Inert fluid assays for sealed core recovery

Abstract

Methods of determining if a test fluid is inert to reservoir oil at RTP, by assaying a composition, density and bubble or dew point of live oil to generate a first dataset, equilibrating a sample of live oil with a test fluid at RTP to generate an oil phase; assaying a composition, density and bubble or dew point of the oil phase to generate a second dataset; comparing the first and second datasets, wherein significant changes in the datasets indicate that the test fluid is not inert to reservoir oil at RTP. By contrast, if there are no significant changes, the test fluid is inert, and would therefore be suitable to collecting core samples at RTP. Various options for inert fluids are also provided.

Description

PRIOR RELATED APPLICATIONS

[0001] This application claims priority to US Serial No. 63 / 244,953, filed September 16, 2021, and incorporated by reference in its entirety for all purposes. FIELD OF THE DISCLOSURE

[0002] This disclosure provides methods of testing core preservation fluids for drilling core samples and returning them to the surface in an unchanged condition. BACKGROUND OF THE DISCLOSURE

[0003] One of the ways of studying rock characteristics is to drill and analyze a core sample from a reservoir. Similar to a drill bit, the rotary coring bit consists of solid metal with diamonds or tungsten for cutting at the reservoir rock, but unlike a drill bit, a rotary coring bit has a hollow center. The cutting apparatus thus surrounds the hollow center, called the core barrel, where the core sample is stored. The core barrel is made up of an inner and outer barrel separated by ball bearings, which allows the inner barrel to remain stationary and retain the core sample, while the outer barrel is rotated by the drill string and cuts the core. The core catcher is located within the core barrel and has finger-like apparatuses that move the core sample farther into the barrel and keep it from falling back into the well. After the core sample has been cut from the well, the drill string is raised, and the rotary coring bit, barrel and catcher are removed, and the core sample is retrieved. The drill bit is reattached, and drilling can commence again.

[0004] However, obtaining an unaltered core sample from a reservoir with these simple prior art devices remains challenging. As the core is retrieved from deep in the reservoir, the temperature and pressure decrease which allows gases to evolve out of solution and together with free gases, expand, resulting in reservoir fluids being forced out of the core. Thus, accurate sampling, especially of fluids, is difficult, if not impossible to obtain.

[0005] To address this problem, the core samples are sometimes collected and sealed in a chamber, in a method known as "pressure coring". Pressure coring at least partially solves the problem by maintaining the core specimen at bottom-hole pressure—BHP—until the core fluids can be recovered. This concept, first proposed by Sewell in the 1930's, remained a "laboratory" tool until the late 1970's, but with the advent of ever improving technology, the method is much more popular now.

[0006] However, in pressure coring the core samples are contained in an inert fluid known as FC-40 aka FLUORINERT™ which was developed for electronic uses, not uses in the petroleum industry. FC-40 is a colorless, thermally stable, fully fluorinated liquid that was believed to be inert, even at reservoir temperature and pressure (RTP). With the data presented herein, we now know that it in fact solubilizes some of the lighter fractions of oil, and thus skewing the results of high pressure core analysis. The discrepancy arises from the fact that standard testing techniques are wholly inappropriate for use with a so-called “inert” fluid developed for electronic uses, as opposed to downhole uses.

[0007] This disclosure for the first time provides assays and methodology to correctly assay downhole core samples, and further develop novel inert, high density fluids for use in obtaining and analyzing reservoir core samples. SUMMARY OF THE DISCLOSURE

[0008] FC-40 contains C5-18 perfluorocarbon chains, that are largely inert to electronics, but less so for petroleum, which contains short, medium, and long chain hydrocarbons. Table A provides the known FC-40 properties: Table A: FC-40 1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Liquid Odor, Color, Grade: Colorless, odorless liquid. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point 153 - 173 °C Flash Point No flash point Evaporation rate < 1 ^<S / J:BUOAC=1] Flammability (solid, gas) Not Applicable Flammable LimitsfLEL) None detected Flammable Limits(UEL) None detected Vapor Pressure 3 mmHg [(S' 25 °C] Vapor Density 22.5 [@ 25 °C]        AIR= 1 ] Density i .9 g / ml Specific Gravity7 1.9 ’ [^<SNLWATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanoV water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 2 centistoke [@ 25 °C ] Molecular weight No Data Available Volatile Organic Compounds [Details: Exempt] Percent volatile 100 % VOC Less H2O & Exempt Solvents [Details: Exempt]

[0009] As is apparent, FC-40 is not particularly viscous, but is fairly dense at 1.9 g / ml. Insomuch as electronics are concerned, it is fairly inert, but as demonstrated herein, light hydrocarbons have significant solubility in FC-40, even at atmospheric conditions, and at reservoir temperature and pressure (RTP), the problem is greatly exacerbated.

