Pesticidal compositions.

Abstract

The present invention relates to a molecule of the following formula: wherein: (a) Ari is a substituted phenyl wherein said substituted phenyl has one or more substituents independently selected from Q-C6 haloalkyl and C,-C6 haloalkoxy; (b) Het is a 1,3 -disubstituted 1,2,4-triazole where A rl and Ar2 are not ortho to each other but are 1,3; (c) Ar2 is a phenyl, (d) XI is 0 or S; (e) X2 is 0 or S; and (f) R4 is H or C1 -C6 alkyl; (g) Ri, R2 , and R3 are independently selected from H, F, Cl, Br, I, CN, N 0 2, C,-C6 alkyl, C,-C6 haloalkyl, C3 -C6 cycloalkyl, C3 -C6 halocycloalkyl, C2 -C6 alkenyl, C2 -C6 alkynyl, C(=0)H, C(=0)NRxRy, (Ci-C6 alkyl)NRxRy, C(=0)(C|C6 alkyl), C (=0)0(C i-C6 alkyl),(C,- C6 alkyl)0(C,-C6 alkyl)0(Ci-C6 alkyl), C(=0)(Cr C6 haloalkyl), C (=0)0(C ,-C6 haloalkyl), C(=0)(C3C6 cycloalkyl), C (= 0)0(C3 -C6 cycloalkyl), C(=0)(C2 -C6 alkenyl), C (= 0)0(C2 -C6 alkenyl), (CrCe alkyl)0(Ci-C6 alkyl), (C,-C6 alkyl)S(C,-C6 alkyl), C(=0)(Ci-C6 a!kyl)C (= 0 )0 (0 , -C6 alkyl), C(=0)phenyl, phenyl, Cj-Ce alkylphenyl, C(=0)phenoxy, phenoxy, C1 -C6 alkylphenoxy, C(=0)H et-l, Het-1, or C,-C6 alkylHet-1, wherein Het-1 is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, and wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, phenoxy, and Het-1, are optionally substituted with one or more substituents independently selected from F, Cl, Br, I, CN, NO2 , oxo, C,-C6 alkyl, C,-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C1 -C6 alkoxy, C1 -C6 haloalkoxy, C2 -C6 alkenyl, C2 -C6 alkynyl, S(=0)n(Ci- C6 alkyl), S(=0)n(C,-C6 haloalkyl), 0 S 0 2(C,-C6 alkyl), 0 S 0 2(Ci-C6 haloalkyl), C(=0)H, C(=0)NRxRy, (Ci-C6 alkyl)NRxRy, (Ci-C6 alkenyl)NRxRy, (C1 -C6 alkynyl)NRxRy, C(=0)(C,-C6 alkyl), C (=0)0(C ,-C 6 alkyl), C(=0)(Ci-C6 haloalkyl), C (=0)0(C i-C 6 haloalkyl), C(=0)(C3-C6 cycloalkyl), C (=0)0(C 3C6 cycloalkyl), C(=0)(C2-C6 alkenyl), C (=0)0(C 2-C6 alkenyl), (Ci-C6 alkyl)0(Ci-C6 alkyl), (Ci-C6 alkyl)S(C,-C6 alkyl), C(=0)(C,-C6 alkyl)C(=0)0(Ci-C6 alkyl), phenyl, phenoxy, and Het-1, wherein n = 0 , 1, or 2; wherein Rx and Ry are independently selected from H, Ci-C6 alkyl, C1 -C6 haloalkyl, C3 - C6 cycloalkyl, C3 -C6 halocycloalkyl, C3 Cecycloalkoxy, C3 -C6 halocycloalkoxy,CiC e alkoxy, C1 -C6 haloalkoxy, C 2- C e alkenyl, C2 C e alkynyl, S(=0)n(Ci-C6 alkyl), S(=0)n(C r Cehaloalkyl), 0S02(Ci-C6 alkyl), OSC>2 (Ci-C6 haloalkyl), C(=0)H, C(=0)(C,-C6 alkyl), C (O )0 (C ,-C 6 alkyl), C (=0)(C r C6 haloalkyl), 0 (= 0 )0 (0 ,-C6 haloalkyl), C(=0)(C3- C6 cycloalkyl), C (=0)0(C3 -C6 cycloalkyl), C(=0)(C2 -C6 alkenyl), C (= 0)0(C2 -C6 alkenyl), (Ci-C6 alkyl)0(Ci-C6 alkyl), (Ci-C6 alkyl)S(Ci -C6 alkyl), C(=0)(Ci -C6 alkyl)C(=0)0(C,- C6 alkyl), phenyl, and phenoxy; wherein Ri and R2 together can optionally form a 3 - to 1 2 -membered saturated or unsaturated cyclic group which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen with the proviso that there is not a Ci— 0 - bond in such cyclic group) wherein said cyclic group may have one or more substituents independently selected from F, Cl, Br, I, CN, N 0 2, 0 x0 , C1 -C6 alkyl, C1 -C6 haloalkyl, C3 -C6 cycloalkyl, C3 -C6 halocycloalkyl, C3 -C6 cycloalkoxy, C3 -C6 halocycloalkoxy, C1 -C6 alkoxy, C,-C6 haloalkoxy, C2 -C6 alkenyl, C2 -C6 alkynyl, S(=0)n(C,-C6 alkyl), S(=0)n(C,-C6 haloalkyl), 0 S 0 2(Ci-C6 alkyl), 0 S 0 2(C,-C6 haloalkyl), C(=0)H, C(=0)NRxRy, (Ci-C6 alkyl)NRxRy, C(=0)(C,-C6 alkyl), C (=0)0(C,C6 alkyl), C(=0)(Ci-C6 haloalkyl), C (=0)0(C,-C 6 haloalkyl), C(=0)(C3-C6 cycloalkyl), C (=0)0(C 3C e cycloalkyl), C(=0 )(C2 -C6 alkenyl), C (=0)0(C 2-C6 alkenyl), (C,-C6 alkyl)0(C,-C6 alkyl), (C1 -C6 alkyl)S(Ci-C6 alkyl), C(=0)(C,-C6 alkyl)C(=0)0(Ci-C6 alkyl), phenyl, phenoxy, and Het-1. and pesticidal compound suitable for controlling ectoparasites and endoparasites in the veterinary medicine sector.