiment 11: Preparation of Petroleum Resin
Embodiment 1
[0142] In a 1 L autoclave, 27% by weight of dicyclopentadiene (DCPD, Kolon Industries Co., Ltd, purity 80.21%) was dissolved in toluene as a solvent to prepare a mixture, and 23% by weight of C 9 Distillate (20% by weight of styrene, 18% by weight of indene, 16% by weight of vinyltoluene and 5% by weight of α-methylstyrene), the reactor was connected to the autoclave, and then the reaction temperature was maintained at 279°C. Thermal polymerization was performed for 1 hour, and the reaction was terminated.
[0143] After the reaction was completed, the obtained product was put into a four-necked autoclave and left under vacuum at room temperature. The vacuum was maintained at 10 Torr and the product was heated to 260°C with stirring. On reaching 260°C, the concentration time was counted and held for 10 minutes. When the concentration was completed, the vacuum was released in the state to obtain molten petroleum resin.
[0144] 1.5 times the amount of toluene as a hydrogena...
Embodiment 2 to Embodiment 14
[0147] As described in Table 1 below, except that the contents of dicyclopentadiene, C9 fraction, and toluene were changed, and the reaction temperature during thermal polymerization and the reaction temperature during hydrogenation were changed, the same method as in Example 1 was used. Method for the preparation of partially hydrogenated petroleum resins.
[0148] [Table 1]
[0149]
[0150]
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