Insecticide mixture containing pyrazol compounds

Abstract

Insecticide mixture comprising the following as an active compound: 1) 1-[(1RS)-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazine-4-yl-1H-pyrazol-4-carboxamide and 2) At least one additional compound B selected from the following: B.1) a succinate dehydrogenase inhibitor as defined in the specification; B.2) an inhibitor of oxysterol-binding protein as defined in the specification; B.3) an inhibitor of complex III at the Qi site selected from the following: a) florylpicoxamide, and b) fenpicoxamide; B.4) strobilurin as defined in the specification; B.5) an inhibitor of C14-demethylase in sterol biosynthesis as defined in the specification; B.6) an inhibitor of cell division and cytoskeleton as defined in the specification; B.7) other compounds of unknown mode of action as defined in the specification; and B.8) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl]methyl]cyclopropanecarboxamide; wherein component 1) and component 2) are present in a weight ratio of 1000:1 to 1:1000; a method for combating invertebrate pests, such as insects, spiders, nematodes and / or harmful fungi in and on plants, and for protecting such plants invaded by pests and / or harmful fungi, and the use of this mixture.

Description

Technology Field

[0001] The present invention relates to a synergistic insecticidal mixture comprising a pyrazol compound as an active compound and at least one fungicide or insecticide.

[0002] The present invention therefore relates to an insecticidal mixture comprising the following as an active compound:

[0003] 1) 1-[(1 of Equation I RS )-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazine-4-yl-1H-pyrazol-4-carboxamide (common name dimpropyridaz):

[0004]

[0005] and

[0006] 2) At least one additional compound B selected from the following:

[0007] B.1) Succinate dehydrogenase inhibitors selected from the following: a) pidiflumetophen, b) pyraziflumide, c) inpirfloxam, d) pyrapropone, e) fluindapyr, f) isoflushipram, g) 2-(difluoromethyl)-N-(1,1,3-trimethylindane-4-yl)pyridine-3-carboxamide, h) 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindane-4-yl]pyridine-3-carboxamide, i) 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethylindane-4-yl)pyridine-3-carboxamide, j) 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indane-4-yl]pyridine-3-carboxamide, k) 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indane-4-yl)pyridine-3-carboxamide, l) 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indane-4-yl]-pyridine-3-carboxamide, m) 2-(difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indane-4-yl)pyridine-3-carboxamide, n) 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indane-4-yl]pyridine-3-carboxamide, o) N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-5-fluoro-1-methyl-pyrazole-4-carboxamide, and p)methyl(E)-2-[2-[(5-cyano-2-methyl-phenoxy)methyl]phenyl]-3-methoxy-prop-2-enoate;

[0008] B.2) Inhibitors of oxysterol-binding proteins selected from the following: a) oxathiapiproline, b) 2-{3-[2-(1-{[3,5-bis(difluoromethyl-1H-pyrazole-1-yl]acetyl}piperidin-4-yl)-1,3-thiazole-4-yl]-4,5-dihydro-1,2-oxazole-5-yl}phenylmethanesulfonate, c) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazole-1-yl]acetyl}piperidin-4-yl)-1,3-thiazole-4-yl]-4,5-dihydro-1,2-oxazole-5-yl}-3-chlorophenylmethanesulfonate, d) 4-[1-[2-[3-(difluoromethyl)-5-methyl-pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, e) 4-[1-[2-[3,5-bis(difluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, f) 4-[1-[2-[3-(difluoromethyl)-5-(trifluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, g) 4-[1-[2-[5-cyclopropyl-3-(difluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, h) 4-[1-[2-[5-methyl-3-(trifluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, i) 4-[1-[2-[5-(difluoromethyl)-3-(trifluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, j) 4-[1-[2-[3,5-bis(trifluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide, and k) 4-[1-[2-[5-cyclopropyl-3-(trifluoromethyl)pyrazole-1-yl]acetyl]-4-piperidyl]-N-tetraline-1-yl-pyridine-2-carboxamide,

[0009] B.3) Inhibitors of Complex III at the Qi site selected from the following: a) florylpicoxamide, and b) fenpicoxamide;

[0010] B.4) Strobilurin selected from the following (inhibitor of Complex III, Qo site): a) (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazole-3-yl]-oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide, b) (Z,2E)-5-[1-(4-chlorophenyl)pyrazole-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide, and c) 2-(ortho-((2,5-dimethylphenyl-oxymethylene)phenyl)-3-methoxy-acrylic acid methyl ester;

[0011] B.5) Inhibitors of C14-demethylase in sterol biosynthesis selected from the following (DMI fungicides): a) 2-(2,4-difluorophenyl)-1,1-difluoro-3-(tetrazole-1-yl)-1-[5-[4-(2,2,2-trifluoroethoxy)phenyl]-2-pyridyl]propan-2-ol, b) 2-(2,4-difluorophenyl)-1,1-difluoro-3-(tetrazole-1-yl)-1-[5-[4-(trifluoromethoxy)phenyl]-2-pyridyl]propan-2-ol, c) 2-(chloromethyl)-2-methyl-5-(p-tolylmethyl)-1-(1,2,4-triazole-1-ylmethyl)cyclopentanol, d) 4-[[6-[2-(2,4-difluoro-phenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazole-1-yl)propyl]-3-pyridyl]oxy]benzonitrile;

[0012] B.6) Inhibitors of cell division and cytoskeleton selected from the following: a) pyridaclomethyl, b) N-ethyl-2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]butanamide, c) N-ethyl-2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-2-methylsulfanyl-acetaamide, d) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-(2-fluoroethyl)butanamide, e) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-(2-fluoroethyl)-2-methoxy-acetaamide, f) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-propyl-butanamide, g) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-2-methoxy-N-propyl-acetamid, h) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-2-methylsulfanyl-N-propyl-acetamid, i) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-(2-fluoroethyl)-2-methylsulfanyl-acetamid, j) 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol-3-amine,

[0013] B.7) Other compounds of unknown mode of action selected from the following: a) diclocimet, b) fenitrophane, c) harpine, d) picarbutrazox, e) dicloventiazox, f) pyrifenamine, g) quinofumelin, h) ipflufenoquine, i) 4-cyclopropyl-N-(2,4-dimethoxyphenyl)thiadiazole-5-carboxamide, j) N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazole-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, k) N'-(5-bromo-6-indane-2-yloxy-2-methyl-3-pyridyl)-N-ethyl-N-methyl-formamidine, l) N'-[5-bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methyl-3-pyridyl]-N-ethyl-N-methyl-formamidine, m) N'-[5-bromo-6-(4-isopropylcyclohexoxy)-2-methyl-3-pyridyl]-N-ethyl-N-methyl-formamidine, n) N'-[5-bromo-2-methyl-6-(1-phenylethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine, o) ethyl (Z)-3-amino-2-cyano-3-phenyl-prop-2-enoate, p) pentyl N-[6-[[(Z)-[(1-methyltetrazole-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate, q) but-3-inyl N-[6-[[(Z)-[(1-methyl-tetrazole-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate (picarbutrazox), r) 2-(6-benzyl-2-pyridyl)quinazolin, s) 2-[6-(3-fluoro-4-methoxy-phenyl)-5-methyl-2-pyridyl]quinazolin, t) N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine, and

[0014] B.8) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidine-1-yl]phenyl]methyl]cyclopropanecarboxamide;

[0015] Here, component 1) and component 2) are present in a weight ratio of 1000:1 to 1:1000. Background Technology

[0016] One typical problem in the field of pest control is the need to allow for effective pest control while reducing the dosage of the active ingredient to mitigate or avoid adverse environmental or toxicological effects. Another problem encountered relates to the need for available pest control agents that are effective against a wide range of pests or crop diseases.