[0010] Thus, what is needed in the art are test methods for correctly assaying inert fluids for downhole uses. Such assays would allow the art to develop new materials that do not dissolve light hydrocarbons but is otherwise as dense and inert to the full range of petroleum constituents, especially at RTP. In the absence of an absolute inert fluid, characterization of solubility in FC-40 and other fluids at atmospheric and at reservoir conditions will provide methods to characterize interactions within the reservoir and simulate processes under reservoir conditions. The invention includes any one or more of the following embodiments, any one or more of which can be combined with any other one or more in any combination(s) thereof. A method of assaying a test fluid for collecting reservoir core samples at reservoir temperature and pressure (RTP) and determining if said test fluid is inert at RTP, said method comprising: a) assaying live oil to generate a first dataset using methods comprising two or more of: i) determining a weight contribution of components of said live oil; ii) determining a bubble point of said live oil; iii) determining a density of a remaining oil when said live oil is flashed to ambient conditions; or iv) determining a weight contribution of gaseous components flashed from said live oil; b) assaying live oil plus a test fluid mixed together and equilibrated at RTP to form a hydrocarbon phase and a test fluid phase to generate a second dataset, using methods comprising two or more of: i) determining a bubble point of said hydrocarbon phase; ii) determining a weight contribution of components of said hydrocarbon phase; iii) determining a density of a remaining hydrocarbon phase when said hydrocarbon phase is flashed to standard temperature and pressure (STP) or ambient conditions; or iv)     determining a weight contribution of gaseous components flashed from said hydrocarbon phase; c) comparing said first dataset and said second dataset, wherein changes in said datasets after equilibration with said test fluid indicates that said test fluid is not inert, but no changes in said datasets indicates said test fluid is inert and can be used to collect reservoir core samples at RTP. Any method described herein could also use instead of i-iv) or in addition thereto, any one or more of the following: determining total acid number (TAN), metal content, viscosity, asphaltene content, C7 content; nitrogen content, water content, carbon content, total contents; wax content; carbon residue content, conductivity, pour point, density@15°C; salt content, sediment content, specific gravity; light end hydrocarbon content; mercaptan content; hydrogen content, total sulfur, hydrogen sulfide content or vapor pressure of said hydrocarbon phase or said remaining hydrocarbon phase. A method of assaying a test fluid for inertness in collecting reservoir core samples at RTP, said method comprising: a)      obtaining an oil sample having a first characterization of elements, C1-C40 components, dissolved gas and density; b) mixing said oil sample plus a test fluid to form a mixture, and equilibrating said mixture at RTP to produce a hydrocarbon phase and a test fluid phase; c) assaying said hydrocarbon phase to determine a second characterization of elements, C1-C40 components, dissolved gas and density; d) comparing said first characterization with said second characterization to identify changes in characterization; e) wherein changes in characterization indicates that said test fluid is not inert, but no changes in characterization indicates said test fluid is inert and can be used to collect reservoir core samples at RTP, A method of determining if a test fluid is inert to reservoir oil at RTP, comprising: a) assaying a composition, density and bubble or dew point of live oil to generate a first dataset; b)equilibrating a sample of said live oil with a test fluid at RTP to generate a hydrocarbon phase; c) assaying a composition, density and bubble or dew point of said hydrocarbon phase to generate a second dataset; d) comparing said first and second datasets, wherein significant changes in said dataset indicates that said test fluid is not inert to reservoir oil at RTP. Any method herein described, wherein weight contribution is determined with gas chromatography, preferably with GC / FID, but other methods could be used including HPLC, elemental analysis, and the like. Any method herein described, wherein density of a fluid is determined using a HPHT densitometer at RTP. Any method herein described, wherein bubble point of a fluid is determined by stepping down the pressure from RTP and observing a pressure at which bubbles appear or by ASTM D2889 -95 (2019).' Any method herein described, wherein RTP is an average temperature and pressure of a play in the reservoir. Although we focus on composition, density, and bubble or dew points herein, other characterization methods could also be used, e.g., measuring Acidity TAN - total acid number; metals; viscosity; asphaltene, C7; nitrogen basic; water content; carbon content; nitrogen, total content; wax content; carbon residue; phosphorous content; conductivity; pour point; density@15°C; salt; distillation; sediments, gravity; silicon content; light end hydrocarbons; sulfur, mercaptans; hydrogen content; sulfur, total; hydrogen sulfide; vapor pressure and the like. These can be added to the characterization sets or in many cases substituted therefor. For example, in our experiments it would have sufficed to test for light ends only.

[0011] As used herein, “brominated” or “fluorinated” means to replace one or more hydrogens with bromine or fluorine.

[0012] As used herein, “perbrominated” or “perfluorinated” is to combine with the maximum amount of fluorine especially in place of hydrogen.

[0013] As used herein, “high pressure” means higher than 1 atm, and includes all typical downhole pressures (e.g. up to and even beyond 25,000 psi).

[0014] As used herein, a “high temperature” means reservoir temperatures which are greater than 100 °F, typically about 200-400 °F in a reservoir.

[0015] As used herein “live oil” is oil containing dissolved gas in solution that may be released from the oil solution at surface conditions. Live oil must be handled and pumped under closely controlled conditions to minimize the risk of explosion or fire.

[0016] As used herein “dead oil” is oil that has been flashed to STP or ambient conditions at the surface and no longer containing very much dissolved gas.

[0017] As used herein, “bubblepoint” or “bubble-point pressure” is defined as the temperature and pressure at which gas begins to break out of an under saturated oil and form a free gas phase in the matrix or a gas cap. In layman’s terms it may be thought of as the pressure at which the first bubble of gas appears at a specific temperature. The phase diagram of typical black oils shows that the bubble-point pressure could be different at different temperatures and pressures dependent upon many factors including gas concentration and oil composition. Often the oil is saturated with gas when discovered, meaning that the oil is holding all the gas it can at the reservoir temperature and pressure, and that it is at its bubblepoint. Occasionally, the oil will be undersaturated. In this case, as the pressure is lowered, the pressure at which the first gas begins to evolve from the oil is defined as the bubblepoint. In the petroleum industry, if bubble-point pressure value is mentioned without reference to a particular temperature, the temperature is implicitly assumed to be the reservoir temperature.

[0018] As used herein, “reservoir T” or “reservoir P” or “reservoir TP” or “RTP” refer to reservoir temperature, reservoir pressure, or reservoir temperature and pressure conditions at the depth the hydrocarbon is found at. If the depth of the play is significant, an average RTP within the play can be used.

[0019] As used herein, “standard TP” or “STP” is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 105 Pa (100 kPa, 1 bar). Standard temperature and pressure in the oil industry may vary, however, as standard temperature is 15 °C and pressure may vary by state regulations. Further, many use ambient conditions in the lab instead as providing for easier experiments.

[0020] As used herein, “saturation pressure” is the pressure at a given temperature where the fluid goes into the two-phase region (from a one-phase region). The two-phase region may be influenced by gas concentration and oil composition at a given reservoir temperature and pressure. The vapor pressure of a liquid can be defined as the saturation pressure at ambient temperature. Inversely, the saturation pressure of a gas condensate is its dewpoint pressure. Saturation pressure is equivalent to bubble point pressure at a given pressure and temperature below the critical point. At temperatures above the critical point, the saturation pressure is equivalent to dew point until a single phase gas reservoir is reached at an upper temperature.

[0021] As used herein, “zero-flash” refers to flashing a live oil sample to standard conditions in a closed loop system so that nothing escapes.

[0022] The use of the word “a” or “an” in the claims or the specification means one or more than one, unless the context dictates otherwise.

[0023] The term “about” means the stated value plus or minus the margin of error of measurement or plus or minus 10% if no method of measurement is indicated.

[0024] The use of the term “or” in the claims is used to mean “and / or” unless explicitly indicated to refer to alternatives only or if the alternatives are mutually exclusive.

[0025] The terms “comprise”, “have”, “include” and “contain” (and their variants) are open-ended linking verbs and allow the addition of other elements when used in a claim.

[0026] The phrase “consisting of’ is closed, and excludes all additional elements.

[0027] The phrase “consisting essentially of’ excludes additional material elements, but allows the inclusions of non-material elements that do not substantially change the nature of the invention.

[0028] Any claim or claim element introduced with the open transition term “comprising,” may also be narrowed to use the phrases “consisting essentially of’ or “consisting of,” and vice versa. However, the entirety of claim language is not repeated verbatim in the interest of brevity herein.

