Compound salt of glycyrrhizin and kurarinol, its production and use
A technology of matrine and glycyrrhizic acid, applied in the direction of steroids, organic chemistry, etc., can solve the problems of insufficient clinical curative effect and therapeutic range
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Embodiment 1
[0023] Embodiment 1: Preparation of the compound salt of glycyrrhizic acid and matrine
[0024] In a 100ml reaction bottle, add 40ml of deionized water, add 2.00g (2.43mmol) of glycyrrhizinic acid and 0.686g (2.43mmol) of monohydromatrine under normal temperature and pressure, stir and dissolve, and wash the pump with water at 60°C to reduce the temperature. Concentrate under pressure (20mmHg) to a volume of 10ml, slowly add acetone dropwise under stirring, so that the precipitated white oily turbid precipitate dissolves, when the dropwise addition of acetone reaches 20ml, the precipitated white oily turbid precipitate no longer dissolves, suspend the dropwise addition of acetone, and stir until It takes about 30 minutes to 1 hour for the white oily precipitate to turn into a white solid crystal, continue to add acetone dropwise to 60ml within 30 minutes, stir in a water bath at 50°C for 1 hour, then naturally cool to room temperature and stir for 2 hours, filter, and wash with...
Embodiment 2
[0026] Example 2: Preparation of freeze-dried powder of glycyrrhizinate bimatrine compound salt
[0027] In a 100ml reaction bottle, add 2.00g (2.43mmol) of glycyrrhizic acid, 1.372g (4.86mmol) of monohydromatrine, add 30ml of deionized water, stir to dissolve, filter, and freeze-dry the filtrate to obtain 3.26g of freeze-dried powder. The yield is 99.3%.
Embodiment 3
[0028] Example 3: Preparation of freeze-dried powder of glycyrrhizic acid trimatrine compound salt
[0029] In a 100ml reaction bottle, add 2.00g (2.43mmol) of glycyrrhizinic acid, 2.06g (7.29mmol) of matrine monohydrate, add 30ml of deionized water, stir to dissolve, filter, and freeze-dry the filtrate to obtain 3.88g of freeze-dried powder. Yield 98.8%.
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