[0017] Another difficulty associated with the use of insecticides is that the repeated, exclusive application of individual insecticidal compounds often leads to the rapid selection of pests and harmful fungi that have developed natural or adapted resistance against the active compound in question. Therefore, there is a need for pest control agents that help prevent or overcome resistance.

[0018] The compound of Formula I is known from WO 2012 / 143317. It is stated that this compound is useful for combating invertebrate pests.

[0019] Therefore, the objective of the present invention is to provide an insecticidal mixture for resistance management, for example, reducing the dosage rate, improving the active range, combining knockdown activity with extended control, or solving at least one of the discussed problems.

[0020] It was found that at least one of these tasks is achieved by a combination of active compounds defined at the start.

[0021] Furthermore, it has also been found that the simultaneous application of dimpropyridas and one or more active compounds B, either jointly or separately, or the sequential application of dimpropyridas and one or more active compounds B, allows for improved control of pests and / or harmful fungi compared to the control rates possible with the individual compounds.

[0022] Furthermore, the present invention relates to the following.

[0023] - An agrochemical composition comprising an insecticidal mixture as defined herein and at least one inert liquid and / or solid acceptable carrier;

[0024] - A method for controlling or eradicating invertebrate pests, comprising contacting said pest or its food source, habitat, or breeding ground with an insecticidal amount of an insecticidal mixture as defined herein;

[0025] - Use of insecticidal mixtures as defined herein for protecting growing plants or plant propagation materials from attack or infestation by invertebrate pests;

[0026] - A method for controlling plant pathogenic harmful fungi, wherein the fungi, their habitats, or plants, soil, or seeds to be protected against fungal attack are treated with an effective amount of an insecticidal mixture comprising dimpropyridase and at least one specific compound B; and

[0027] - A method for protecting plants from plant pathogenic harmful fungi, wherein the fungi, their habitats, or plants, soil, or seeds to be protected against fungal attack are treated with an effective amount of an insecticidal mixture comprising dimpropyridase and at least one specific compound B. Specific details for implementing the invention

[0028] The mixture of the present invention may be a physical mixture of dimpropyridase and at least one compound B. Accordingly, the present invention also provides a mixture comprising dimpropyridase and at least one compound B. However, the composition may also be any combination of dimpropyridase and at least one compound B, and it is not required that compounds A and B be present together in the same formulation.

[0029] The term “invertebrate pests” (also referred to as animal pests) as used herein encompasses a group of animals, such as insects, spiders, and nematodes, that attack plants and cause substantial damage to the attacked plants.

[0030] The terms “compound(s) according to the present invention,” or “compound of Formula I,” or “pyrazol compound A” include dimpropyridase as defined herein, as well as its stereoisomers, salts, tautomers, or N-oxides.

[0031] Dimpropyridase has a single chiral center; it exists as a mixture of enantiomers. The present invention provides both the pure enantiomer or diastereomer and mixtures thereof, and the pure enantiomer of dimpropyridase or mixtures thereof, and uses according to the present invention.

[0032] Additional commercially available compound B is among other literatures The Pesticide Manual, 17th Edition, British Crop Protection Council (2015), and its online database https: / / www.bcpc.org / product / bcpc-online-살충제-manual-latest-versionIt can be found in. Each of compounds B1 to B8 and their fungicidal or insecticidal actions are CN 1456054, WO2017008583, CN 1907024, WO2015197530, WO2016097003, WO2016139189, WO2016096944, WO2016096849, WO2017220491, WO2018046431, WO2016109257, WO2016122802, WO 2016187201, WO2018098216, WO2018098243, WO2018098245, WO 2014 / 60177, WO2013116251, WO 2015036379, It is known from WO13127704, WO2015 / 65922, WO 2011 / 80044, WO2012 / 146125, WO 2009115557, WO2012045798, WO2012 / 69652, EP2865265, and WO2016 / 180802, respectively.

[0033] The inventors have discovered that the joint or separate simultaneous application of dimpropyridas and at least one compound B, or the continuous application of dimpropyridas and at least one compound B, allows for better control of animal pests and / or harmful fungi than is possible with the individual compounds alone (synergistic mixtures).

[0034] Dimpropyridase can be used as a synergist for different fungicidal active compounds. By the simultaneous application of dimpropyridase and at least one active compound B1 to B7, either jointly or separately, fungicidal activity is increased in an additive manner. By the simultaneous application of dimpropyridase and compound B8, either jointly or separately, insecticidal activity is increased in an additive manner.

[0035] The references provided below regarding preferred embodiments of the variables are also valid with respect to dimpropyridas, where applicable, as well as with the uses and methods according to the present invention and mixtures of the present invention, not only by themselves but preferably in combination with one another.

[0036] A particular embodiment of the present invention is any one of insecticidal mixtures A, B, C, D, E, F, G, and H:

[0037] Insecticide mixture A contains the following as an active ingredient:

[0038] A1) Dimpropiridaz, and

[0039] A2) A succinate dehydrogenase inhibitor selected from group B.2 as defined in the beginning;

[0040] Here, components A1) and A2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0041] Preferred mixture A is a combination of dimpropyridase of the mixture ratio mentioned above and compound B selected from the following: pidiflumethofen, inpirfloxam, pyrapropone, isoflushipram, 2-(difluoromethyl)-N-(1,1,3-trimethyl-indane-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindane-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indane-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indane-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indane-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indane-4-yl]-pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indane-4-yl)pyridine-3-carboxamide, and 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indane-4-yl]pyridine-3-carboxamide.

[0042] In another embodiment, a preferred mixture A is a combination of dimpropyridase of the mixture ratio as mentioned above and a compound B selected from the following: A2 a) to A2 n) as defined at the beginning.

