Methods for forming a layer comprising a metal nitride or forming a threshold voltage tuning layer on a substrate and methods for filling a gap on a substrate

A method for depositing metal nitride layers on substrates by converting metal oxides with nitrogen-containing reactants addresses the challenge of finding suitable gate materials in CMOS devices and other semiconductor structures, enhancing device performance through work function and threshold voltage tuning.

TW202633270APending Publication Date: 2026-08-01ASM IP HLDG BV
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Patent Information

Application Number
TW115115025
Authority / Receiving Office
TW · TW
Patent Type
Applications
Current Assignee / Owner
Priority Date
2021-03-02
Filing Date
2022-02-23
Publication Date
2026-08-01

AI Technical Summary

Technical Problem

Conventional semiconductor device scaling techniques face challenges in finding suitable conductive materials for gate electrodes, particularly in CMOS devices, and there is a demand for new materials in structures like MIM and VNAND cells.

Method used

A method is developed for depositing a metal nitride layer on a substrate by converting a metal oxide using a nitrogen-containing reactant, involving deposition cycles with metal precursor and oxygen reactant pulses, followed by nitrogen exposure, suitable for forming layers in CMOS devices, MIM structures, and VNAND cells.

Benefits of technology

The method enables the formation of metal nitride layers suitable for work function tuning and threshold voltage adjustment, providing improved performance in CMOS devices and other semiconductor applications.

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Abstract

Disclosed are methods and systems for depositing layers comprising a metal and nitrogen. The layers are formed onto a surface of a substrate. The deposition process may be a cyclical deposition process. Exemplary structures in which the layers may be incorporated include field effect transistors, VNAND cells, metal-insulator-metal (MIM) structures, and DRAM capacitors.
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