[0029] The following abbreviations may be used herein: ABBREVIATION TERM API American Petroleum Institute BHP bottom-hole pressure CCE Constant composition expansion, aka constant mass expansion (CME). The bubble point pressure is determined by an experiment called the CCE. The device used to perform this experiment is the PVT cell. CCE test is performed on a sample in a high pressure cell fitted with a glass window. In this test the cell pressure is reduced in steps and the pressure at which the first sign of gas bubbles is observed is recorded as bubble-point pressure for the oil samples and the first sign of liquid droplets is ABBREVIATION TERM recorded as the dew-point pressure for the gas condensate samples. FC-40 a commercial inert fluid used to store cores, also known as FLUORINERT™ Not actually inert as it dissolves lighter hydrocarbons. FID Flame Ionization detector GC Gas chromatography GOR Gas to oil ratio GTM Gas transient model HPHT High pressure, high temperature—suitable for RTP conditions. HPLC High pressure liquid chromatography P Pressure RTP Reservoir Temperature & Pressure STP Standard Temperature & Pressure TAN Total acid number TP Temperature & Pressure T Temperature PVT cell A pressure, volume, temperature cell—a vessel capable of assay at RTP. BRIEF DESCRIPTION OF THE DRAWINGS

[0030] FIG. 1.1. CCE experiment on live oil at 303 °F. Relative volume as a function of pressure.

[0031] FIG. 1.2. CCE experiment on live oil at 303 °F. Oil compressibility as a function of pressure.

[0032] FIG. 2.1. CCE experiment of live oil / FC-40 fluid system at 303 °F. Relative volume as a function of pressure.

[0033] FIG. 2.2. CCE experiment of live oil / FC-40 fluid system at 303 °F. Oil / FC-40 compressibility as a function of pressure.

[0034] FIG 3. PICTURE 1: Oil before contact with FC-40.

[0035] FIG. 4. PICTURE 2: Initial contact with FC-40.

[0036] FIG. 5. PICTURE 3: Oil / FC-40 initial interface (no mixing).

[0037] FIG. 6. PICTURE 4: Oil / FC-40 dispersion layer (no mechanical mixing).

[0038] FIG. 7. PICTURE 5: Oil / FC-40 dispersion layer 2 (no mechanical mixing).

[0039] FIG. 8. PICTURE 6: Initiate mechanical mixing.

[0040] FIG. 9. PICTURE 7: Oil / FC-40 interface fluid change during mechanical mixing.

[0041] FIG. 10. PICTURE 8: Oil / FC-40 interface after aging overnight.

[0042] FIG. 11. PICTURE 9: Oil / FC-40 interface at saturation pressure.

[0043] FIG. 12. PICTURE 10: Oil / gas interface at saturation pressure.

[0044] FIG. 13. PICTURE 11: FC-40 after flashing from cell. DETAILED DESCRIPTION OF THE DISCLOSURE

[0045] To further advance our sealed cell development work, an experiment was devised to understand liquid and gas phase hydrocarbon solubilities in FC-40 (FLUORINERT™). Previous accepted industry standards for oil solubilities in FC-40 (e.g., none) were established at atmospheric temperature and pressure conditions. However, due to the nature of the sealed cell acquisition and laboratory procedures, FC-40, reservoir samples and associated hydrocarbons are in contact with each other at pressures and temperatures in great excess of those used to establish the original solubility standards. Thus, we suspected that the prior data is not accurate.

[0046] To understand the temperature and pressure impact on hydrocarbon solubilities in FC-40 a number of tests at RTP were conducted, as described below. In these experiments, Eagle Ford Hunsaker B9 live oil samples with reconditioned FC-40 fluid were studied at RTP of this play (5000 psia, 303 °F). In general, the live oil is characterized before and after equilibration with FC-540 or other test fluid, and changes in the characterization indicate that the test fluid is not inert. In particular, one might see changes in density, components, bubble point, dew point and the like. In this instance, we determined that FC-40 is not inert—solubilizing some of the lighter oil components and thus changing each of these parameters.

[0047] It is common to use recycled FC-40 in the coring apparatus due to the high expense of FC-40 and in reliance on the assumption that it is inert. Depending on the program, we have requested virgin FC-40 to be used, but our initial proof of concept work was performed with used FC-40. Preparing the FC-40 as described herein ensures if the experiment is undertaken with recycled fluids the full solubility of oil in the FC-40 is measured.

[0048] FC-40 fluid obtained from previous pressure core projects was subjected to vacuum and heat overnight to remove any previously solubilized hydrocarbon components. The FC-40 fluids from different core samples were combined and then analyzed for chemical constituency with gas chromatography with carbon disulfide (CS2) solvent with an internal standard.

[0049] To obtain the composition of live oil, we flash to ambient conditions, measure the gas, the dead oil composition, and the gas to oil ratio (GOR) and calculate the live oil composition from that by adding the gas components back in. The same can be done after equilibration of test fluid, such as FC-40, at RTP and the results compared to determine if the test fluid is indeed inert.

[0050] The bubble point pressure is determined by an experiment called the constant composition expansion or CCE. The CCE is done on the live oil before and after RTP equilibration with FC-40. If FC-40 is truly inert, the bubble point should not change. To perform a CCE, a known volume of live oil from a cylinder is transferred to a PVT cell. The live oil or live oil and FC-40 mixture are stabilized for 24 hours at RTP conditions. Then, an isothermal depressurization of at least 9 pressure steps is undertaken above saturation pressure. Below the bubble point pressure, a similar isothermal depressurization down to maximum expansion of the PVT cell volume is conducted. Cell volume is recorded at each pressure step. Saturation pressure is determined visually (herein we used bubble point) and graphically from the CCE experiment.

[0051] In more detail, these experiments are described as follows: FC-40 AND LIVE OIL MIXTURE STUDY

[0052] The following experimental procedures were followed, and corresponding results are included herein:

[0053] 1. Measure the composition of live oil (including weight % of the components) and density (HPHT densitometer) at 5000 psi and 303 °F (RTP).

[0054] 2. Perform a CCE test to determine bubble point of live oil at RTP.

[0055] 3. Flash the live oil and measure the density of the remaining oil.

[0056] 4. Clean the cell and charge it with 310 cc of reconditioned FC-40 and 60-cc live oil.

[0057] 5. Mix.

[0058] 6. Equilibrate the mixture at RTP.

[0059] 7. Measure the volume of the oil phase and FC-40 phase at RTP.

[0060] 8. Perform another CCE experiment to determine bubble point of the equilibrated FC-40 / oil system at RTP.

[0061] 9. Displace the FC-40 and flash a portion of the remaining oil phase to STP or ambient conditions to measure amount and composition of gas that leaves solution.

[0062] 10. Displace the remainder of the oil phase and measure density (HPHT densitometer) and composition of the oil at STP.

