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Phenol-ammonia wastewater treatment device and process for degassing and grading treatment of light oil and heavy oil

A technology for wastewater treatment and grading treatment, which is applied in degassed water/sewage treatment, centrifugal separation water/sewage treatment, water treatment parameter control, etc. To achieve the effect of shortening processing time and saving floor space

Active Publication Date: 2022-05-13
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current conventional treatment methods for emulsified oil droplets and suspended particles in phenolic ammonia wastewater include chemical precipitation, biological flocculation, membrane filtration, etc., but these methods generally have problems such as high process and equipment costs, low efficiency, complicated operation, and difficult follow-up treatment.
[0003] Invention application CN110540329A discloses a method and system for treating phenolic ammonia wastewater, in which a traditional oil skimming tank is used to remove the oil phase and solid phase, and the gravity sedimentation method is used to carry out the sedimentation treatment, but the treatment time of this treatment method is long. and requires a larger processing space
The utility model CN204891292U discloses a light and heavy oil separator in phenol water, which mainly adopts natural sedimentation and heating and evaporation to realize the concentration of phenol water and the separation of light and heavy oil. The separation effect is not obvious and other defects

Method used

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  • Phenol-ammonia wastewater treatment device and process for degassing and grading treatment of light oil and heavy oil
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  • Phenol-ammonia wastewater treatment device and process for degassing and grading treatment of light oil and heavy oil

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Embodiment 1

[0040] The invention provides a kind of phenolic ammonia wastewater treatment device for degassing and classification treatment of light and heavy oil, such as figure 1 and figure 2 As shown, the phenol ammonia wastewater treatment plant includes an oil-gas-water three-phase separator 1, a centrifuge 2, a settling tank 3, a spray tank 4, a combined medium coalescer 5 and a combined fiber coalescer 6, wherein:

[0041] The oil-gas-water three-phase separator 1 is a horizontal separator for pre-separation of the oil phase, solid phase, gas phase and water phase in the phenol ammonia wastewater, and one end of the oil-gas-water three-phase separator 1 is provided with a phenol Ammonia wastewater inlet 1-1, light oil phase outlet 1-2 and gas phase outlet 1-3 are arranged on the top, solid phase outlet 1-4, heavy oil phase outlet 1-5 and water phase outlet 1-6 are arranged in sequence at the bottom; The inlet of the centrifuge 2 is connected with the heavy oil phase outlet 1-5 of...

Embodiment 2

[0079]Aiming at the problems of long process flow, long processing time, and substandard outlet water quality in the treatment of phenol ammonia wastewater in an existing chemical plant. The phenol ammonia waste water flow rate of described chemical plant is 300m 3 / h, the composition is complex, wherein the total phenol content is 6000mg / L, the ammonia nitrogen content is greater than 8000mg / L, and the oil content is 8500mg / L. The oil phase composition is complex, including light oil and heavy oil, and the suspended solid content is greater than 1000mg / L. The pH is 9 and contains a lot of dissolved gases.

[0080] The phenolic ammonia wastewater treatment process of degassing and light and heavy oil graded advanced treatment described in Example 1 is used to carry out deep and efficient treatment of the described phenolic ammonia wastewater, so that the oil content in the purified water after treatment is less than 300mg / L, and the suspended solids content is less than 100mg ...

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Abstract

The invention provides a phenol-ammonia wastewater treatment device and process for degassing and light and heavy oil staged treatment, the device comprises an oil-gas-water three-phase separator, a combined medium coalescer and a combined fiber coalescer, the oil-gas-water three-phase separator is internally provided with a rotational flow core tube module, a sedimentation module, a light oil collection module and a flow baffle in sequence; a liquid distributor, a liquid rectifier and an anisotropic medium coalescence filtering module are sequentially arranged in the combined medium coalescer from top to bottom; an inlet distributor, a primary enhanced coalescence module, an enhanced sedimentation module and a secondary enhanced coalescence module are sequentially arranged in the combined fiber coalescer. The degassing efficiency of the phenol-ammonia wastewater treated by the process is greater than 99%, the oil content in a water phase is lower than 200mg / L, the particle suspended matter content is lower than 40mg / L, the suspended solids with the particle size of more than 50mu m can be completely removed, and the device is small in occupied area and high in treatment precision, and can be widely applied to oil removal and clarification of oil / turbidity-containing production wastewater in industries such as petrochemical industry and coal chemical industry.

Description

technical field [0001] The invention belongs to the technical field of wastewater treatment in coal chemical industry and environmental protection, and in particular relates to a phenol ammonia wastewater treatment device and process for degassing and graded treatment of light and heavy oil. Background technique [0002] In the process of coal chemical production, a large amount of wastewater is usually produced, which is characterized by a large amount of water and complex water quality. According to the existing process, converting 1 ton of coal usually produces 0.8-1.1 ton of phenol ammonia wastewater. These wastewaters often contain a large amount of toxic and refractory phenolic compounds, oil, ammonia nitrogen and a large number of suspended particles. Since the oil contained in wastewater has great reuse value, and the existence of suspended particles will affect the advanced treatment of downstream phenolic ammonia wastewater, it is necessary to recover the emulsifi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/02C02F101/32C02F101/34C02F101/38C02F103/36
CPCC02F9/00C02F2101/345C02F2101/38C02F2103/365C02F1/38C02F1/40C02F2101/32C02F2209/10C02F2209/44C02F1/20
Inventor 杨强朱华曈卢浩李裕东
Owner EAST CHINA UNIV OF SCI & TECH
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