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Method for lowering melting point of fusible polyacrylonitrile resin through additive

A technology of polyacrylonitrile resin and additives, which is applied in the field of reducing the melting point of meltable polyacrylonitrile resin by adding solid additives, so as to achieve the effects of improving melt index, improving processing performance and improving flow performance

Inactive Publication Date: 2006-02-01
SINOPEC SHANGHAI PETROCHEMICAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The invention provides a method for reducing the melting point of meltable polyacrylonitrile resin with additives. The technical problem to be solved is to add a solid additive to the existing meltable polyacrylonitrile resin to make the meltable The processing melting point of the acrylonitrile resin is lowered to below 200°C, and the added additives will not have adverse effects on the melt processing of the polyacrylonitrile resin and the performance of the product.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Take the meltable polyacrylonitrile resin and additives and add them into a 2L open container equipped with a stirring device according to the required weight ratio, and stir for about 15 minutes until the additives and the resin are mixed evenly. If the additives are lumpy, first crush the additives into powder or fine particles, and the particle size should not exceed 200 mesh.

[0020] Fusible polyacrylonitrile resin is a copolymer of acrylonitrile and methyl methacrylate, based on the total amount of all polymerized units, the content of methyl methacrylate in the copolymer is 15wt%, and the viscosity-average molecular weight of the resin is 4000 , the melting point of the resin is 240°C, and the melt index measured at 240°C is 11g / 10 minutes.

Embodiment 2～8

[0022] The meltable polyacrylonitrile resin is a copolymer of acrylonitrile and acrylonitrile, the content of acrylonitrile in the copolymer is 14wt% based on the total amount of all polymerized units, and the viscosity-average molecular weight of the polyacrylonitrile resin is 3500. All the other are the same as embodiment 1

[0023] The specific additives used in each embodiment, the weight ratio of additives and polyacrylonitrile resin mixed, and the melting point and melt index of the mixture are listed in Table 1.

[0024] Further with the low-melting-point fusible polyacrylonitrile resin that embodiment 2~8 obtains as raw material, adopt the technology of melt spinning to carry out spinning, make the acrylic fiber of 1.46dtex, test the breaking strength and breaking elongation of fiber, its result sees Table 2.

[0025] Additives

[0026] Breaking strength

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Abstract

A process for lowering the fusion point of fusible polyacrylonitrile resin to lower than 200 deg.C features that the fusible polyacrylonitrile resin particles are proportionally and mechanically mixed with the solid additive chosen from salioylic acid, thiourea peroxide and their mixture.

Description

technical field [0001] The invention relates to a method for lowering the melting point of meltable polyacrylonitrile resin, in particular to a method for lowering the melting point of meltable polyacrylonitrile resin by adding solid additives. Background technique [0002] Polyacrylonitrile resin is a high polymer with a wide range of uses, especially the performance of fibers made of polypropylene resin is similar to that of wool, and it occupies a large proportion in the total production of synthetic fibers. However, a defect of polyacrylonitrile resin is that the melting point (theoretical value is 319°C) is higher than the decomposition temperature (generally 250°C), so it cannot be processed by melting, and polyacrylonitrile fibers can usually only be processed by solution spinning. This spinning method uses a large amount of toxic, harmful or corrosive solvents. During the production process, the solvent must be recovered and purified, and the fibers must be washed an...

Claims

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Application Information

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IPC IPC(8): C08L33/20C08K5/09C08K5/405
Inventor 李荣安季春晓杜欣庄王雁周涛
Owner SINOPEC SHANGHAI PETROCHEMICAL CO LTD