COMPOSITIONS CONTAINING HFO-1234ZE, HFO-1225ZC AND HFO-1234YF AND PROCESSES FOR PRODUCING AND USING THE COMPOSITIONS

MX434021BActive Publication Date: 2026-05-19THE CHEMOURS CO FC LLC

Patent Information

Authority / Receiving Office
MX · MX
Patent Type
Patents
Current Assignee / Owner
THE CHEMOURS CO FC LLC
Filing Date
2021-10-25
Publication Date
2026-05-19

AI Technical Summary

Technical Problem

There is a need for refrigerant compositions that have low ozone depletion potential and low global warming potential, and efficient processes to produce these compositions without the need for additional purification or separation steps to remove excessive amounts of undesirable isomers.

Method used

A method involving the gas-phase dehydrofluorination of 1,1,1,3,3-pentafluoropropane using a catalyst such as fluorinated Cr2O3 or Cr/Ni on fluorinated alumina, in the presence of an oxygen-containing gas, to produce a mixture of HFO-1234ze(E), HFO-1225zc, and HFO-1234yf, minimizing the need for isomer separation or purification steps.

Benefits of technology

The process achieves a high yield of the desired isomer (HFO-1234ze(E)) while eliminating the need for additional purification steps, resulting in compositions suitable for use as refrigerants with low ozone depletion and global warming potential, suitable for refrigeration systems and other applications.

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Abstract

A fluoropropene composition comprising E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, and 2,3,3,3-tetrafluoropropene, wherein the total amount of 1,1,3,3,3-pentafluoropropene and 2,3,3,3-tetrafluoropropene is 1.0% by weight or less, based on the total weight of the fluoropropene composition. A method for producing the fluoropropene, the composition, and methods for using the fluoropropene composition are also described.
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