Fungicide composition, use and disease control methods with fenpropimorphe, fluxapiroxade and protioconazole

Description

[01] This invention relates to mixtures of agricultural pesticides containing FENPROPIMORF, Fluxapyroxade and protioconazole in effective amounts, with a synergistic effect.

[02] In addition to the aspect presented in the previous paragraph, this invention relates to the use of agricultural pesticide mixtures containing FENPROPIMORF, Fluxapyroxade and protioconazole in synergistically effective amounts for the protection of plants, plant propagation materials, and their growing environment against disease attack and infestation.

[03] In addition to the aspects presented in the previous paragraphs, this invention relates to a method of disease control, which involves applying effective amounts of pesticide mixtures containing FENPROPIMORF, FLUXAPYROXADE and PROTHIOCONAZOLE in effective amounts to a plant, plant propagation materials, its growth environment; to diseases or to its food source, habitat or growing sites.

[04] In addition to the aspects presented in the previous paragraphs, this invention relates to the use of agricultural pesticide mixtures containing FENPROPIMORF, Fluxapyroxade and protioconazole in effective quantities for combating selected diseases of the order Chytridiomycota, Neocallimastigomycota, Blastocladiomycota, Microsporidia, Glomeromycota, Ascomycota and Basidiomycota. In another aspect, the present invention relates to a method of controlling diseases. Petition 870250008816, dated 03 / 02 / 2025, page 6 / 43 2 / 30 selected from the order Chytridiomycota, Neocallimastigomycota, Blastocladiomycota, Microsporidia, Glomeromycota, Ascomycota and Basidiomycota, wherein the control method includes the treatment of the diseases, their food source, their growth environment or plant, seed, soil, area, material or environment in which the diseases are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected against disease attack or infestation with an effective amount as an agricultural pesticide of the agricultural pesticide mixtures comprising FENPROPIMORF, FLUXAPIROXAD and PROTHIOCONAZOLE in effective amounts.

[05] In addition to the aspects already mentioned in the paragraphs above, this invention relates to the use of FENPROPIMORF, FLUXAPIROXADE in an effective quantity as an agricultural pesticide to protect a soybean plant, its plant propagation material or its growing environment, from attacks or infestations by diseases selected from the group consisting of Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum, Corynespora cassiicola, Sclerotinia sclerotiorum, Phaeosphaeria maydis and Ramularia areola and their aggregates.

[06] In addition to the aspects already mentioned in the paragraphs above, this invention relates to the use of PROTIOCONAZOLE in an effective quantity as an agricultural pesticide to protect a soybean plant, its plant propagation material or its growing environment, from attacks or infestations by diseases selected from the group consisting of Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum, Corynespora cassiicola, Sclerotinia sclerotiorum, Phaeosphaeria maydis and Ramularia areola and their aggregates. Petition 870250008816, dated 03 / 02 / 2025, page 7 / 43 3 / 30

[07] In addition to the aspects already mentioned in the paragraphs above, this invention relates to the use of FENPROPIMORF, FLUXAPIROXADE in effective quantities, as an agricultural pesticide, to protect a soybean plant, its plant propagation material or its growing environment, from attack or infestation by diseases selected from the group consisting of Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum, Corynespora cassiicola, Sclerotinia sclerotiorum, Phaeosphaeria maydis and Ramularia areola and their aggregates. State of the Art.

[08] The state of the art regarding fungicides used in agriculture presents a wide variety of compounds, including triazoles, strobilurins, and carboxamides, which are applied alone or in generic mixtures. Despite their effectiveness, these fungicides face increasing challenges, especially due to fungal resistance, high application costs, and adverse environmental impacts. Pathogenic fungi, such as Phakopsora pachyrhizi, the causal agent of Asian soybean rust, have demonstrated a significant capacity to develop resistance to many fungicides available on the market. Furthermore, the need for high doses to achieve adequate control levels increases both operational costs and environmental risks.

[09] Among the most widely used fungicides, triazoles, such as prothioconazole, stand out for their systemic action, inhibiting ergosterol biosynthesis in fungi. However, their isolated use has limitations, including reduced efficacy against resistant fungi and the need for high doses. Similarly, carboxamides such as fluxapyroxad, which act by inhibiting ergosterol biosynthesis, are also notable for their systemic action. Petition 870250008816, dated 03 / 02 / 2025, page 8 / 43 4 / 30 of mitochondrial respiration, they face challenges related to the emergence of resistance and limited effectiveness in some agricultural crops. Generic mixtures, despite broadening the spectrum of control, often do not fully exploit the synergies between compounds, resulting in high doses and inefficient use of active ingredients.

