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Elastomer silicone vulcanizates

An elastomer, static vulcanization technology, applied in the field of elastomer composition, can solve problems such as incompatibility and difficulty in obtaining a homogeneous mixture

Inactive Publication Date: 2007-06-06
DOW CORNING CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Difficulty obtaining a stable homogeneous mixture due to the incompatibility of elastomers with these silicone-based polymers

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] GP-50 (60 g) and Luperox F (0.2 g) were mixed on an open mill to form a silicone compound. The silicone compound (60.2 g) and EPDM (140 g) were added to a 379 ml Haake internal mixer equipped with a Banbury rotor at 150°C and 100 rpm. After about 2.5 minutes and before the torque was increased, the material was removed and placed in the press at 177°C for 10 minutes. Divide the elastomer composition into parts. 1A was further compounded as is. 1B was heat aged at 16hr / 90°C before compounding. The resulting EPDM elastomer composition (50 g) was compounded with Varox (3 g) and N990 (8 g), AustinBlack (4 g) and ZnO (2 g) on ​​an open mill and the components were mixed until homogeneous.

Embodiment 2

[0060]GP-50 (60 g) and EPDM (140 g) were added without compounding to a 379 ml Haake internal mixer equipped with a Banbury rotor at 150°C and 100 rpm. After about 2.5 minutes, the elastomer blend was removed. The elastomer blend was divided into parts. 2A was further compounded as it is. 2B was heat aged at 16hr / 90°C before compounding. The resulting elastomer blend (50 g) was compounded with Luperox F (0.05 g), Varox (3 g) and N990 (8 g), Austin Black (4 g) and ZnO (2 g) on ​​an open mill to obtain the 1 of the same final ingredients, and mix the components until homogeneous.

[0061] Examples 1-2 were pressure cured at 177°C for 20 minutes. The physical properties of the resulting cured elastomeric compositions and blends are summarized in Table 1.

Examples#

Embodiment 3

[0063] For Example 3A, Silicone Compound A (142 g) and G902 (344 g) were added to a 310 ml Haake internal mixer equipped with Banbury rollers at 90°C and 125 rpm (rev / min). middle. When 130°C was reached and before torque was increased, the blend was removed and then placed in a 200°C press for 10 minutes to form a FKM elastomeric composition with an ML(1+10) of 43 at 121°C. Sample 3B is the same as Sample 3A except that for Sample 3B the blend was brought to 160°C and reacted, then removed 5 minutes after the torque was increased to give a ML(1+10) of 67 at 121°C FKM elastomer composition. The resulting FKM elastomer composition (100 parts) was then compounded with ZnO (3.44 parts), Varox (2.06 parts) and TAIC (2.75 parts) on a Haake mill until homogeneous. The samples were pressure cured at 160°C for 10 minutes and then post-cured at 200°C for 4 hours. Sample 3A has a Shore A durometer hardness of 60, a tensile strength of 7.39MPa, an elongation of 320%, and a permeabilit...

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Abstract

A method is disclosed for preparing an elastomeric composition comprising: (I) mixing; (A) an elastomer, (B) an optional compatibilizer, (C) an optional catalyst, (D) a silicone base comprising a curable organopolysiloxane, (E) an optional crosslinking agent, (F) a cure agent in an amount sufficient to cure said organopolysiloxane; and then, (II) statically vulcanizing the organopolysiloxane, wherein the weight ratio of elastomer (A) to silicone base (D) in the elastomeric composition ranges from 95:5 to 30:70. The elastomer compositions obtained by the present method and cured elastomeric compositions prepared therefrom have good low and high temperature properties.

Description

[0001] Cross References to Related Applications [0001] This application claims priority to US Patent Application No. 60 / 584,306, filed June 30,2004. field of invention [0002] The present invention relates to a process for the preparation of elastomeric compositions comprising polysiloxanes and other elastomers based on the static vulcanization of polysiloxanes. The invention further relates to the products prepared by this method, and the cured elastomeric compositions obtained therefrom. Background of the invention [0003] Silicone rubber is characterized by good high and low temperature properties, weather resistance and processing characteristics. There remains a need to modify other elastomers in an efficient manner to improve their performance at extreme temperatures. In particular, there remains a need to provide elastomeric compositions for use in various applications requiring high and or low temperature properties. There remains a need to modify elastomers i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L27/12
CPCC08G77/70C08L27/12C08L27/16C08G77/14C08L23/16C08G77/26C08G77/28C08G77/20C08L83/04C08L83/00C08L2666/14C08L2666/04C08L21/00
Inventor I·乔尔瓦特L·M·汤奇
Owner DOW CORNING CORP