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Method for granulating fine-grained titanium-rich material

A technology of titanium-rich materials and fine particles is applied in the field of titanium resource reuse, which can solve the problem that fine-particle titanium-rich materials cannot be directly applied, and achieve the effects of low drying cost, good product quality and low production cost.

Pending Publication Date: 2022-07-05
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In order to solve the difficult problem that the fine-grained titanium-rich material cannot be directly applied in the boiling chlorination furnace, the object of the present invention is to provide a method for granulating the fine-grained titanium-rich material, which has the advantages of low production cost, easy operation, The characteristics of high production efficiency and no impact on the quality of fluidized chlorination furnace and products can meet the requirements of fluidized chlorination process

Method used

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  • Method for granulating fine-grained titanium-rich material
  • Method for granulating fine-grained titanium-rich material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Weigh 20g of aluminum sulfate into 100g of water to prepare a binder solution for later use. Weigh 1000 g of fine-grained high-titanium slag (particle size less than 150 μm) and place it in a high-speed stirring granulator. The speed of the stirring paddle is 300 rpm, and the stirring time is 2 minutes. Stir well. The prepared binder solution is evenly sprayed into the material by the spray gun of the high-speed mixer for granulation treatment. The granulated product particles are placed in a fluidized bed dryer for drying, and the particle size distribution is between 150 and 1000 μm, accounting for 85%, the particle cold strength wear index is 5.67%, and the particle hot strength wear index is 2.80%.

[0033] The particle wear index experiment shows that the wear index of particle cold strength is 5.67%, which proves that the prepared particles have good cold strength and can meet the requirements of material transportation and furnace strength. After the heat treatm...

Embodiment 2

[0035]Weigh 30g of aluminum sulfate into 100g of water to prepare a binder solution for later use. Weigh 1000 g of fine-grained high-titanium slag (particle size less than 150 μm) and place it in a high-speed stirring granulator. The stirring paddle rotates at 300 rpm and the stirring time is 2 minutes. The prepared binder solution is uniformly sprayed into the material by the spray gun of the high-speed mixer for granulation treatment. The granulated product particles are placed in a fluidized bed dryer for drying, and the particle size distribution is between 150 and 1000 μm, accounting for 90%, the particle cold strength wear index is 4.36%, and the particle hot strength wear index is 1.76%.

[0036] The particle wear index experiment shows that the wear index of particle cold strength is 4.36%, which proves that the prepared particles have good cold strength and can meet the requirements of material transportation and furnace strength. After heat treatment, the wear index...

Embodiment 3

[0038] Weigh 20g of aluminum sulfate into 120g of water to prepare a binder solution for later use. Weigh 1000 g of fine-grained high-titanium slag (particle size less than 150 μm) and place it in a high-speed stirring granulator. The stirring paddle rotates at 300 rpm and the stirring time is 2 minutes. The prepared binder solution is uniformly sprayed into the material by the spray gun of the high-speed mixer for granulation treatment. The granulated product particles were placed in a fluidized bed dryer to dry, and the particle size distribution was between 150 and 1000 μm, accounting for 92%, the particle cold strength wear index was 4.98%, and the particle hot strength wear index was 2.13%.

[0039] The particle wear index experiment shows that the wear index of particle cold strength is 4.98%, which proves that the prepared particles have good cold strength and can meet the requirements of material transportation and furnace strength. After heat treatment, the wear inde...

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Abstract

The invention discloses a method for granulating a fine-grained titanium-rich material, which comprises the following steps: (1) weighing aluminum sulfate and water according to a set proportion, mixing the aluminum sulfate and the water, and stirring until the aluminum sulfate and the water are completely dissolved to prepare a binder solution; the addition amount of the aluminum sulfate is 0.5-6% of the mass of the fine-grain titanium-rich material; the addition amount of the water is 4-20% of the mass of the fine-grain titanium-rich material; (2) uniformly mixing the fine-grain titanium-rich material; and (3) uniformly spraying the prepared binder solution into the uniformly mixed fine-grain titanium-rich material through a built-in spray gun of a high-speed stirring granulator, so that the fine-grain titanium-rich material and the binder solution are fully mixed, and then drying to obtain a product. According to the invention, aluminum sulfate is used as a binder, and the granulated product particles have the characteristics of high cold strength, good thermal stability, high chlorination reactivity and the like. The problem that the fine-grain titanium-rich material is difficult to be applied to the boiling chlorination furnace to prepare titanium tetrachloride is solved, and the process has the characteristics of simplicity in operation, low cost and easiness in production.

Description

technical field [0001] The invention belongs to the technical field of reuse of titanium resources, and relates to a method for granulating and treating fine-grained titanium-rich materials, in particular to a method for granulating and treating fine-grained titanium-rich materials. Background technique [0002] At present, the products of the titanium industry mainly include titanium dioxide, titanium sponge and other titanium materials. Titanium dioxide is widely used in pigments, coatings, cosmetics and other fields because of its good dispersibility, high whiteness, high refractive index, and good covering properties. About 95% of the world's titanium resources are used to produce titanium dioxide. Titanium and titanium alloys prepared from sponge titanium have the characteristics of low density, high strength, non-magnetic, and strong corrosion resistance, which are widely used in aerospace, military, medical equipment and other fields. TiCl Prepared by Treatment of T...

Claims

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Application Information

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IPC IPC(8): C01G23/02B01J2/10
CPCC01G23/022B01J2/10Y02P10/20
Inventor 陈凤郭宇峰王帅杨凌志侯晓磊问悦凯李冬月郑宇
Owner CENT SOUTH UNIV