[10] The proposed composition, based on the synergistic combination of FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE, overcomes these limitations by offering an innovative solution for the control of resistant fungi. The synergy between the three active ingredients allows for superior efficacy with reduced doses, minimizing costs and environmental impacts. Specifically, optimized proportions, such as 52:6:3 to 25:18:12, were developed to maximize the control of pathogenic fungi such as Phakopsora pachyrhizi, Septoria glycines and Corynespora cassiicola. Furthermore, the invention is applicable to various high-value economic crops, including soybeans, corn, cotton and citrus, expanding its commercial viability.

[11] Another advantage of the composition is its ability to reduce environmental impact, with application rates ranging from 50g to 1000g per hectare. This characteristic not only reduces the amount of pesticides used, but also reduces toxicity to non-target organisms and the risk of environmental contamination. Thus, the proposed composition represents a significant advance in the state of the art, meeting the need for more effective, sustainable and economically viable solutions for the control of fungal diseases in agriculture. Tables. Petition 870250008816, dated 03 / 02 / 2025, page 9 / 43 5 / 30

[12] Table 1: Description of treatments used to evaluate the control of Asian Soybean Rust (Phakopsora pachyrhizi) in soybean cultivation. Rio Verde - GO. Crop season 2023 / 2024.

[13] Table 2: Percentage of control (E) of Asian Soybean Rust (Phakopsora pachyrhizi) in soybean crop, in relation to the control without fungicide and to market standards, calculated by the area under the disease progress curve, AUDPC, Rio Verde - GO. Crop 2023 / 2024.

[14] Table 3: Comparison of average productivity between market standards, control and CCABPF22 coded product in soybean cultivation. Rio Verde - GO. Crop 2023 / 2024. Description.

[15] Consequently, there is a strong need for pesticides and mixtures thereof to control the diseases mentioned above on the large-scale crops mentioned above. It is therefore the object of the present invention to provide a mixture of pesticides that is suitable for the control of diseases, particularly Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum, Corynespora cassiicola, Sclerotinia sclerotiorum, Phaeosphaeria maydis and Ramularia areola, preferably any of the genera and species of Chytridiomycota, Neocallimastigomycota, Blastocladiomycota, Microsporidia, Glomeromycota, Ascomycota and Basidiomycota mentioned above or combinations thereof, which have specific importance with regard to soybean, corn, cotton, sugarcane, citrus, coffee and pasture plants, particularly with regard to soybean plants.In this particular case, it is also an object of the present invention to provide a mixture of pesticides that overcomes problems of fungal resistance with respect to the diseases mentioned above. In the form used in the present invention, a. Petition 870250008816, dated 03 / 02 / 2025, page 10 / 43 6 / 30 The expression "fungal resistance" refers to resistance to fungi against other pesticides and pesticide mixtures.

[16] This invention also aims to provide a pesticide composition that can be used at lower dosage rates compared to other pesticides and pesticide compositions, in order to avoid adverse toxicological or environmental effects.

[17] In addition to the aspects already mentioned, this invention aims, with regard to diseases and their aggregations, typically present in soybeans, to provide agricultural pesticides that are suitable for selective control of diseases, should infestation with one or more of them occur.

[18] It has been identified that the above targets can be reached by a composition of pesticides containing FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE in a synergistically effective quantity and its forms of use which include the application of the aforementioned composition as defined below.

[19] It has been identified that, taken together, the composition of pesticides according to this invention is suitable for controlling the diseases mentioned above, particularly Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum, Corynespora cassiicola, Sclerotinia sclerotiorum, Phaeosphaeria maydis and Ramularia areola and their aggregates.

[20] As a result, plants selected from soybean, corn, cotton, sugarcane, citrus, coffee and pasture plants, particularly soybean plants, can be efficiently protected against defoliation by these diseases, in order to avoid yield reduction. In this particular case, it is an important benefit of the composition as Petition 870250008816, dated 03 / 02 / 2025, page 11 / 43 7 / 30 This invention states that the composition is also suitable for controlling the diseases mentioned above in cases of resistance to conventional pesticides or pesticide compositions. Another benefit of the pesticide composition according to this invention is that the compositions can be applied at lower dosage rates compared to conventional pesticides and pesticide compositions.

[21] The compounds of this invention comprising FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE in synergistically effective amounts are characterized in detail below. The compounds of this invention shall hereinafter be referred to as the “composition according to the present invention”. Remarks regarding preferred embodiments of the composition according to the present invention shall be understood as preferred in isolation, as well as in combinations with each other and in combinations with preferred manipulations in relation to their use and methods encompassing the application of the composition according to the present invention in accordance with what is defined herein and in combination with preferred manipulations with reference to the agrochemical composition stipulated herein.

[22] The composition comprising FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE according to the present invention typically includes FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE in a possible ratio and weight of 1:1:100 / 1:100:1 / 100:1:1, preferably 52:6:3 - 25:18:12, specifically 59:09:06. In these manipulations, the composition according to the present invention is a tertiary composition, meaning that it does not include any other pesticide compounds besides FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE.