[0043] Insecticide mixture B contains the following as an active ingredient:

[0044] B1) Dimpropiridase, and

[0045] B2) Inhibitor of an oxysterol-binding protein selected from group B.2 as defined in the beginning;

[0046] Here, components B1) and B2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0047] A preferred mixture B is a combination of dimpropyridase of the mixture ratio mentioned above and compound B selected from the following: oxathiapiproline, and 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1 H -pyrazol-1-yl]-acetyl}piperidine-4-yl)-1,3-thiazole-4-yl]-4,5-dihydro-1,2-oxazole-5-yl}-3-chlorophenyl methane-sulfonate.

[0048] In another embodiment, a preferred mixture B is a combination of dimpropyridase in the mixture ratio as mentioned above and compound B selected from below: B.2 a) to B.2 c) as defined in the introductory section. In another embodiment, a preferred mixture E is a combination of dimpropyridase in the mixture ratio as mentioned above and compound B selected from below: B2 d), B2 h), and B2 t) as defined in the introductory section.

[0049] Insecticide mixture C contains the following as an active ingredient:

[0050] C1) Dimpropiridase, and

[0051] C2) a) floryl pecoxamide, or b) fenpecoxamide;

[0052] Here, components C1) and C2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0053] A preferred mixture C is a combination of dimpropyridase and florylpicoxamide in the mixture ratio as mentioned above.

[0054] Insecticide mixture D contains the following as an active ingredient:

[0055] D1) Dimpropiridase, and

[0056] D2) Strobilurin selected from group B.4 as defined in the beginning;

[0057] Here, components D1) and D2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0058] A preferred mixture D is a combination of dimpropyridase in the mixture ratio mentioned above and compound B selected from the following: (Z ,2 E )-5-[1-(2,4-dichloro-phenyl)pyrazol-3-yl]-oxy-2-methoxyimino- N ,3-dimethyl-pent-3-enamide, and ( Z ,2 E )-5-[1-(4-chlorophenyl)pyrazole-3-yl]oxy-2-methoxyimino- N ,3-dimethyl-pent-3-enamide.

[0059] Insecticide mixture E contains the following as an active ingredient:

[0060] E1) Dimpropiridase, and

[0061] E2) A DMI fungicide selected from Group B.5 as defined in the beginning;

[0062] Here, components E1) and E2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0063] A preferred mixture E is a combination of dimpropyridase and 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazole-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, as described above.

[0064] Insecticide mixture F contains the following as an active ingredient:

[0065] F1) Dimpropiridas, and

[0066] F2) Inhibitors of cell division and cytoskeleton selected from group B.6 as defined in the intro;

[0067] Here, components F1) and F2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0068] The preferred mixture F is a combination of dimpropyridase and pyridaclomethyl in the mixture ratio as mentioned above.

[0069] Insecticide mixture G contains the following as an active ingredient:

[0070] G1) Dimpropiridase, and

[0071] G2) Other compounds of unknown mode of action selected from Group B.6 as defined in the beginning;

[0072] Here, components G1) and G2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0073] A preferred mixture G is a combination of dimpropyridase of the mixture ratio mentioned above and compound B selected from the following: picarbutrazox, quinofumelin, ipflufenoquine, and N' -(2,5-dimethyl-4-phenoxy-phenyl)- N -ethyl- N -Methyl-formamidine.

[0074] Insecticide mixture H contains the following as an active ingredient:

[0075] H1) Dimpropyridase, and

[0076] H2) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidine-1-yl]phenyl]methyl]cyclopropanecarboxamide;

[0077] Here, components H1) and H2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, particularly 20:1 to 1:20. In the aforementioned ratios, one embodiment relates to a ratio of 1:1 to an excess amount of dimpropyridase; in another embodiment, the ratio is 1:1 to an excess amount of compound B.

[0078] A binary mixture of dimpropyridase and compound B is one preferred embodiment of the present invention.

[0079] The mixture of the present invention is particularly suitable for controlling Lepidoptera, Coleoptera, Diptera, Thysanoptera, and Hemiptera.

[0080] In particular, the mixture of the present invention is useful for controlling thrips and hemiptera, especially hemiptera.

[0081] In a preferred embodiment, the present invention relates to insecticidal mixtures A to H that are particularly suitable for controlling pests of the Pentatomidae and / or Cicadellidae and / or Aleyrodidae and / or Aphididae, which are typical pests of soybean plants.

[0082] In one preferred embodiment, the present invention relates to a use or method comprising the application of an insecticidal mixture as defined above, wherein the pest is a green stink bug (Accordionum hilare ( Acrosternum cheerful )), brown marmorated stink bug (haliomorpha halis ( Halyomorpha halys )), Red-banded Stench Bug (Piezodorus guildinii ( Piezodorus guildinii )), Neotropic Brown Stink Bug (Ushstein Heros ( Euschistus the hero )), Brown Stench Bug (Yushistus Servus ( Euschistus, servant )), Kuzburg (Megacopter Crivralia ( Megacopta sieve )), Red Shoulder Stench Bug (Tianta Custator ( Thyantas guardian )) and Dusky-Brown Stink Bug (Uschistus tristigmus ( Euschistus tristigmus )), Southern Green Stink Bug (Nezara Viridula ( Green-leaved nezara It is selected from a group consisting of ), and combinations thereof.

[0083] In one embodiment, the stink bug targets are Nezara viridula, Piezodorus species, Acrosternum species, Euchistus, and especially Euchistus herous ( Euchistus the hero ) is a desirable target. More preferably, the insecticidal mixture is the green stink bug (Acrosternum hilare ( Acrosternum cheerful )), brown marmorated stink bug (haliomorpha halis ( Halyomorpha halys )), Red-banded Stench Bug (Piezodorus guildinii ( Piezodorus guildinii )), Neotropic Brown Stink Bug (Ushstein Heros ( Euschistus the hero )), Brown Stench Bug (Yushistus Servus ( Euschistus, servant )), and Kuzburg (Megacopter Crivralia ( Megacopta sieve )), Red Shoulder Stench Bug (Tianta Custator ( The guardian of Thyantas )), Dusky-Brown Stench Bug (Ushstein's Tristigmus ( Euschistus tristigmus )), and Southern Green Stink Bug (Nezara Biridula ( Green-leaved nezara It is used to control the family Pentomidae, including )).