[0063] The reservoir fluid composition is reported in Table 1. It had a bubble point of 3547 psia at 303 °F (Table 2). Constant composition expansion at 303 °F indicated a fluid density of 0.5302 g / cc at the saturation pressure (bubble point) of 3547 psia (Table 3), and average total compressibility of 4.227 x 10'5 psi'1 (Table 4). Table 5 reports a constant composition expansion experiment performed on the reservoir fluid / FC-40 mix where a bubblepoint of 617 psia (shown in Table 6) at 303 °F was measured. The oil phase volume shrank from 60 cc at 5015 psig to 20.30 cc after mixing. FIG. 4-7 (Pictures 2-5) show the rapid diffusion of the oil into the FC-40 phase before mixing.

[0064] The 20.3 cc of oil remaining was displaced and its composition measured as reported in Table 7. The FC-40 was displaced and flashed to ambient conditions; a gas phase was recovered and its composition measured and an oil phase that separated from the FC-40 also had its composition determined.

[0065] The composition of the oil components that solubilized into the FC-40 was estimated in Table 8 by combining the gas and oil phases that came out of the FC-40 at ambient conditions by material balance. The material balance around the entire experiment (Table 9) indicates that the live oil composition reported in Table 8 should have more light ends. This is probably due to the fact that light hydrocarbons have significant solubility in FC-40 even at atmospheric conditions. FIG. 13 confirms that the light hydrocarbons are more soluble in FC-40, leaving the heavier components in the oil phase.

[0066] Since the current standard so-called “inert” fluid (FC-40) (Table 10) removes light hydrocarbons, it would be beneficial to find a better inert fluid for downhole uses at RTP. The ideal fluid should be dense, and inert to hydrocarbons, as well as not preferentially solubilize any of the hydrocarbon components. In addition, the solution should be reasonably safe to use, and not contribute to environmental degradation or present safety hazards.

[0067] To that end, we will test silicon-based molecules that are fully substituted with fluorine, or silicon-based compounds with hydrophobic R groups, including siloxanes (SiH3(OSiH2)nOSiH3), or silicones.

[0068] Silicone fluids can be discussed in two categories: inert fluids and functional fluids. Polydialkyl-, arylalkyl- and fluoroalkylsiloxane polymers and co-polymers, carrying no reactive (under-the-use conditions) groups, belong to the first category and may be tested as described herein.

[0069] A possible test fluid is (CH3)3-Si-O-Si(CH3)2-O-Si(CH3)(R)-O-Si(CH3)3 where (R) is hydrophobic.

[0070] Another test fluid might be a fluorosyl: W CkA / .....i ? s H i s ? CHHsj 0             C^i 'CHs j > s > s j •' j ■ J ■ § C A         V«« 0 ® > §

[0071] In fact, many fluorosyls are available for testing herein, including Fluorosil 2010, Fluorosil H418, Fluorosil JI5, Fluorosil LI 18, Fluorosil OH C7-F, Silwax F, Fluorosil OH ACR C7-F, Fluorosil TFP 1000, Fluorosil TFP 10,000, Fluorosil TFP D7, and the like.

[0072] High Temperature Silicones such as Dynalene 600 or SYLTHERM (a polydimethylsiloxane liquid) may also be tested.

[0073] Another option   is phenylsiloxane-dimethylsiloxane copolymer and diphenylsiloxane-dimethylsiloxane copolymers. As phenyl groups replace methyl groups in a polysiloxane, several changes occur. Oxidation resistance, thermal stability, and shear resistance are enhanced.

[0074] Modified silicones that have a higher density and chemical resistance and are potential candidates include: ] FL-45 iso OS X-22-S21 * .$ ,■ j ,              -. * ■» taaS sssssfesteBicss .......—h           : Pssjss5ss5i(i?y iso -CHsCHsCFs FL-180-186¾¾ FL UT 1 «ts i FL1«-^.00Ces 455) -¾ i . ' Polysther-mcdified / / $$^S$!& / $ / / / £$^^^ / / / / / / / / / / ^&&$: / $ RMS? A. 73 ■L&g 1.433      12 24:-' sohjgSB ®SiSf 54544:3:1: Lew sifted psSWSbilSy' 1.883 1.448 ? ................ .......433 »8 .......rsa 1.433 1.433 ..........1g.. 18 is? 1.&7 1.45S 12 KMiSA 1XS 1.451 10 so _________ 1.88 1.428 4 RF-O3 1X1 1.444 14 KM42 1.1¾ 1.44g 12 1.&1 1.442 14 RSMX4 1X2 1.44g 11 rx-slsq w ixs 1.41? 4 R.F-XS’CM ?s 1X5 1..4S1 10 xoi 1X3 1.448 0 -mCAOMCsHsOMT RFC®“1 RA R.s~ $ 1X? LLv i 54 i L = * £ ................ Phenyf-tnodifieti / / / / / / / &^^ / / / / / ^ / / / / / : / / $j^;X: / / / : : / / / $ / $W / / / : / / / / S; / ifes / / / / / illoBiltl KF-SO-IOScs ISO &.58S 1.42? KF-SO^acs 388 8jm 1.42? ■m irc^" ..sU- nJl. <X..n. RF-^-tSaOes 1XS8 i« 1.42? f^A..   n. kp-^-3s£mes 090 14» 1.42? r < twtsy * .ofc CHS RF-S3 1.48S ISSISS-SSWK SsSSSiSS KF-34 486 IX? 1X88 x / svws « IX? i.m RF-S4SS 888 IX? 1 '4>-

[0075] Brominated hydrocarbons may also work, and mercury compounds or mercury containing mixes in the manner similar to that described herein. Any of the above described or similar compounds that test as inert in the herein described tests will be used as core sampling inert fluids and / or core storage inert fluids.