[23] The application methods of particular importance for the compositions according to the present Petition 870250008816, dated 03 / 02 / 2025, page 12 / 43 8 / 30 of the invention are detailed below. Specific preferences are given below. In one aspect, the present invention relates to the use of the composition according to the present invention for protecting plants, plant propagation materials and their growing environment from attack or infestation by diseases. Furthermore, the present invention relates to a means of disease control, wherein the means includes the application of effective amounts as agricultural pesticides of compositions according to the present invention to a plant, plant propagation materials and their growing environment; to diseases or to their food source, habitat or growing environment.Furthermore, the present invention relates to a means of controlling diseases, wherein the means includes the treatment of diseases, their food source, their habitat or growth environment, or plant, seed, soil, area, materials or locations in which the diseases are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected against disease attack or infestation with an effective quantity as an agricultural pesticide of the agricultural pesticide compositions.

[24] The application of the composition according to the present invention in accordance with its use or method above involves contact with the plant or plant propagation material and contact with its growth environment. The term “growth environment” should be understood as the environment where the plant is growing, whether it is the soil or water where the plant is growing. Furthermore, the method according to the present invention refers to a manipulation to be applied to diseases, their food source, habitat or growth environment.

[25] In the method described above, the composition according to the present invention is placed on the foliage and / or Petition 870250008816, dated 03 / 02 / 2025, page 13 / 43 9 / 30 plant roots, preferably in quantities of 0.1L to 2L / HA, with a greater preference for quantities of 1L / HA.

[26] Diseases can appear on wild-type plants and plants that have been altered through conventional cultivation, mutagenesis, genetic engineering, or one of these fusions. In one embodiment, the term “plant” refers to a plant that has been altered through conventional cultivation, mutagenesis, genetic engineering, or one of these fusions.