[0084] Insecticide mixtures A to H are preferably stink bugs, for example, Nesara species (e.g., Nesara viridula) Green-leaved nezara ), Nezara Antennata ( Nezara antennata ), Nezara Hilaris ( Nezara is cheerful. )), Piezodorus species (e.g., Piezodorus gildiniii ( Piezodorus guildinii )), Acrostornum species (e.g., Acrostornum Hilare ( Acrosternum cheerful )), Eusistus species (e.g. Eusistus Heros ( Euchistus the hero ), Eusistus Servus ( Euschistus, servant )), Haliomorpha Halis ( Halyomorpha halys ), Megakovta Krivaria ( Megacopta sieve ), Plautia crosota ( Plautia crossota), Riptortus Clavatus ( The nailed riptortus ), Ropalus maculatus ( Rhopalus muscled ), Antestiopsis orbitalus ( Antestiopsis orbitalus ), Dectes Texanus ( Texas hawk ), Dichelops species (e.g., Dichelops furcatus ( Dichelops furcatus ), Dicellops melacanthus ( Dichelops melacanthus )), Eurygaster species (e.g., Eurygaster intergrisepsis ( Eurygaster intergriceps ), Yurigaster Maurd ( Eurygaster maurd )), Oebalus species (e.g., Oebalus mexicana ( Mexican Oebalus ), Oevalus poesillus ( Oebalus poecilus ), Oevalus pugnaze ( Oebalus is fighting. )), Scotinophara species (e.g., Scotinophara lurida ( Scotinophara lurida ), Scotinopara Coarchtata ( Scotinophara coarctata To control )) it is used on the Faboideae, especially soybeans.

[0085] Desirable targets include Acrosternum hilare ( Acrosternum cheerful ), Antestipsis orbitalus ( Antestiopsis orbitalus ), Dichelops furcatus ( Dichelops furcatus ), Dichelops melacanthus ( Dichelops melacanthus ), Euclitus Heros ( Euchistus the hero ), Euclitus Servus ( Euschistus, servant ), Megakovta Krivaria ( Megacopta sieve ), Nejara Biridullah ( Green-leaved nezara ), Nezara Hilare ( Nezara cheerful ), Piezodorus gildini ( Piezodorus guildinii ), Haliomorpha Halis ( Halyomorpha halys ) is included.

[0086] Additional Pentomidae pests that can be controlled according to the present invention are Eysarcoris, particularly Eysarcoris aeneus (Eysarcoris aureus ) am.

[0087] The mixture is preferably flour, for example, sweet potato flour (Bemisia Tabashi ( Bemisia tabaci It is used on legumes, especially soybeans, to control ))

[0088] The mixture is preferably aphids, for example, soybean aphids (apis glycine ( Wisteria aphids It is used on legumes, especially soybeans, to control ))

[0089] The mixture is preferably a cicada, for example, a potato cicada (empoascari ( Bean sprouts It is used on legumes, especially soybeans, to control ))

[0090] The mixture is preferably made of leafhoppers, for example, Lorito verde (small green pakeet) (Empoasca crameri ( Empoasca kraemeri It is used on legumes, especially soybeans, to control ))

[0091] Insecticide mixtures A to H are preferably Lepidopterans (Lepidoptera), e.g., Spodoptera prugiferda ( Spodoptera frugiperda ), Spodoptera Litoralis ( Spodoptera littoralis ), Spodoterra Ritura ( Spodoptera litura ); Protoptera (Coleoptera), for example Antonomus grandis ( Anthonomus grandis ), Antonomus formorum ( Anthonomus pomorum ), and atractylodes (Thrips (Thysanoptera)), e.g. Skirtotrips sitri ( Citrus Scirtothrips It is used to control ).

[0092] Each of the mixtures and compositions of the present invention is particularly suitable for the control of the following plant diseases:

[0093] Ornamental plants, vegetables (e.g., A. candida ( A. candida)) and sunflowers (e.g., A. tragopogonis ( A. tragopogonis )) regarding Albugo spp. (Albugo spp.) (white rust); vegetables (e.g., A. Dowsy ( A. dauci ) or A. Poly ( A. leek )), rapeseed (A. Brassicola ( A. brassicicola ) or to Brassica ( cabbages )), sugar beet (A. Tenuis ( A. thin )), fruit (e.g., A. Grandis ( A. grandis )), rice, soybeans, potatoes, and tomatoes (e.g., A. Solani ( A. solani ), A. Grandis ( A. grandis ) or A. Alternata ( A. alternata )), tomato (e.g., A. Solani ( A. solani ) or A. Alternata ( A. alternata )) and mill (e.g., A. Tritisina ( A. triticina Alternaria spp. ( Alternaria spp.) (Alternaria leaf spot); Aphanomyces spp. on sugar beets and vegetables. Aphanomyces spp.); Ascocchita spp. for grains and vegetables ( Ascochyta spp.), for example, A. Tritish for wheat ( A. wheat A. Horday on ) (anthracnose) and barley ( A. barley Aureobasidium erythropoiesis ( Aureobasidium zeae ) (Synonym: Capatiella ( Kapatiella zeae)); regarding the cone Non-polaris ( Bipolar ) and Drexlera spp. ( Drechslera spp.) (Perfect generation type: Cocliobolus spp. ( Snail spp.)), for example, Southern leaf blight (D. mydis ( D. maydis )) or Northern leaf blight (b. J. Jaikola ( B. zeicola )), for example, barley leaf spot on grains (b. soroquiniana ( B. sorokiniana )) and, for example, regarding rice and grass, B. Oryzae ( B. oryzae ); Blumeria for grains (e.g., wheat or barley) Flower shop ) (Previously Ericipe ( Erysipelas Graminis ( grass ) (powdery mildew); Botrytis cinerea on fruits and berries (e.g., strawberries), and vegetables (e.g., lettuce, carrots, celery, and cabbage) Botrytis cinerea ) (Fully generational type: Botryotinia pucheliana ( Botryotinia fuckeliana ): gray mold); onion family, rapeseed, ornamental plants (e.g., B. elliptica ( B elliptical )), B. Squamosa ( for vines, forestry plants and wheat B. squamosa ) or b. Ali ( B. allii ); Bremia lactuca for lettuce ( Bremia lettuce ) (downy mildew); Ceratosistis on broadleaf and evergreen trees ( Ceratocystis ) (Synonym: opiostoma ( Ophiostoma )) spp. (rot or wilt), e.g., seeds of elm trees. Ulmi ( C. elm ) (Dutch elm disease); cone (e.g., gray leaf spot: s. zea-emaidis ( C. zeae-maydis )), rice, sugar beet (e.g., seeds. Veticola ( C. beticola )), sugarcane, vegetables, coffee, soybeans (e.g., seeds. Soybeans or ( C. sojina ) or Mr. Kikuchi ( C. kikuchii )) and cercospora spp. on rice. Cercospora spp.) (Cercospora leaf spot); Cladobotrium on mushrooms ( Cladobotryum ) (Synonym: Dactylium ( Dactylus )) spp. (e.g., C. Micophyllum ( C. mycophilum ) (Previously Dactylium dendroides ( Dactylium dendroides ), perfect generation type: Nectria Albertini ( Nectria albertinii ), Nectria Rosella ( Nectaria rosella ) Synonym Hippomice rosellus ( Hypomyces rosellus )); Tomato (e.g., seed. Fullboom ( C. fulvum ): Cladosporium spp. (leaf fungus) and grains Cladosporium spp.), for example, seeds of wheat. Herbarum ( C. herbs ) (black ear); Claviceps purpurea on grain ( Claviceps purpurea ) (ergot); cone (seed. carbonum ( C. carbon )), grain (e.g., seed. Sativus ( C. sativus ), incomplete generation type: b. soroquiniana ( B. sorokiniana )) and rice (e.g., seeds. Miyabeanus ( C. miyabeanus ), Incomplete generation type: H. Orizae ( H. oryzae Cocliobolus ( )) regarding ( Snail ) (Incomplete generation type: Non-Polaris ( Bipolar )'s Helminthosporium ( Helminthosporium )) spp. (leaf spot); cotton (e.g., seeds. gossypie ( C. gossypii )), cone (e.g., seed. Graminicola ( C. graminicola ): Anthracnose, stalk rot), soft fruits, potatoes (e.g., seeds. Cocodes ( C. coccus ): black spots), beans (e.g., seeds. Lindemutianum ( C. lindemuthianum )), soybeans (e.g., seeds. Truncatum ( C. truncatum ) or seed. Gloeosphorioides ( C. gloeosporioides )), vegetables (e.g., seeds. Lagenarium ( C. lagenarium ) or seed. Capsi ( C. capsicum )), fruit (e.g., seed. Acutatum ( C. acutatum )), coffee (e.g., seed. Coffeanum ( C. coffeanum ) or Mr. Kahawae ( C. kahawae Coletotrichum ( )) regarding ( Colletotrichum) (Fully Generational Type: Glomerella ( Glomerulus )) spp. (anthracnose) and seeds for various crops. Gloeosphorioides ( C. gloeosporioides Corticus spp. on rice. Bark spp.), for example, Mr. Sasaki ( C. sasakii ) (sheath blight); Corynesphora cassicola on soybeans and ornamental plants ( Corynespora cassicola ) (leaf spot); Cycloconium spp. on olive trees. Cyclone spp.), for example, C. oleaginum ( C. oleaginous ); fruit trees, vines (e.g., seeds. Liriodendri ( C. liriodendri ), Full Generation Type: Neonectria Liriodendri ( Neonectria liriodendri ): Cylindrocarphon spp. for blackfoot disease) and ornamental plants. Cylindrocarpon spp.) (e.g., fruit tree blight or young vine decline, perfect generation type: Nectria ( Nectarine ) or neonectria spp. ( Neonectria spp.)); Dematophora for soybeans ( Dematophora ) (Fully generational type: Roselinia ( Rosellinia )) Necatrix ( murderer ) (root and stem rot); Diaporte spp. on soybeans ( Diaporthe spp.), for example, D. passeolorum ( D. bean ) (damping-off); corn, grain, e.g., barley (e.g., D. Teres ( Mr. teres ), stales) and wheat (e.g., D. triticis-lepentis ( D. tritici-repentis ): Yellowish-brown spot), Drexlera for rice and turf ( Drechslera ) (Synonym: Helminthosporium ( Helminthosporium ), complete generation type: Pyrenophora ( Pyrenophora )) spp. ; Formitiforia ( Formitiporia ) (Synonym: Pelinus ( Phellinus )) Punctata ( dotted), F. Mediterranea ( F. mediterranea ), Paeomoniella chlamidospora ( Phaeomoniella chlamydospora ) (Previously, Paeoacremonium chlamidosporum ( Phaeoacremonium chlamydosporum )), Paeoacremonium alleophyllum ( Phaeoacremonium aleophilum ) and / or Botriospaeria obtusa ( Botryosphaeria obtusa Esca (stem blight, scrofula) on vine plants caused by ); pomegranates (this. snail ( E. pyri )), soft fruits (I. Veneta ( E. veneta ): Anthracnose) and vines (i. ampelina ( E. ampelina Elsinore spp. (Anthracnose) Elsinore spp.); Antilomatous oryzae for rice ( Rice Entyloma ) (leaf smut); Epicocum spp. on wheat ( Epicoccum spp.) (black mold disease); sugar beet (i. betae ( E. beet )), vegetables (e.g., this. fish ( E. peas )), for example, the gourd (for example, this *Sicoracearum* ( E. chicory )), cabbage, rapeseed (e.g., this. cruciferarum ( E. cruciferaru Ericiphe spp. for m)) Erysipelas spp.) (powdery mildew); Eutiparata on fruit trees, vines and ornamental trees ( Eutypa lata ) (Utipa blight or stem blight, imperfect stage: Cytosporina lata ( Cytosporin broad ), Synonyms: Libertella bleparis ( Libertella blepharis )); Con (e.g., this. thursicum ( E. turcicum Exerohillum ( regarding )) Exerohyl ) (Synonym: Helminthosporium ( Helminthosporium )) spp. ; Fusarium on various plants ( Fusarium ) (Fully Generational Type: Gibberella ( Gibberella)) spp. (wilt, root or stem rot), e.g. F. graminearum for grains (e.g., wheat or barley) F. graminearum ) or F. Coolmorum ( F. culms ) (root rot, hull or ear blight), F. oxysporum for tomatoes, F. solani for soybeans ( F. solani ) (f. sp. Glycines (f. sp. wisteria ), Current synonym: F. Birguliforme ( F. virguliforme )) and F. Tukumania ( F. tucumaniae ) and F. Brasilience ( F. brasiliense ) (each causing sudden death syndrome), and F. Bertisilioides for Con ( F. verticillioides ); Gaeumannomyces graminis for grains (e.g., wheat or barley) and cones ( Gaeumannomyces graminis ) (sinkhole); grain (e.g., g. Jea-e ( G. zeae )) and rice (e.g., Ji. Fujikuroi ( G. fujikuroi ): Gibberella spp. against Bacchanae's disease) Gibberella spp.); Glomerella shingulata on vines, pomegranates and other plants ( Glomerella cingulate G. regarding ) and cotton. G.C.P.E. ( G. gossypii ); grain-staining complex for rice; Guignardia vidwellii for vines ( Guignardia bidwellii ) (Black rot); Gymnosporangium spp. on Rosaceae plants and junipers. Gymnosporangium spp.), for example, regarding the ship. To Sabina ( G. sabinae ) (rust); Helminthosporium spp. on corn, grains, and rice. Helminthosporium spp.) (Synonym: Drexlera ( Drechslera ), perfect generation type: Cocliobolus ( Snail )); Hemilea spp. ( Hemileiaspp.), for example, H. Vastattrix ( H. vastatrix ) (coffee leaf rust); Isariopsis clavispora on vines ( Isariopsis clavispora ) (Synonym: Cladosporium vitis ( Cladosporium vitis Macroformina phaseolina for soybeans and cotton ( Macrophomina phaseolina ) (Synonym: Passeoli ( beans )) (root and stem rot); Microdocium (for grains (e.g., wheat or barley) Microdochium ) (Synonym: Fusarium ( Fusarium )) Nibale ( snowy ) (Pink eye rot); Microspaela difusa on soybeans ( Microsphere diffuse ) (powdery mildew); Monilinia spp. on drupes and other Rosaceae plants. Monilinia spp.), for example, M. laxa, M. fructicola ( M. fructicola ) and M. Fructigena ( M. fructigena ) (Synonyms Monilia spp. ( Necklaces spp.): Flower and branch blight, brown rot); Micosphaerella spp. on cereals, bananas, soft fruits, and peanuts. Mycosphaerella spp.), for example, M. Graminicola for wheat ( M. graminicola ) (Incomplete generation type: Zymoseptoria Tritish ( Zymoseptoria of wheat ) Previously, Septoria Tritish ( Septoria wheat ): Septoria Bloch ( Septoria blotch )) or M. psygensis for banana ( M. fijiensis ) (Synonym Pseudocercospora phygensis ( Pseudocercospora fijiensis ): Black Cigarette (in a bottle) and M. Musicola ( M. musicola ), M. Arachidicola ( M. arachidicola ) (Synonym M. Arachidis ( M. arachidis ) or Sercospora arachidis ( Cercospora arachis )), M. Berkelley on peanuts ( M. berkeleyi ), M. Fish on peas ( M. pea M. brassiciola ( ) and Brassica plants ( M. brassicola ); cabbage (e.g., p. brasicae ( Brassica graminae )), rapeseed (e.g., p. parasitica ( P. parasitica )), onion (e.g., blood. destructor ( P. destructor )), cigarettes (P. Tabashina ( P. tabacina )) and soybeans (e.g., p. mansurika ( P. manshurica Pheronospora spp. ( Downy mildew spp.) (downy mildew); Pachopsora pachyridge on soybeans ( Phakopsora pachyrhizi ) and p. Meibomia ( P. meibomiae ) (soybean rust); for example, vine plants (e.g., Phragmites thracnose ( P. tracheiphila ) and p. tetraspora ( P. tetraspora )) and soybeans (e.g., p. gregata ( P. gregata ): Pyalopora spp. against stem rot) Phyllophora spp.); pomaringam for rapeseed and cabbage ( Phoma lingam ) (Synonym Leptospiria biglobosa ( Leptosphaeria biglobosa ) and El. Maculans ( L. maculans ): Root and stem rot), blood on sugar beets. On beta ( P. beet ) (root rot, leaf spot, and damping-off) and corn. Zeaemidis ( P. zeae-maydis ) (Synonym: Philostia ( Zea phyllostica )); sunflower, vine plant (e.g., blood. Viticola ( P. viticola ): Can and leaf spot) and soybeans (e.g., stem rot: p. phaseoli ( P. bean ), fully generational type: Diaporte Passeolorum ( Diaporthe beanolorum Pomorphosis spp. ( Phomopsis spp.); Pisoderma maidis for the cone ( Physoderma maydis) (spot disease); various plants, e.g., paprika and gourds (e.g., paprika. capsicum ( P. capsici )), soybeans (e.g., p. megasperma ( P. megasperma ), synonyms: p. to the small ( P. sojae )), potatoes and tomatoes (e.g., p. infestans ( P. infestans Phytophthora spp. ( ): leaf blight) and hardwoods (e.g., P. ramorum: oak sudden death) Phytophthora spp.) (wilt disease, stems, leaves, fruits, and upper roots); Plasmodiophora brasica on cabbage, rapeseed, radish, and other plants ( Brassica spp. ) (root knot disease); Plasmophara spp. ( Plasmopara spp.), for example, blood on vine plants. Viticola ( P. viticola ) (grapevine downy mildew) and p. for sunflowers. Halsteady ( P. halstedii ); Rosaceae plants, hops, pome and soft fruits (e.g., pomegranates for apples. Leukotriecas ( P. leucotricha )) and gourd (P. Zanti ( P. xanthii Podosphaera spp. (powdery mildew) against )) grains, e.g., barley and wheat (P. graminis ( P. graminis )) and sugar beet (P. Beta ( P. beet Polymixa spp. for )) Polymyx spp.) and infectious viral diseases caused by them; Pseudocercosporella herpotlycoides on grains, e.g., wheat or barley ( Pseudocercosporella herpotrichoides ) (Synonyms: Okulimakula Yallundae ( Yalunda's eyespots ), Oh. Acupomys ( O. acuformis ): Anjeom, full generation type: Tapescia Yallundae ( Tapesia yallundae )); Pseudopheronospora on various plants ( Downy mildew ) (downy mildew), for example, on gourds. Quvensis ( P. cubensis) or P. humili for hops; Pseudopexicula tracheiphylla for vines ( Pseudopezicula tracheiphila ) (Red flame or Rotbrenner ( red burner ), incomplete generation type: phialophora ( Phyllophora )); Fushinia spp. on various plants ( Powdery mildew spp.) (rust), for example, on grains, e.g., wheat, barley, or rye. tritisina ( P. triticina ) (brown or leaf rust), p. striiformis ( P. striiformis ) (striped or yellow rust), blood. Horday ( Barley gram ) (dwarf rust), blood. Graminis ( P. graminis ) (stem or black rust) or p. recondita ( P. hidden ) (brown or leaf rust), bleeding of sugarcane. Quenii ( P. kuehnii Blood on ) (orange rust) and asparagus. Asparagi ( P. asparagus ); Pyrenophora for wheat ( Pyrenophora ) (Incomplete Generation Type: Drechslera) Tritish-Repentis ( wheat-creeping ) (yellowish-brown spot) or blood on barley. Teres ( P. teres ) (Red spot); Pyricularia spp. on rice. Firefly spp.), for example, p. Oryzae ( P. oryzae ) (Fully Generational Type: Magnaporte Grisea ( Magnaporthe grisea ), blast) and blood on grass and grain. Grisea ( P. grisea ); Pythium spp. for grass, rice, corn, wheat, cotton, rapeseed, sunflower, soybean, sugar beet, vegetables and various other plants. Pythium spp.) (Damping-off) (e.g., P. ultimum ( P. ultimate ) or p. Aphanidermatum ( P. aphanidermatum )) and blood regarding mushrooms. Oligandrum ( P. oligandrum ); Lamularia spp. on barley. Ramulariaspp.), for example, al. colo-signi ( Swan-necked R. ) (Lamularia leaf spot, physiological leaf spot) and egg for sugar beets. Beticola ( R. beticola Rhizoctonia spp. on cotton, rice, potatoes, grass, corn, rapeseed, sugar beets, vegetables, and various other plants. Rhizoctonia spp.), for example, al. regarding soybeans. Solani ( R. solani ) (root and stem rot), eggs regarding rice. Solani ( R. solani ) (sheath blight) or eggs for wheat or barley. Cerealis ( R. cerealis ) (Rhizoctonia spring blight); Rhizopus stolonifera on strawberries, carrots, cabbage, vines and tomatoes ( Rhizopus stolonifera ) (black mold, soft rot); Lincosporium secalis on barley, rye, and rye ( Rhynchosporium secalis ) and al. Komune ( Common rose ) (Dame); Sarcophyllum oryzae on rice ( Sarocladium oryzae ) and S. atenuatum ( S. attenuatum ) (sheath rot); vegetables (S. minor ( S. minor ) and S. Schulerotiorum ( S. sclerotiorum ) and crops, e.g., rapeseed, sunflower (e.g., S. sclerotiorum ( S. sclerotiorum Sclerotinia spp. on )) and soybeans. Sclerotinia spp.) (stem rot or white mold), S. rolfsii on soybeans, peanuts, vegetables, corn, grains and ornamental plants ( S. rolfsii ) (Synonym: Arteria Rolfsiy ( Athelia rolfsii )); Ceptoria spp. on various plants ( Septoria spp.), for example, S. glycine for soybeans ( S. glycine ) (scaber), S. tritis for wheat ( Wheat S. ) (Synonym Zymoceptoria triticis ( Zymoseptoria of wheat ), Septoria Bloch ( Septoria blotch)) and S. regarding grains. ( S. ) (Synonym: stagonospora ( Stagonospora )) Nodoroom ( knots ) (Stagonospora bloch ( Stagonospora blotch Uncinula (for climbing plants) Hook ) (Synonym: Ericipe ( Erysipelas )) Necator ( murderer ) (Powdery mildew, imperfect generation: Oedium tucheriai ( Tucker's powdery mildew )); con (e.g., S. thursicum ( S. turcicum ), synonyms: Helminthosporium tursicum ( Helminthosporium turcicum )) and Cetosphaeria spp. on grass. Setospaeria spp.) (leaf blight); cone (e.g., S. leiliana ( S. reiliana ), synonym Ustilago Leiliana ( Reiliana striatum ): Smut), Spacelloteca spp. on sorghum and sugarcane. Sphacelotheca spp.) (smut); Sphaerotheca pulginea on gourds ( Sphaerotheca fuliginea ) (Synonym: Podospera Zanti ( Podosphaera xanthii ): powdery mildew); Spongospora subterranea on potatoes ( Subterranean sponge ) (powdery spot) and infectious viral diseases caused by it; Stagonospora spp. on grains. Stagonospora spp.), for example, S. nodorum for wheat ( S. nodorum ) (Stagonospora Bloch, Perfect Generation Type: Leftospaeria ( Leptosphaeria ) [Synonym: Phaeospaeria ( Phaeosphere )] Nodoroom ( knots ), synonym Septoria nodorum ( Septoria knotweed )); Synchytrium endobioticum on potatoes ( Synchytrium endobioticum ) (potato wart disease); Tapirina spp. on peaches. Taphrina spp.), for example, T. Deformance ( T. deformans Tea for ) (leaf curl) and plums. Pruni ( T. pruni) (plum pocket disease); Tielabiopsis spp. on tobacco, pomegranates, vegetables, soybeans, and cotton. Thielaviopsis spp.) (black root rot), for example, tea. basicola ( T. basicola ) (Synonym: Kalara elegans ( Chalara elegans )); Tiletia spp. for grains ( Tilletia spp.) (common bunt or stinking smut), e.g., on wheat. trititis ( T. wheat ) (Synonym: T. Caries ( T. caries ), wheat smut) and T. Controversa ( T. controversa ) (dwarf disease, fishy smut); Trichoderma harzianum on mushrooms ( Trichoderma harzianum ); Tipula incarnata for barley or wheat ( Typhula incarnata ) (Gray-eye rot); Urocytis spp. on rye. Urocyst spp.), for example, U. Occulta ( U. occulta ) (stem smut); vegetables, e.g., beans (e.g., *Apendiculatus* ( U. appendiculatus ), Synonyms: U. Passeoli ( U. bean )), sugar beet (e.g., Yu. Beta ( U. beet ) or Yu. Veticola ( U. beticola )) and legumes (e.g., milk, vignet ( U. vineyards ), U. Fish ( U. peas ), Yu. Bisiae-Pabae ( U. viciae-fabae ) and Yu. Pabae ( U. beans Ouromyces spp. regarding )) Uromyces spp.) (rust); grain (e.g., oil. Nuda ( U. naked ) and U. Abaenae ( U. avenae )), Con (e.g., You. My This ( U. maydis ): Ustilago spp. (corn smut) and sugarcane I burn. spp.) (Smut); Apple (e.g., V. inaequalis ( V. unequal Venturia spp. ( )) and on the vessel Ventura spp.) (black star spot); and Verticillium spp. (on various plants, e.g., fruit and ornamental plants, vines, soft fruits, vegetables and crops) Verticillium wilt spp.) (wilt disease), for example, V. longisporum for rapeseed ( V. longisporum ), V. to strawberries, rapeseed, potatoes, and tomatoes. To dahlias ( V. dahliae V. Fungikola ( V. Fungi ); Zymoseptoria tritisii for grains ( Zymoseptoria of wheat ).