[0076] Suitable compounds may not be 100% inert, but the ideal solution would be 95% inert or better for the time it takes to collect core samples and test them—e.g., no more than 5% change in content. Thus, the inert fluid should be at least 95% inert when tested with core at RTP for at least 6 hours, preferably at least 12, or even 24, 36 or 48 hours. Even more preferred is a 96, 97, 98, or 99% inertness. Table 1 Reservoir Fluid Comssosition Component Flashed Gas Molecular Weight Specife Gravity Reservoir Flttid Mole % ............. 8¾ ........wt........ % Mde % Wt % 0.237 8.600 oooo 28.01 0=818-3 3.171 0.067 Carbon Cioade CG> 1.Q2S ¢..009 9.680 44.31 >3.8278 0,741 3.453 Hydra^n SuSpnsfe h5s 0.003 8.G0O 0.000 34.08 0.7»3 B.BBG 0.000 Keferse Ci 68.732 ¢..074 0.986 16,05 0.3888 49.593 11.161 Ethane Ci 14.516 0.335 0,551 30.07 0.3560 :10,562 4.461 Propane C> S.Q84 ¢.701 0.151 4446 0.5613 5.969 3,698 i-Stitarie !_L^ 1.348 0.325 0.-399 53.12 ■3.5570 1,057 8.863 p-Butane n-C^ 2.879 1.365 0,413 58..12 8.5793 2.457 2.086 ^Pentane i<S 1.198 ■.425 0.535 72.15 3.6200 1,256 3.273 :':-P&nt3;F:e n-C, 0.=939 2.217 0,832 72.15 0.626-3 1.332 1.850 Hexanes cs 9.733 5.727 2,504 84..0:} 8.6933 2.136 2.486 Q 8.182 8,092 3.957 95.08 3.7270 2361 3.151 Octanes £s 0.=196 16.632 5,921 187.00 8.7493 3.939 4.588 Duanes C, 6.091 ¢,451 5.953 121.08 3.7680 4.538 Decanes t-xi 0.007 7.451 5.274 135.00 0,7320 2,331 3.977 Lfrsde<»F^s C;-c 6.069 5.045 4.611 149.08 0.7938 1.557 3.467 Dodecanes Qj 0.888 4.795 4.-369 163.00 88040 1337 3,868 Tsidecsnes Cji 4.593 4.287 176 00 8.8153 1,230 3.164 Tetedecpnes Q* 3,552 3.929 191.68 3.S268 1,W1 2.955 P^tadecanes. >*-15 3.579 3055 287..00 8=0353 3.997 2.900 Heaedecanes CiS 2.005 3.345 221.99 3.34301 0,818 2.514 Cry 2.617 3.223 237.00 8,0513 3.729 2.428 Octadecases ciS 2.,468 3.199 249.08 3.3568 8.588 2.406 ^cnadeeanes --½ 3.361 3,125 261.00 3.8610 0,641 2.358 Ek£jS3?5«S: £.¾ 1.897 2.715 275.. 00 0.8663 8.529 2.042 heneicosanes Cli 1.716 2.584 239.88 3.3718 0,479 1.943 Dssosanes '-li 1.485 2 142 383,00 8=8763 3.414 1.761 Tricosanes c3 1.354 2.234 317.08 3.3818 0,877 1.536 T etfacosanes Cy 1.238 2.102 331.00 8,885-9 3.346 1.581 Pentacosanes 1.035 1.949 345.88 3.3888 8.302 3.466 Hexscosanes Cis 1,011 1.398 359.38 3.8928 0,282 1.421 Heptacosanes Ci; 6.914 1,775 373,00 8.8959 3.255 1.335 Qctacosanes C® ¢,3.34 1.688 387.88 3.3998 8.232 1.264 Hopacosanes £^ 6.750 1.562 488,88 8.9829 0,269 1,174 Trtcc^isrses C.w ¢.665 1.436 415.00 3.9653 8.185 1.080 Hentriacontanes ' :: ¢..579 1.292 429.08 3.9099 0,161 8.972 Dstrfecontsnes Qi 6.550 1.269 443..00 8.9123 8.153 0.9.5.5 TnfriacGntanes c® ¢,499 1.187 457.38 3.9158 0,1.39 3.39-3 Tebatriacontees C« 6.483 1,197 471,00 8.917-3 3.136 0.900 f^tstcacentanes Css ¢,404 1.828 485.88 3.9280 0.11.3 3.767 Hexatlaeontanes plus £^< 3.693 12.494 658,88 8 / 5913 1,329 9,395 iGO.bo '108.043 ......100.00"" .....ioOij"" Motobr Weight 24.47 19Z13 71.19 Compositional Grouping and Pius Fraction Properties Group Md% wt% HW Density C7+ 24.,.76 72.16 20749 0.8461    : C12+ 12.92 52.41 255.79 0,8758 C20+ 534 30.63 4007 0,9195 O0+ 1.92 14.96 555.73 0,3605    : 06+ L03 9.40 650.00 0,9913 TABLE 2 Main PVT Results TEST CONDITIONS | Pressure                                      5000 psia | TemperattB-e:                                303.0 F CONSTANT COMPOSITION EXPANSION @ 303.8 F | Saturation Pressure {Bobble Point)          3547.31 psa CompressMty 'ix Saturation Pressure..........4.2274E-05 psia SEPARATOR FLUID FLASH TEST TO AMBIENT CONDITIONS At Saturation Pressure Oil FonTsation Volume Factor 2.0052 res.bbl / STB Hash Gas-Oil Ratio At Tank Conditions 1432.89 scf / STB Residual Oil Density 0.7996 aCiT3 API Gravity 45.47 Measured MW 195.30 CylinderTftirabsr: 832808 Volume of oil left: 300 cc at 5000 pss slid 3 53 F TABLE 3 Constant Coni position Expansion @ 393.OF Pressure ReiativeVokime [1] Y-Fuaction [2] Fluid Density Liquid Volume vliq / vlm bMbl 7015 0.905’3 0.585.3 6515 0.9146 0.5797 6015 0.9244 0.5736 5515 0.9354 0.5668 5015 119480 0.5593 4515 0.9627 0.5508 4015 0.9802 0.5409 1.&M8 8.5302 100.808 337’3 1.0251 1.9791 94.430 3211 1.9541 1.9339 90.836 304.3 1.0877 1.8886 88.019 2875 1.1268 1.8434 85.321 2707 1.1725 1.7982 82.849 2539 1..2285 1.7530 80.754 2371 1.2904 1.7077 78.589 2283 1.3669 1.8625 76.583 2:535 1...4593 1.5173 74.507 1867 1...5723 1.5721 72.604 1694 1.7123 1.5268 70.896 1531 1.8886 1.4818 69.257 1383 2.1153 1.4364 67.744 1195 2...4144 1.3912 65.998 1027 2.822:5 1.3459 64.600 [1] Volume at indicated pressure per volume at satisatian pressure [2] Y Function = ((fW-P) / Py(Reiatwe Volume - 1} [3] Measured by HPHT detisiometer Psat - Saturate Pressure TABLE 4 Constant Composmon Expansion @ 303.0F Oil CompressihiJity as a Function of Pressure Pressure Range            ; Average From To Total Compressibility (psia) (psia)        | (psi’1) 7015 6515 1.303E-O5 6515 ;             60IS 2.111E-0S 6015 5515        | 2.357E-05 5515 5015        § 2.65 ZE-05 5015 4515        i 3.tU9E-ns 4515 4015        | L VO; -(>5 3547 Psat «276-05 TABLE 5 Constant Composition Expansion of Live Oit / fC-40 Fluid System @ 303.8F Pressure Total Volume cc RelabveVoluine [1] Y-Fu fiction [2] Bas Knase Volume UB PHftSe Volume cc Sil 5 374.