[27] The term “plant health” is defined as the condition of the plant and / or its products which is determined by numerous aspects individually or in combination with each other, such as production, plant vigor, quality and tolerance to biotic and abiotic stress. It is necessary to emphasize that the plant health effects mentioned above are also present when the plant is not under biotic stress and, particularly, when the plant is not under disease pressure. It is understandable that a plant suffering from fungi produces less biomass and generates a lower yield compared to a plant that has been treated against pathogenic fungi or any other important pest and that its damage can increase due to the biotic stress factor. The means according to this invention, however, generate better plant health, even in the absence of any biotic stress.This means that the improvement in plant health cannot be explained solely by the activities of FENPROPIMORF, FLUXAPYROXADE, and PROTHIOCONAZOLE independently, or by a composition containing a mixture of FENPROPIMORF, FLUXAPYROXADE, and PROTHIOCONAZOLE. Each plant health indicator listed below, selected from the groups consisting of yield, plant vigor, quality, and tolerance to biotic and / or abiotic stress, must be understood. Petition 870250008816, dated 03 / 02 / 2025, page 14 / 43 10 / 30 as a preferred embodiment of this invention, alone or in combination with each other. According to this invention, "improved plant yield indicates that the yield of a plant product increases equivalently through the use of FENPROPIMORF, FLUXAPIROXADE, PROTHIOCONAZOLE. Increased yield can be indicated, among others, by the following improved plant properties: greater plant weight, greater plant height, more biomass such as higher overall fresh weight, greater number of flowers per plant, greater grain and / or fruit yield, more branches or lateral shoots (twigs), larger leaves, greater shoot growth, higher protein content, higher oil content, higher starch content, higher pigment content, higher chlorophyll content (chlorophyll content has a positive correlation with the plant's photosynthesis rate and, consequently, the higher the chlorophyll content, the higher the plant's production)."Grain" and "fruit" should be understood as any plant material that is complementarily used after harvest, such as fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g., in the case of forestry plants), flowers (e.g., in the case of gardening, ornamental plants), etc., that is of economic value produced by the plant. According to the present invention, the yield is increased by at least 780 kg more in productivity per hectare. Another indicator of plant condition is plant vigor. Plant vigor becomes manifest in several aspects, such as overall visual appearance. Increased plant vigor can be characterized, among others, by the following improved plant properties: increased plant vitality, increased plant growth, increased plant development, improved visual appearance, increased planting (less plant lodging), increased... Petition 870250008816, dated 03 / 02 / 2025, p. 15 / 43 11 / 30 emergence, increased root growth and / or more developed root system, increased nodulation, particularly rhizobial nodulation, larger leaf blade, larger size, increased plant height, increased number of branches, increased number of lateral shoots, increased number of flowers per plant, increased shoot growth, increased photosynthetic activity (e.g., based on increased stomatal conduction and / or increased CO2 assimilation rate), increased pigment content, earlier flowering, earlier fruiting, early and improved germination, earlier grain maturation, fewer unproductive branches, fewer dead basal leaves, less need for inputs (such as fertilizers or water), greener leaves, complete maturation under reduced vegetation periods, less need for seeds, easier harvesting, faster and more uniform ripening, longer shelf life, longer panicles, delayed senescence,Stronger and / or more productive branches, improved ingredient extraction capacity, increased seed quality (for sowing in subsequent seasons for seed production) and / or reduced ethylene production and / or inhibition of its uptake by the plant. Another indicator of plant condition is the "quality" of a plant and / or its products. According to the present invention, improved quality indicates that certain plant characteristics, such as the content or composition of certain ingredients, are improved or enhanced by a measurable or observable amount over the same factor of the control plant produced under the same conditions. Improved quality can be characterized, among other things, by the following enhanced properties of the plant or its product: increased nutrient content, increased protein content, increased fatty acid content, increased, Petition 870250008816, dated 03 / 02 / 2025, page 16 / 43 12 / 30 of the metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, increased nutrient composition, increased protein composition, increased fatty acid composition, increased metabolite composition, increased carotenoid composition, increased sugar composition, increased amino acid composition, improved or ideal fruit color, improved leaf color, greater storage capacity, and greater processing capacity of harvested products. Another indicator of plant condition is the plant's tolerance or resistance to biotic and / or abiotic stress factors. Biotic and abiotic stress, especially over longer periods, can have damaging effects on plants. Biotic stress is caused by living organisms, while abiotic stress is caused, for example, by environmental extremes.According to the present invention, “increased tolerance or resistance to biotic and / or abiotic stress factors indicates (1) that certain negative factors caused by biotic and / or abiotic stress are reduced in a notable or measurable amount compared to control plants exposed to the same conditions and (2) that the negative effects are not reduced by the direct action of FENPROPIMORF, FLUXAPYROXADE, PROTHIOCONAZOLE or a mixture of FENPROPIMORF, FLUXAPYROXADE and PROTHIOCONAZOLE, for example, by their fungicidal action, but by stimulating the plants' own defensive reactions against the aforementioned stress factors. Negative factors caused by biotic stress such as these are widely known and range from spotted leaves to total plant destruction. Biotic stress can be caused by living organisms such as competing plants (e.g., weeds), microorganisms (such as phytopathogenic bacteria and / or fungi) and / or viruses. Negative factors. Petition 870250008816, dated 03 / 02 / 2025, p. 17 / 43 13 / 30 caused by abiotic stress are also well known and can often be observed as reduced plant vigor (see above), for example: spotted leaves, “burnt leaves”, reduced growth, fewer flowers, less biomass, lower crop yields, reduced nutritional value of crops and delayed crop maturation, to give just a few examples. Abiotic stress can be caused, for example, by: temperature extremes such as heat or cold (heat stress / cold stress), strong temperature variations, unusual temperatures for the specific season, drought (drought stress), extreme humidity, high salinity (salt stress), radiation (e.g., through increased UV radiation due to ozone layer depletion), increased ozone levels (ozone stress), organic pollution (e.g., by phytotoxic amounts of pesticides) and inorganic pollution (e.g., by heavy metal contaminants).

[28] As a result of biotic and / or abiotic stress factors, the quantity and quality of stressed plants, their yields and fruits are reduced. Regarding quality, reproductive development is usually severely affected with consequences for yields that are important for fruits or seeds. Protein synthesis, accumulation and storage are mainly affected by temperature; growth is slowed by almost all types of stress; the synthesis of polysaccharides, both structural and storage, is reduced or modified; these effects result in reduced biomass (yield) and changes in the nutritional value of the product. Advantageous properties, obtained especially from treated seeds, are, for example, improved germination and field establishment, better vigor and / or establishment. Petition 870250008816, dated 03 / 02 / 2025, page 18 / 43 14 / 30 in the most homogeneous field. As indicated above, the indicators identified above for plant health condition may be interdependent or may result from one another. Increased resistance to biotic and / or abiotic stress, for example, may generate better plant vigor, such as for larger and better harvests and therefore increased yield. On the other hand, a more developed root system may result in increased resistance to biotic and / or abiotic stress. These interdependencies and interactions are not, however, fully known or fully understood, and therefore the different indicators are described separately.

[29] The means and their uses according to this invention may also involve a phase of determining whether fungi are resistant to certain pesticides. This phase generally involves collecting a sample of fungi from the area to be treated, before the actual application of FENPROPIMORF, FLUXAPYROXAD, PROTHIOCONAZOLE or a composition of FENPROPIMORF, FLUXAPYROXAD and PROTHIOCONAZOLE and testing (using, for example, any appropriate phenotypic, biochemical or molecular biological method) to determine resistance / sensitivity.