[0094] The mixture of the present invention can be converted into conventional types of agrochemical compositions, e.g., solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof. These and additional types of compositions are defined in "Catalogue of pesticide formulation types and international coding system", Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.

[0095] The composition is prepared in a known manner, such as as described in Mollet and Grube-mann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

[0096] The mixture of the present invention is used either in itself or in the form of a composition by treating plants, plant propagation materials, such as seeds, soil, surfaces, materials, or spaces to be protected from insect or fungal attack with an insecticidally effective amount of the active compound. Application may be performed both before and after infection of plants, plant propagation materials, such as seeds, soil, surfaces, materials, or spaces by insects.

[0097] The present invention also comprises a method for combating animal pests and harmful fungi, comprising contacting fungi and / or animal pests, their habitats, breeding grounds, feeding grounds, cultivated plants, seeds, soil, areas, materials, or environments where animal pests are growing or may grow, or materials, plants, seeds, soil, surfaces, or spaces to be protected from animal attack or intrusion, with a mixture according to the present invention in an insecticidal amount.

[0098] Dimpropyridase and one or more compound(s) B are typically applied in a weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, or 20:1 to 1:20, particularly 10:1 to 1:10.

[0099] Generally, "insecticidal effective amount" refers to the amount of the mixture of the present invention or a composition containing such mixture required to achieve a visible effect on the growth of a target organism, including necrosis, death, disruption, prevention and elimination, destruction, or other reduction in occurrence and activity. The insecticidal effective amount may vary depending on the various mixtures and / or compositions used in the present invention. The insecticidal effective amount of the mixtures and / or compositions will also vary depending on the desired insecticidal effect and prevailing conditions such as duration, climate, target species, location, method of application, etc.