(51 0.8822 20.39 481S 3SU. 2.5 0.59*39 20.61 3015 387.90 0.9149 2(1.64 2515 392.72 0.9263 20.54 2015 3$ 8,3 6 0.9396 20.54 1515 405.22 0.9558 20..59 1015 414.00 0 / / 765- 20.67 617 Psat 1,8089 »» &0-6 427.51 1.6084 2.165 6.444 19.79 595 431.73 1.0183 2.017 94yS 19.51 584 435.55 1.0284 1.991 13.961 19.23 573 440.30 1.0385 1.992 20,549 18.96 56-2 445.19 1.0501 1.954 28.527 18.78 551 4b 1,63 1,0653 1.835 33.881 18.86 540 .16 1.8807 1.767 40.2V 18.33 529 464.79 1.^63 1.727 47.793 19.91 518 471.51 1.1122 1.704 56.762 19.08 507 478.70 1.1291 1.68« 63.983 19.29 456 486.12 1,1466 1.-654 70.907 19.55 485 493.67 1.1644 1.655 78.589 19.81 474 501.32 1.1825 1.653 87.084 20.07 403 508.66 1.1998 1.665 95.&8W 20.00 452 514.58 1.2138 1.798 103.248 18.80 [1] Volume at im seated pressure per volume at saturation pressure [2] Y Function = .{Psat-PJ / PXRelaSve Volume - 1) Psat - Saturation Pressure Loading formation (5W sag & 383 aFJ Reservoir cc                     6(1.00 FC--0, cc 314.011 TABLE & Constant Composition Expansion of Live OiI / FC-40 Fluid System @ 303.0F Live OII / F04O Fluid System Compressibility as a Function of Pressure Pressure Range Average Total Compressibility From To (psia) (psia) 5015 4015 1.S55E-05 4413 3015 12391E-05 3015 25 IS Z468E-05 2515 2015 Z854E-05 2015 ISIS 3.417E-05 1515 1015 4.286E-05 1015 £17 Psat 5^73E-O5 Tabla 7 Oil Phase           { Aha? b-hkIe^     FC-40 ws the PVT ce^} .................................. ............H^Sg........... M^eas.^ar ............08 Pfese Male 44 Weight Srawty s J4c4e Wt 4¾ .....................r- 2.918 MES 8.930 28.83 3.81® ’ 0.8S6 9®9 Csiiss-s M& ak 9,005 W 0.308 44.01 £^527^ $ 9199 9S3S Hp&aoen StJpkide H;S S;®0 M® 0.930 34.05 9,7969 s 9®9 y,€W JSsjwe 9 66.763 MIS MSI 16.85 938® * 15.742 1.165 Share C.< 15.474 3,191 9021 35.87 93S® ; 4.G2S 9559 P-ss&ane £> S.G75 9651 0..134 44.13 2,4® 9480 1.850 &28S 8.961 58.12 8,5578 s 0.469 9126 a^sstatw 2.188 1,338 8.21S 58.12 S.57S5 s 1.384 9353 £4&TtiK» 8,603 9772 0,231 72.15 &52DG $ 5,732 9244 ■>-Panran§ r-Cs 5,572 1.1® 0.398 73.15 &.S® s 0,®3 §337 Ct 3.333 2.377 •2» S4.Q3 959® s 1.909 9739 ^aptafss s,m 3,547 S21S 95..® 0,7273 s 3,737 1,199 <Kt=res & 9,945 0 466 2.583 187.08 97456 s 4,953 2.444 iSmsK^es Cs 4..034 2.111 121.08 9^SS s 3,691 LOSS Ss-Sf-SS. c® S.333 4,317 2.124 136,83 97S3S * 3.351 2,073 <.?™fec®TSS Cr 9,000 3,844 2.383 145.® S.7938 s 2,954 2,529 iWstaftas C^ 6,™ 3.535 2..086 163.® S.S&® 5 2,®5 2.S33 Ttidecaines c« 3v7S5 2.410 176C8 $ 2.893 .2,348 TeKafecagies Q.< 3.545 19s.-® 0,32® s 2,706 2,454 b<S: 3.675 .2,.752 267.® 6.S3® s 2,S® 2,651 $^ads£ii£!s$ 3,-332 2.-664 221.® 9S43S s 2,SI? LSSS Jfegtedeca?^- 9- 3.256 2.791 237.® $ 2.450 2.723 <)d&£feciSf5&S: €;> 3,275 2,655 34S-® 0,85® s 2,504 2,875 ifesasiecanes ■’-M 3396 3.152 261.® 2sS52 987$ EcsHarfss 0» 2.984 2.059 275® S.S668 s 2.252 2.093 Cft 2,®4 .3,.616 269,® 9871S i 2.205 3,S3® CsSEQ-SafSS. i<E<55 2,518 3S3,® 170?® s 2,029 2,535 Tdiosanes 8-^ 2.325- 2.531 317.® &-SS£G s 3.,954 TfSjaZQSK'SSS c< 2422 2,939 331.® 93SS0 ’ 1.SS2 2,826 Css ZJS2 ZSll 345.® 0,®® s 1,722 2,759 HesaoiEwf^s £.. 2.124 .2,638 355.® 0,0928 s 1,671 2,760 ^e^tassH^ras 2.353 2.778 373® 989® s 1,^9 2.6® 9s 1,925 2,885 3S7.® 98500 s L472 2,625 c„ 1,775 2,5S3 «S.® 9®2S s 1.357 2,533 T^ior^anes 8^ 1.645 2.476 415® 9®® s 1,2® 2.412 Q> 1.459 2.263 429.® 9®?® ’ 1.134 2.235 DcS&aaXTSarSS cs 1,425 2,285 44.3,® &SL2S $ 1^88 £225 T'ivissx^&fs®. 1,257 2444 457® 0,9158 s 5,®2 2,®9 TefratnasstSras Cs» 1,294 2.204 471,® 9917S s 0.959 2.143 Psn^feCJST&fSS Qs 1,175 2,962 485,® 992® s 3,898 2.909 aka 10,786- 25,174 656,® 99913 s 5183 24.520 """ W«.sg Cafe feted MW 23,53 275,43 i                     216,06 CtanposftiGHaiS Srosspinss and Plus FtaetioR Sre^sefties MW     BeraSty £74- ..........71»..... 95.55...... 299E7 8.8882 £122+ 53.93 06,97 324.9? assss £23+- 33,64 6538 43MS B.92S& £30+ 14..53 S1.S6 0.9635 C36+ 916 34.53 659® 8.9913 Zero R^fe fesafe ¢330- psig 3. 303F1 Live <x; da^ity; gteo ■SJBS83- ®3R, sc&sfe 125.82 Flashed ok densSy. 9S42& Fished 5®¥ 287.® Ya^e S Fkase Se&ftsws hi FC-4G £&n^3s$isfs nnxing with F£>4® PVTc^) J Rashed Sas| ^32^5 Gi3 J^cseasisr feiit S$>ecs&e Lf<^ er $ f^ofe : 9¾ J Hs^e A»£ Msfe % .........1¾ 44: ■ : N. S,SBS aas &s@e 2&SJ «.«©> B.®1 &=ss CisIX'^D^^e      : vX S 1.017 O.0SG ¢.373 44G£ &S3?& W 0920 i                                                                                                                                                      : 90® s,a« as® 34^8 0795® acec ossa Cx j S5<727 ■ aoss ascE 18, ¢5 OS® §3.153 la»? ■                                                                                                   ;i c j £4149 ai32 as® 3aa? &33S& : 13.233 0756 ScsJi.'