[30] The following are appropriate formulations and applications with respect to the present application. These preferred manipulations refer to (i) the composition according to this invention, as well as uses and means that comprise the application of said composition, (ii) uses and means that comprise the application of FENPROPIMORF, FLUXAPIROXADE according to this invention and (iii) uses and means that comprise the application of PROTIOCONAZOLE according to this invention.

[31] According to this invention, the composition of FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE can be Petition 870250008816, dated 03 / 02 / 2025, page 19 / 43 15 / 30 provided in the form of an agrochemical mixture comprising the composition according to this invention, FENPROPIMORF, FLUXAPIROXADE or PROTIOCONAZOLE. An agrochemical mixture comprises an effective quantity as an agricultural pesticide of a composition according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTIOCONAZOLE. The expression "effective quantity as an agricultural pesticide" is set forth below. The compositions according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTIOCONAZOLE can be converted into customary types of agrochemical mixtures, such as solutions, emulsions, suspensions, dry powders, powders, pastes, granules, pressed powders, capsules and compositions thereof. Examples of mixture types are suspensions (such as SC, OD, FS), emulsifiable concentrates (such as EC), emulsions (such as EW, EO, ES, ME), capsules (such as CS, ZC), pastes, tablets, dry or wettable powders (such as WP, SP, WS, DP, DS), pressed products (such as BR, TB, DT), granules (such as WG, SG, GR, FG, GG, MG).These and other types of mixtures are defined in Catalogue of Pesticide Formulation Types and International Coding System, Technical Monograph No. 2, sixth edition, May 2008, CropLife International.

[32] Examples of suitable auxiliaries are solvents, liquid vehicles, solid vehicles or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesive agents, thickeners, wetting agents, repellents, attractants, feeding stimulants, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, adhesives and binders.

[33] Suitable solvents and liquid vehicles are water and organic solvents, such as oil fractions. Petition 870250008816, dated 03 / 02 / 2025, page 20 / 43 16 / 30 minerals with medium to high boiling points, such as kerosene and diesel oil; vegetable or animal oils; aliphatic, cyclic and aromatic hydrocarbons, such as toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, such as ethanol, propanol, butanol, benzyl alcohol and cyclohexanol; glycols; DMSO; ketones, such as cyclohexanone; esters, such as lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, such as N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

[34] Suitable solid vehicles or cargoes are mineral earths, such as silicates, silica gel, talc, kaolin, lime, limestone, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; powdered polysaccharides, such as cellulose and starch; fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate and ureas; products of vegetable origin, such as cereal dough, tree bark dough, wood dough, nut shell dough and mixtures thereof.

[35] Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes and their compositions. These surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids or adjuvants.

[36] Suitable anionic surfactants are alkaline, alkaline-earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates and their compositions. Examples of sulfonates are alkylaryl sulfonates, diphenyl sulfonates, alpha-olefin sulfonates, lignin sulfonates, Petition 870250008816, dated 03 / 02 / 2025, page 21 / 43 17 / 30 Sulfonates of oils and fatty acids, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecyl and tridecylbenzene sulfonates, naphthalene and alkylnaphthalene sulfonates, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of oils and fatty acids, ethoxylated alkylphenols, alcohols, ethoxylated alcohols or fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, carboxylated alcohols or alkylphenol ethoxylates.

[37] Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and their compositions. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with one to fifty equivalents. Ethylene oxide and / or propylene oxide may be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters, or alkyl polyglycosides. Examples of polymeric surfactants are homo- or copolymers of vinylpyrrolidone, vinyl alcohols, or vinyl acetate.

[38] Suitable cationic surfactants are quaternary surfactants, such as quaternary ammonium compounds with one or two hydrophobic groups or salts of Petition 870250008816, dated 03 / 02 / 2025, page 22 / 43 18 / 30 long-chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are AB or A-BA type block polymers comprising polyethylene oxide and polypropylene oxide blocks or ABC type block polymers comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkaline salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.

[39] Suitable adjuvants are compounds that have negligible or even no pesticidal activity on their own and that improve the biological performance of the compositions according to this invention, FENPROPIMORF, Fluxapyroxade and protioconazole act on the target. Examples include surfactants, mineral or vegetable oils, and other auxiliaries.

[40] Suitable thickeners are polysaccharides (such as xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates and silicates.

[41] Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

[42] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

[43] Suitable antifoaming agents are silicones, long-chain alcohols and fatty acid salts.

[44] Suitable dyes (such as reds, blues or greens) are pigments with low water solubility and water-soluble dyes. Examples are inorganic dyes (such as iron oxide, titanium oxide and iron hexacyanoferrate) and organic dyes (such as dyes of Petition 870250008816, dated 03 / 02 / 2025, page 23 / 43 19 / 30 alizarin, azo and phthalocyanine).