[0100] Examples

[0101] The present invention is now illustrated in more detail by the following examples.

[0102] Synergy can be described as an interaction where the combined effect of two or more compounds is greater than the sum of the individual effects of each compound. In terms of control rate or efficacy ((%)), the presence of a synergistic effect between two mixing partners (X and Y) can be calculated using the Colby equation (Colby, SR, 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22):

[0103]

[0104] The relative growth rate (%) of the pathogen at the active compound was determined by comparing the measured parameters with the growth of the active compound-free control variant (100%) and the fungal-free blank values. These percentages were converted into efficacy.

[0105] Efficacy 0 means that the growth level of the pathogen corresponds to the growth level of the untreated control; efficacy 100 means that the pathogen did not grow.

[0106] The expected efficacy of the active compound mixture was verified using the Colby formula [RS Colby, "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] and compared with the observed efficacy.

[0107] The following tests may demonstrate the control efficacy of the mixture or composition of the present invention against specific fungi. However, the pest control protection provided by the said compound, mixture, or composition is not limited to these species. In certain cases, a combination of the compound of the present invention with other invertebrate pest control compounds or agents has been found to exhibit a synergistic effect against certain important invertebrate pests and / or harmful fungi.

[0108] The active compound was separately prepared as a stock solution having a concentration of 10,000 ppm in dimethyl sulfoxide.

[0109] The product oxathiapiproline was used as a commercially finished formulation and diluted with water to produce the active compound at the mentioned concentration.

[0110] 1. In a micropotency test, the leaf blight pathogen Phytophthora infestans ( Phytophthora infestans ) activity for

[0111] Mix the stock solution according to the specified ratio, pipette onto a microtiter plate (MTP), and dilute with water to the mentioned concentration. Phytophthora infestans containing pea juice-based aqueous nutrient medium or DDC medium ( Phytophthora infestans The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0112]

[0113] 2. In the microtiter plate test, the gray mold Botrytis cinerea ( Botrytis cinerea ) activity for

[0114] Mix the stock solution according to the specified ratio, pipette onto a microtitrate plate (MTP), and dilute with water to the stated concentration. Botrytis cinerea in an aqueous biomalt or yeast-bactopeptone-sodium acetate solution ( Botrytis cinerea The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0115]

[0116] 3. Septoria Tritish ( Septoria wheat Activity against wheat leaf blight caused by )

[0117] Mix the stock solution according to the specified ratio, pipette onto a micro-titration plate (MTP), and dilute with water to the stated concentration. Ceptoria triticis in aqueous biomalt or yeast-bactopeptone-glycerin or DOB solution ( Septoria wheat The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0118]

[0119] 4. In the microtitivity test, Certospora sojina ( Cercospora soybean ) activity for

[0120] Mix the stock solution according to the specified ratio, pipette it onto a micro-titration plate (MTP), and dilute with water to the stated concentration. Certospora sojina in an aqueous biomalt or yeast-bactopeptone-sodium acetate solution ( Cercospora soybeanThe spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0121]

[0122] 5. In the micro-titration plate test, Coletotrichum orbiculare ( Colletotrichum orbiculare ) activity for

[0123] Mix the stock solution according to the specified ratio, pipette it onto a micro-titration plate (MTP), and dilute with water to the stated concentration. Coletotrichum orbiculare in an aqueous biomalt or yeast-bactopeptone-sodium acetate solution ( Colletotrichum orbiculare The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0124]

[0125] 6. In the micro-titer plate test, Lincosporium secalis ( Rhynchosporium secalis ) activity for

[0126] Mix the stock solution according to the specified ratio, pipette onto a microtiter plate (MTP), and dilute with water to the stated concentration. Lincosporium secalis in aqueous biomalt or yeast-bactopeptone-glycerin or DOB solution ( Rhynchosporium secalis The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0127]

[0128] 7. In the microtiter plate test, Sclerotinia sclerothiorum ( Sclerotinia sclerotiorum ) activity for

[0129] The stock solution was mixed according to the specified ratio, pipetted onto a micro-titration plate (MTP), and diluted with water to the stated concentration. Sclerotinia sclerothiorum in an aqueous biomalt or yeast-bactopeptone-glycerin or DOB solution ( Sclerotinia sclerotiorum The spore suspension of ) was then added. The plate was placed in a steam-saturated chamber at a temperature of 18°C. Using an absorption photometer, MTP was measured at 405 nm on the 7th day after inoculation.

[0130]

Claims

Claim 1 Insecticide mixture comprising the following as an active ingredient: 1) 1-(1,2-dimethylpropyl)-N-ethyl-5-methyl-N-pyridazine-4-yl-pyrazole-4-carboxamide of Formula I: and 2) at least one additional compound B selected from the following: B.1) a succinate dehydrogenase inhibitor selected from the following: a) pidiflumetophen, b) pyraziflumide, d) pyrapropone, e) fluindapyr, and f) isoflushipram; B.3) an inhibitor of complex III at the Qi site, florylpicoxamide; and B.5) 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazole-1-yl)propyl]-3-pyridyl]oxy]benzonitrile; wherein component 1) and component 2) are present in a weight ratio of 1000:1 to 1:1000. Claim 2 In claim 1, the insecticidal mixture in which component 1) and component 2) exist in a weight ratio of 100:1 to 1:

100. Claim 3 In claim 1, the insecticidal mixture is present in a weight ratio of 20:1 to 1:20, wherein component 1) and component 2) are present. Claim 4 In claim 1, the insecticidal mixture is present in a weight ratio of 10:1 to 1:10, wherein component 1) and component 2) are present. Claim 5 In claim 1, an insecticidal mixture comprising one compound B. Claim 6 In any one of claims 1 to 5, component 2) is an insecticidal mixture selected from compounds B.1 a), b), and d) to f). Claim 7 delete Claim 8 In any one of claims 1 to 5, component 2) is an insecticidal mixture of compound B.

3. Claim 9 delete Claim 10 In any one of claims 1 to 5, component 2) is an insecticidal mixture of compound B.

5. Claim 11 delete Claim 12 delete Claim 13 A method for controlling plant pathogenic harmful fungi, comprising contacting the fungi, their habitats, or plants, soil, or seeds to be protected against fungal attack with an effective amount of an insecticidal mixture according to any one of claims 1 to 5. Claim 14 A method for protecting a growing plant or plant propagation material from attack or intrusion by invertebrate pests, comprising contacting the plant, plant propagation material, or soil or water on which the plant is growing with an effective amount of an insecticidal mixture according to any one of claims 1 to 5.

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