®                 ■: C, J 7.522 ass. &i® 44.18 asms asi OS83 S-EiSSK             j u>x% LSI as? &132 58.13 as?B 1864 is473 ; ^-B&ars              ■; n-£s 3.53« 132S &496 SS.12 &5T38 1372 5x234 ; ^Pentisrje                  ’ HLj: 3343 73.15 ass® IBM 1.736 ■ i^Bf-tane              5 !>Ck j     & 5S8 | 2<lvS &S7S 7235 aS250 1.82S 1.769 &9SS!«B            J Q S,SJ3 5.5® as@e MOB S4866 1.368 2,?5S ; Bepaws Vv j     §.225 as? 3.235 ®,Q8 •a-73^ 1.378 Ol® <ssanes             j Q 5.184 IS. 37? 11.1® 187.02 O7®0 Z..313 0634 ! & M93 11,577 S.S17 mas &76S8 2.,517 4x@52 P^KjeS’^K                 ' G» as® 3.^73 8,23-3 13S.® MS3B 2.3® 4242 ■ ^■^aca-’^s             ’ C, J &5B3 7.5&J 7.254 14a® 0,7333 1,842 .3.887 : :J>xfeGir«S              > ca S.»>3 5.8ES &1S4 153,® aso® B.®§ 3.129 Tsissca'ss            J S.7* 6.3QS 178.® osiss 3.733. 3x.§^2 Y*Tj                         : kv 4.225 5.194 191,® asss as® Psr&KSaczsfsaE           ■; £,^ 1555 4.73S S17.® as» «,4® 2,4® : Hscafecsses          ’ '^■S; > : Z553 3> 231.® a®438 &354 LS19 G» 2^8 3>3§8 23?.® ass® B.3S3 £..?1Z ■ OsiadiKafses.            i c!S 1.93S 3.133 24W ass® 0368 L-57S ■ ttoiadecarss         j C-\ 2.685 2^797 261® assis 3.238 t.47? : : 1..S4 71337 375.® asffia «174 1,1.37 ^r^asarsss        : USS 1.968 358.® as7ia 0. ;45 1^1 ; :&c<<s8n®s             ; Css Q^S® 1.8S 35&® asss &1K §»S33 T^csseses           j Cs; ajis 1,445 317.® ass® as® 0733 : ! assa 1,255 331,® a®i &S3S ■                                                                          J a«3 l.B?l 345.® ass® B.» ^54^ : B&SKSSieSfiS            :! 8^14 3357 35^00 3.®? O4S7 ^feCSSSarffiS.          :i 8.353 WB 3?a® w® WS' 8431 : ik^^arsss          : Css ass &719 3S7,® assse as® 0366 : $k^33S3rt®S          J Css B.2® a&M 40&® a.®® 3.684 Ifkcsteses           ■: c» a233 415.® 7 0Ss «.8K 02® 0,159 aw 433.® 090® M23 •>Xi^4 ; L^^c^tanss      ; Css 0.1:3 a43? 443® 09233 aszi §x222 Css &1Z3 C$37? 457.® 0,9153 aois 0.193 : T€5*^£7F^rieS     ! Css aw 0,355 471,® ¢3133 3.817 0186 vX B.156 &333 455,® ass® 3.815 0169 :                         S&S ■: ^•Sa 8.778 2.235 6®® assn 0186 1,837 i....................r iSOJ isois iooaaaij W.O Cakslaled MW »32 | 155.35 ^L9?S irfflXElMfiQ: 3&d     FWKSfiOC- PWCrtSSS                    I iSfcouss Ws^fe v^tS>c. MW DsFi^tV j CT* S,5S 4&SB 164,13 &S11S 1 ■        C12+ •05 ^ZvZti 385,31 &S465 1 CSH 1.6® 3.42 364,35 O902S c®+ 0,23 2,92 548.45 0,5649 C36+ an 1,.64 S5&S6 0580 [ Zero Ffes^          ^¾¾ & W| '^r\5s^'....................."........wliif Fis-e^j-sS ^isc          gz-ra      1.353^ * Lh^ssJ is q? kw ana FC-43 * FC4G derail at STP TABLE 9 Material Balance Cslcula&sn Basils for Table S INITIAL VOLUMETRIC CONDITIONS PFesswe: TeiTipersfoe: 5015 p-ssa 303.0 F Resawr tai votae; Ressf^r ftasd density: 60,80 sc 0,5533 ^cc 0,4714 mote ^placed ^ohoe: Displaced density: 20.30 ££ M8S3 8,0832 mofe 0« phase in scfation * FC-4& 353,71 cc 0,3532 -wle OIL PHASE IN; SOLUTION 4 FC-40 FLASH TEST VOLUI4EFR3CS Total flashed vcfeme: 20.,84 cc 5015 pste & 303 F Gas v^ume co^ectedt 467.51 o: 14,5% pste S. SO F Gas ire          (scsletd) 7333.78^ -- sil sa scteiaa by as^ssiai baLsa.ee 0.0533 rssaie Tsbte M FC-40 Prepasatfsn W<sfeculaf ■Weight 8^®<sfc Mute -¾ Wt ...........%..........; H&oge® w 8,®S 8,808 2S,m MX8® Gates Dfeids 0¾ 3,.300 8.088 44.01 0,8278 Hu MSB 0,808 34.0S 8.7SSS Haters A. S,®0 8,^ 16,85 5» A 8.042 8,81? 33.87 8.35® tapa ne A 8>033 8,818 44,18 4.5010 s-&sSassg i-Q 3..800 8,808 53.12 8.557® St-BtiSaSS® 8,® 0,800 S8.S2 M?® >A 0,®O 8,083 72,15 :0,0300 us4»e®af» 8,0® 0,800 72.15 8,52® Carbc® fteBde £5S 99,810 99.844 76,13 fet'anes A 8,880 8,808 84.:38 8,8» H-ste-ss A 3..800 8,808 95,88 8.727S Coarses A 8.018 0,820 187,:08 8.74® ftoasses A 3.800 8,883 121,33 0,7» QSCSfSS L'jg. 8.088 0,800 138,88 8.?®® JWeeasses 8,888 8,808 143,® 0,7930 Qssfecsses As 8,808 8,888 183.00 8,S0® Tskfearses As 8,888 8,800 176,:08 0,01® Tetsadecanes 3,800 8.008 191,® 0,S3® PesSadecases As 8,083 0,800 207,08 8,03® He^adecarHS A* 0,838 MBS 221,® 0,8438 HesSi-desii^s As 8.088 0,800 237,08 8,05® OcSidesames As 8,838 8,808 249,® 8,85® ^msadecases As 8,800 8,808 251.® 8,®1S As 8,388 8,800 2.75,08 8.0&® fessksssasses As 0,888 8,W 2®,® 0,8718 ©sc-osarse A? 8,083 0,800 383,08 8,07® Trfcssasses As 8,808 8,808 31?,® 0,®18 Tetsacasanes As 8,800 8,808 331,00 8,®® feSasssasss Css 8,888 8,808 345,® 8» fet'acssarsgs A® 3,800 8.008 359,® 0,8928 ^gtstossrses A? 8,0^ 0,800 373,08 8,09® OsSaossaaeB As 0,800 MBS 387.® 0,®® tfej^assss^ As 8,800 8,SBS 4®,® 0,®38 Tsteteraas A> 8,808 8,808 415,® 8.®® HssstesKSanes A: 8,888 8,800 429,® 8,®® ©tslte«B®a?je£ As 3,800 8.008 443,® 8,8138 TrfesstorSs^es As 8,883 0,880 457,08 8,01® Telra&sacKsSaaas A. 0,800 MBS 471,® 0,8138 PsKSastesnsanes As 8,808 0,880 «5,® 8.82® Hssatfia£3B!&Ktes ^is As., 8,808 8,808 8.5513 ">>>>>>>>>>>>>>>>> ssssssss^s^s^s^ >>>>>>>>>>>>>>>>>>>>>>>>>>>>>> Weight of       Used Sisndssrd Added 8.84® 0.8005 9 g