[45] Suitable adhesives or binders are polyvinylpyrrolidones, polyvinyl acetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes and cellulose ethers.

[46] Examples of composition types and their preparation are: (i) Water-soluble concentrates (SL, LS) 10 to 60% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE and 5 to 15% by weight of wetting agent (such as alkoxylate alcohol) are dissolved in water and / or in a water-soluble solvent (such as alcohol) up to 100% by weight. The active substance dissolves upon dilution with water. (ii) Dispersible concentrates (DC) 5-2% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE and 1-10% by weight of dispersant (e.g., polyvinylpyrrolidone) are dissolved in up to 100% by weight of organic solvent (e.g., cyclohexanone). Dilution with water generates a dispersion.(iii) Emulsifiable concentrates (EC) 15-70% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE and 5-10% by weight of emulsifiers (such as calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in up to 100% by weight of water-insoluble organic solvent (such as aromatic hydrocarbon). Dilution with water generates an emulsion. (iv) Emulsions (EW, EO, ES) 5-40% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPYROXADE and PROTHIOCONAZOLE and 1-10% by weight of emulsifiers (such as calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in up to 20-40% by weight of water-insoluble organic solvent (such as aromatic hydrocarbon). This mixture is introduced into water at 100% by weight. Petition 870250008816, dated 03 / 02 / 2025, page 24 / 43 20 / 30 by means of an emulsifying machine and transformed into a homogeneous emulsion. Dilution with water generates an emulsion. (v) Suspensions (SC, OD, FS), in a stirred ball mill, 20-60% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE are fragmented with the addition of 2-10% by weight of dispersants and wetting agents (such as sodium lignosulfonate and alcohol ethoxylate), 0.1-2% by weight of thickener (such as xanthan gum) and up to 100% by weight of water to generate a fine active substance suspension. Dilution with water generates a stable suspension of the active substance. For FS-type compositions, up to 40% by weight of binder (such as polyvinyl alcohol) is added. (vi) Water-dispersible granules and water-soluble granules (WG, SG) 50-80% by weight of the mixture according to this invention, active 1, active 2 and active 3 are finely ground with the addition of up to 100% by weight of dispersants and wetting agents (such as sodium lignosulfonate and alcohol ethoxylate) and prepared in the form of water-dispersible or water-soluble granules by means of technical devices (such as extrusion, spray tower and fluidized bed). Dilution with water generates a stable solution or dispersion of the active substance.(vii) Water-dispersible powders and water-soluble powders (WP, SP, WS) 50-80% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE are milled in a rotor-stator mill with the addition of 1-5% by weight of dispersants (such as sodium lignosulfonate), 1-3% by weight of wetting agents (such as alcohol ethoxylate) and up to 100% by weight of solid carrier, such as silica gel. Dilution with water generates a stable solution or dispersion of the active substance. (viii) Gel (GW, GF) in a stirred ball mill, 525% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPYROXADE and PROTIOCONAZOLE are fragmented with the addition of. Petition 870250008816, dated 03 / 02 / 2025, page 25 / 43 21 / 30 3-10% by weight of dispersants (such as sodium lignosulfonate), 1-5% by weight of thickener (such as carboxymethylcellulose) and up to 100% by weight of water to generate a fine suspension of the active substance. Dilution with water generates a stable suspension of the active substance. (ix) Microemulsion (ME) 5-20% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE are added to 5-30% by weight of a mixture of organic solvents (such as fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a mixture of surfactants (such as alcohol ethoxylate and arylphenol ethoxylate) and water up to 100%. This mixture is stirred for one hour to spontaneously produce a thermodynamically stable microemulsion. (x) Microcapsules (CS) an oil phase comprising 5-50% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE, 0-40% by weight of water-insoluble organic solvent (such as aromatic hydrocarbon), 2-15% by weight of acrylic monomers (such as methyl methacrylate, methacrylic acid and di- or triacrylate) is dispersed in an aqueous solution of protective colloid (such as polyvinyl alcohol). (xi) Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules. Alternatively, an oil phase comprising 5-50% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE, 0.40% by weight of water-insoluble organic solvent (such as aromatic hydrocarbon) and an isocyanate monomer (such as 4,4'-diphenylmethylene diisocyanate) is dispersed in an aqueous solution of protective colloid (such as polyvinyl alcohol).The addition of a polyamine (such as hexamethylenediamine) results in the formation of polyurea microcapsules. The monomers represent 1-10% by weight. Petition 870250008816, dated 03 / 02 / 2025, page 26 / 43 22 / 30 percent by weight refers to the total composition of CS. (xii) Dustable Powders (DP, DS) 1-10% by weight of a mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTIOCONAZOLE are finely ground and thoroughly mixed with up to 100% by weight of a solid carrier, such as finely divided kaolin. (xiii) Granules (GR, FG) 0.5-30% by weight of the mixture according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTIOCONAZOLE are finely ground and associated with up to 100% by weight of a solid carrier (such as silicate). Granulation is achieved by extrusion, spray drying or fluidized bed. (xiv) Liquids under ultra-low volume (UL) 1-50% by weight of the mixture according to this invention, active 1, active 2 and active 3 are dissolved in up to 100% by weight of organic solvent, such as aromatic hydrocarbon.

