Semiconductor device and methods of formation

TW202636940APending Publication Date: 2026-09-01TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
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Patent Information

Application Number
TW114114330
Authority / Receiving Office
TW · TW
Patent Type
Applications
Current Assignee / Owner
Priority Date
2025-02-27
Filing Date
2025-04-16
Publication Date
2026-09-01
Estimated Expiration
2045-04-15

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Abstract

A transistor structure may be formed in an interconnect layer of a semiconductor device in a process that includes ultraviolet (UV) light curing and ozone (O₃) treatment operations on a gate dielectric layer. The UV light curing and O₃ treatment may remove or reduce impurities formed in the gate dielectric layer. The UV light curing operation may break hydrogen bonds in the gate dielectric layer. The O₃ treatment process repairs the broken bonds, which strengthens metal-oxide bonds for the high-k dielectric material of the gate dielectric layer. The strengthening of the metal-oxide bonds in the gate dielectric layer may prevent oxygen from the gate dielectric layer from reacting with metals in an adjacent gate electrode and oxide-semiconductor channel. As a result, the transistor structure may have a higher breakdown voltage and increased performance in comparison to a transistor structure manufactured without using the UV light curing and O₃ treatment processes.
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Claims

1. A method for forming a semiconductor device, comprising: Deposit gate electrodes on the dielectric layer of the interconnect layer; A high-k gate dielectric layer is deposited on the gate electrode; Perform ultraviolet (UV) light treatment on the high dielectric constant gate dielectric layer; perform ozone (O3) treatment on the high dielectric constant gate dielectric layer; deposit an oxide semiconductor channel layer on the high dielectric constant gate dielectric layer; deposit a capping layer on the oxide semiconductor channel layer; and deposit a plurality of source / drain electrodes through portions of the capping layer to portions of the oxide semiconductor channel layer.

2. The method as described in claim 1, wherein the ultraviolet light treatment operation and the ozone treatment operation are performed simultaneously.

3. The method as described in claim 1, wherein the ozone treatment operation is performed after the ultraviolet light treatment operation.

4. The method of claim 1, wherein performing the ultraviolet light processing operation includes exposing the high dielectric constant gate dielectric layer to ultraviolet light having wavelengths ranging from about 100 nanometers to about 440 nanometers.

5. The method of claim 1, wherein the time for performing the ultraviolet light processing operation is in the range of about 30 seconds to about 300 seconds.

6. The method of claim 1, wherein performing the ozone treatment operation comprises flowing a mixture of ozone (O3) and oxygen (O2) over the high dielectric constant gate dielectric layer, and wherein the concentration of ozone in the mixture is in the range of about 10% to about 25%.

7. A method for forming a semiconductor device, comprising: A gate dielectric layer of the transistor structure is deposited on the gate electrode of the transistor structure, wherein the transistor structure is formed in the interconnect layer of the semiconductor device; The gate dielectric layer is exposed to ultraviolet light (UV) and ozone (O3); an oxide semiconductor channel layer is deposited on the gate dielectric layer; a capping layer is deposited on the oxide semiconductor channel layer; a first source / drain electrode is deposited to penetrate a first portion of the capping layer onto a first portion of the oxide semiconductor channel layer; And deposit a second source / drain electrode to pass through the second portion of the capping layer onto the second portion of the oxide semiconductor channel layer.

8. The method as described in claim 7, wherein the oxide semiconductor channel layer and the gate dielectric layer are in direct contact.

9. The method of claim 7, wherein the gate electrode and the gate dielectric layer are in direct contact.

10. A semiconductor device, comprising: Gate electrode; Oxide semiconductor channel layer; A high-k gate dielectric layer is located between the gate electrode and the oxide semiconductor channel layer, wherein the high-k gate dielectric layer directly contacts at least one of the gate electrode or the oxide semiconductor channel layer; a capping layer is located on the oxide semiconductor channel layer; a first source / drain electrode extends through a first portion of the capping layer to a first portion of the oxide semiconductor channel layer; And the second source / drain electrode passes through the second portion of the capping layer to the second portion of the oxide semiconductor channel layer.