Claims

PCT CLAIMS1) A method of assaying a test fluid for collecting reservoir core samples at reservoir temperature and pressure (RTP) and determining if said test fluid is inert at RTP, said method comprising:a) assaying live oil to generate a first dataset using methods comprising at least one of:i) determining a weight contribution of components of said live oil;ii) determining a bubble point of said live oil;iii) determining a density of a remaining oil when said live oil is flashed to STP or ambient conditions; oriv) determining a weight contribution of gaseous components flashed from said live oil;v) determining total acid number (TAN), metal content, viscosity, asphaltene content, C7 content; nitrogen content, water content, carbon content, total contents; wax content; carbon residue content, conductivity, pour point, density@15°C; salt content, sediment content, specific gravity; light end hydrocarbon content; mercaptan content; hydrogen content, total sulfur, hydrogen sulfide content or vapor pressure of said hydrocarbon phase or said remaining hydrocarbon phase;b) assaying live oil plus a test fluid mixed together and equilibrated at RTP to form an hydrocarbon phase and a test fluid phase to generate a second dataset, using methods comprising at least one of:i) determining a bubble point of said hydrocarbon phase;ii) determining a weight contribution of components of said hydrocarbon phase;iii) determining a density of a remaining hydrocarbon phase when said hydrocarbon phase is flashed to STP or ambient conditions; oriv) determining a weight contribution of gaseous components flashed from said hydrocarbon phase;v) determining total acid number (TAN), metal content, viscosity, asphaltene content, C7 content; nitrogen content, water content, carbon content, total contents; waxcontent; carbon residue content, conductivity, pour point, density@15°C; salt content, sediment content, specific gravity; light end hydrocarbon content; mercaptan content; hydrogen content, total sulfur, hydrogen sulfide content or vapor pressure of said hydrocarbon phase or said remaining hydrocarbon phase;c) comparing said first dataset and said second dataset, wherein changes in said second dataset as compared with said first dataset indicates that said test fluid is not inert, but no changes indicates said test fluid is inert and can be used to collect reservoir core samples at RTP.2) The method of claim 1, wherein weight contribution is determined with gas chromatography.3) The method of claim 1-2, wherein i) weight contribution of components of a fluid is determined with elemental composition and gas chromatography or wherein ii) weight contribution of gaseous components is determined with gas chromatography, or wherein iii) weight contribution of components of a fluid is determined with elemental composition and gas chromatography with flame ionization detector (GC / FID).4) The method of claim 1-3, wherein density of a fluid is determined using a HPHT densitometer at RTP.5) The method of claim 1-4, wherein bubble point of a fluid is determined by stepping down the pressure from RTP and observing a pressure at which bubbles appear or wherein bubble point of a fluid is determined by ASTM D2889 - 95(2019).6) The method of claim 1-5, wherein RTP is an average temperature and pressure of a play in the reservoir.7) A method of assaying a test fluid for inertness in collecting reservoir core samples at RTP, said method comprising:a) obtaining an oil sample having a first characterization of elements, C1-C40 components, dissolved gas and density;b) mixing said oil sample plus a test fluid to form a mixture, and equilibrating said mixture at RTP to produce an hydrocarbon phase and a test fluid phase;c) assaying said hydrocarbon phase to determine a second characterization of elements, Cl-C40 components, dissolved gas and density;d) comparing said first characterization with said second characterization to identify changes in characterization;e) wherein changes in characterization indicates that said test fluid is not inert, but no changes in characterization indicates said test fluid is inert and can be used to collect reservoir core samples at RTP.8) The method of claim 7, wherein said second characterization of elements and C1-C40 components is determined with elemental composition and gas chromatography.9) The method of claim 7-8, wherein said second characterization of elements and C1-C40 components is determined by elemental composition and gas chromatography with flame ionization detector (GC / FID).10) The method of claim 7-9, wherein density is determined using a HPHT densitometer at RTP.11) The method of claim 7-10, wherein bubble point is determined by stepping down a pressure from RTP and observing a pressure at which bubbles form.12) The method of claim 7-10, wherein bubble point is determined by ASTM D2889 - 95(2019).13) The method of claim 7-12, wherein RTP is an average temperature and pressure of a play in the reservoir.14) A method of determining if a test fluid is inert to reservoir oil at RTP, comprising:a) assaying a composition, density, and bubble or dew point of live oil to generate a first dataset;b) equilibrating a sample of said live oil with a test fluid at RTP to generate an hydrocarbon phase;c) assaying a composition, density, and bubble or dew point of said hydrocarbon phase to generate a second dataset;d) comparing said first and second datasets, wherein significant changes in said dataset indicates that said test fluid is not inert to reservoir oil at RTP.A core sampling inert fluid for use in coring reservoir samples at RTP, said inert fluid being a fluorinated silicon based compound, a hydrophobic silicon based compound, a brominatedsilicon based compound, or a mercury containing fluid, wherein said inert fluid does not interact with reservoir fluids at RTP, or said inert fluid being a compound herein described.

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