[47] The compositions of types (i) to (xi) may optionally comprise additional auxiliaries, such as 0.1-1% by weight of bactericides, 5-15% by weight of antifreeze agents, 0.1-1% by weight of antifoaming agents and 0.1-1% by weight of colorants.

[48] ​​Agrochemical mixtures commonly comprise from 0.01 to 95%, preferably from 0.1 to 90%, and most preferably from 0.5 to 75% by weight of active substance. The active substances are employed in a purity of 90% to 100%, preferably from 95% to 100%.

[49] Various types of oils, humectants, adjuvants, fertilizers or micronutrients and other agricultural pesticides (such as herbicides, insecticides, fungicides, growth regulators and safety agents) may be added to the active substances or to the compositions comprising them as a premix or, where appropriate, not until immediately before use (mixture of Petition 870250008816, dated 03 / 02 / 2025, page 27 / 43 23 / 30 tank).

[50] The user applies the composition according to this invention normally from a pre-dosing device, backpack sprayer, spray tank, spray plan or irrigation system. Typically, the agrochemical composition is prepared with water, buffer and / or additional auxiliaries to the desired application concentration and the ready-to-use spray liquid or the agrochemical composition according to the present invention is obtained. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquid are applied per hectare of usable agricultural area.

[51] According to one manipulation, individual components of the mixture according to this invention, such as parts of a kit or parts of a binary or ternary composition, can be mixed by the user himself in a spray tank and auxiliaries can be added, if appropriate.

[52] Additionally, in a manipulation, individual components of the mixture according to this invention or partially premixed components, such as components comprising mixtures according to the present invention, FENPROPIMORF, FLUXAPIROXADE and PROTIOCONAZOLE, can be mixed by the user in a spray tank and additional additives and auxiliaries can be added, if appropriate.

[53] In a further embodiment, individual components of the composition according to the present invention or partially premixed components, such as components comprising mixtures according to the present invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE, may be applied together (such as after mixing of Petition 870250008816, dated 03 / 02 / 2025, page 28 / 43 24 / 30 tank) or consecutively.

[54] Mixtures of FENPROPIMORF, FLUXAPIROXAD and PROTIOCONAZOLE are also suitable for use in combating or controlling diseases. The present invention therefore also relates to a method of combating or controlling diseases, which comprises contacting the diseases, their habitat, growth site, food source, crops, plants, plant propagation materials such as seeds, soil, area, material or environment in which the diseases are growing or may grow, with an effective amount of pesticide from a mixture according to the present invention, FENPROPIMORF, FLUXAPIROXAD and PROTIOCONAZOLE. The mixtures according to the present invention, FENPROPIMORF, FLUXAPIROXAD and PROTIOCONAZOLE are effective through contact and ingestion. Furthermore, the mixtures according to the present invention, FENPROPIMORF, FLUXAPIROXAD and PROTIOCONAZOLE can be applied to any and all stages of disease development.

[55] Mixtures of FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE may be applied as such or in the form of compositions comprising them as defined above.

[56] As used herein, the term “contact” includes direct contact (application of the compounds / mixtures / compositions directly onto the pest animal or plant, typically to the foliage, stems or roots of the plant) and indirect contact (application of the compounds / mixtures / compositions to the site, i.e., habitat, growth site, plant, seed, soil, area, material or environment in which the diseases are growing or may grow).

[57] The term “harvest” designates crops that are growing and have been harvested. Petition 870250008816, dated 03 / 02 / 2025, page 29 / 43 25 / 30

