Coating composition
A technology of composition and paint, applied in the direction of coating, primer, etc.
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Embodiment 1
[0109] Preparation of GMA / acrylic resin
[0110] An epoxy functional acrylic adhesive formed from glycidyl methacrylate and styrene was synthesized. The polymerization was carried out in a 2 L, 4 neck reaction flask equipped with heating, cooling, thermocouple, reflux condenser stirring and cooling via motor driven steel stirring blades. A stream of nitrogen was applied to the reaction flask at a rate of 0.2 standard cubic feet (scft) per minute to provide an inert atmosphere. 27.41 parts by weight of A-100 and 0.2 parts by weight of Dowanol PM glycol ether (available from The Dow Chemical Company) were added to the reaction flask and heated to 158°C. Then 4.09 parts by weight of di-tert-amyl peroxide and 6.13 parts by weight of Dowanol PM glycol ether (available from The Dow Chemical Company) were added to the reaction flask over 180 minutes, followed by 55.21 parts over 150 minutes Parts by weight of styrene and 6.13 parts by weight of glycidyl methacrylate. The reaction ...
Embodiment 2-5
[0113] Example primer coating formulations according to the invention (Examples 2, 3, 4 and 5) and Comparative Examples 1 and 2 were prepared as shown in Table 1 below. All amounts are given in parts by weight. The coatings were prepared as typical two-component ("2K") compositions. The two premixed pigmented components (one containing the epoxy functional acrylic adhesive and the other a crosslinker) were mixed together with a pneumatic air mixer at medium speed to mix the container. Homogenize for 1-2 minutes.
[0114] Table 1
[0115]
[0116] 1 68.4% solids
[0117] 2 Ancamine 2569, 90% solids, available from Air Products and Chemicals, Inc.
[0118] 3 Ancamine 2432, 100% solids, available from Air Products and Chemicals, Inc.
[0119] 4 Ancamine K-54, 100% solids, available from Air Products and Chemicals, Inc.
[0120] 5 Epon 828 from Momentive Performance Materials Inc.
[0121] 6 Epon™ 8111 from Momentive Performance Materials Inc.
[0122] 7Magnesium...
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