[58] The term “plant” includes cereals, such as durum wheat and others, barley, rye, triticale, oats, rice or maize (forage maize, sweet maize and field maize); beet, such as sugar beet or fodder beet; fruits, such as pomes, drupes or soft fruits, such as apples, pears, plums, peaches, nectarines, almonds, cherries, papayas, strawberries, raspberries, currants or blackcurrants; leguminous plants, such as beans, lentils, peas, alfalfa or soybeans; oilseed plants, such as rapeseed (canola), wild turnip, mustard, olives, sunflower, coconut, cocoa beans, castor plants, oil palm, peanuts or soybeans; cucurbits, such as pumpkins, squash, cucumbers or melons; fiber plants, such as cotton, flax, hemp or jute; citrus fruits, such as oranges, lemons, grapefruits or tangerines;Vegetables, such as eggplant, spinach, lettuce (e.g., iceberg lettuce), endive, cabbage, asparagus, carrots, onions, garlic, leeks, tomatoes, potatoes, cucurbits, or sweet peppers; laurel plants, such as avocados, cinnamon, or camphor; raw material and energy plants, such as corn, soybeans, canola, sugarcane, or oil palm; tobacco; almonds, such as walnuts; pistachios; coffee; tea; bananas; grapes (table grapes and juice grapes); hops; sweetener leaf (also known as stevia); natural rubber plants or forest and ornamental plants, such as flowers (e.g., carnations, petunias, geraniums / Pelargonium, pansies, and impatiens), shrubs, broadleaf trees (e.g., poplar), or perennials, such as conifers; eucalyptus; grass; turf;Grass for animal feed or ornamental uses. Preferred plants include potatoes, beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, canola, legumes, sunflowers, coffee or sugarcane; fruits; grapes; Petition 870250008816, dated 03 / 02 / 2025, pp. 30 / 43 26 / 30 ornamental plants; or vegetables, such as cucumbers, tomatoes, beans or pumpkins.

[59] The term “plant propagation material” designates all reproductive parts of the plant, such as seeds and plant material such as cuttings and tubers (e.g., potatoes), which can be used for plant propagation. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, seedlings and other plant parts. Seedlings and young plants, which must be transplanted after germination or after emergence from the soil, may also be included. These plant propagation materials may be treated prophylactically with a plant protection mixture at planting, transplanting or before it.

[60] The term “seed” encompasses seeds and plant propagules of all kinds, including, but not limited to, true seeds, seed pieces, buds, stolons, bulbs, fruits, tubers, grains, cuttings, cut shoots and the like, and indicates, in a preferred embodiment, true seeds.

[61] Generally, “effective amount of pesticide” indicates the amount of active ingredient required to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention and removal, destruction or otherwise reduction of the occurrence and activity of the target organism. The effective amount of pesticide may vary for the various compounds / mixtures / compositions used in the present invention. An effective amount of pesticide from the compositions will also vary according to prevailing conditions, such as the desired pesticide effect and duration, weather conditions, target species, location, method of application and the like. Petition 870250008816, dated 03 / 02 / 2025, pages 31 / 43 27 / 30

[62] For use in the treatment of producing plants, for example, by means of foliar application, the application rate of the active ingredients according to the present invention may be in the range of 0.0001 g - 4000 g per hectare, preferably 50 g - 1000 g, more specifically 500 g.

[63] Compositions according to this invention, FENPROPIMORF, FLUXAPIROXADE and PROTHIOCONAZOLE are particularly suitable for the efficient control of diseases such as fungi of the order Chytridiomycota. Neocallimastigomycota, Blastocladiomycota, Microsporidia, Glomeromycota, Ascomycota and Basidiomycota, such as Acremonium strictum (W. Gams), Alternaria alternata ((Fr.) Keissl), Alternaria macrospora (Zimm.), Ascochyta lojae (Miura), Aspergillus flavus (Link ex Fr.), Aspergillus niger (Tiegh.), Aspergillus spp., Bipolaris sacchari ((EJ Butler) Shoemaker), Bipolaris sorokiniana ((Sacc.) Shoemaker), Bipolaris zeicola, Ceratocystis paradoxa ((Dade) C. Moreau), Cercospora gossypina (Cooke), Cercospora kikuchii ((Tak. Matsumoto and Tomoy.) MW Gradner), Cercospora longipes (EJ Buther), Cercospora sojina (Hara), Cercospora sorghi f. sp. maydis (Ellis & Everth), Cercospora zeae-maydis (Tehon & Daniels), Cladosporium cladosporioides ((Fres.) de Vries), Cladosporium herbarum ((Pers.) Link), Cochliobolus stenospilus (T. Matsumoto & W. Yamam.), Colletotrichum dematium ((Pers.) Grove), Colletotrichum falcatum, Colletotrichum gossypii cephalosporioide (AS Costa), Colletotrichum gossypii (South), Colletotrichum graminicola, Colletotrichum truncatum ((Schwein.) Andrus et WD Moore), Corynespora cassiicola ((Berk. et MA Curtis) CT Wei), Curvularia lunata ((Wakk.) Boedijn), Diaporthe phaseolorum f.sp. meridionalis ((Cooke et Ellis) Sacc.), Diaporthe phaseolorum var. caulivora (Athow & Caldwell), Diaporthe Petition 870250008816, dated 03 / 02 / 2025, p. 32 / 43 28 / 30 phaseolorum var. sojae (( Lehman) Wehm.), Erysiphe diffusa ((Cooke & Peck) U. Braun & S. Takan), Exserohilum turcicum, Fusarium moniliforme (J. Sheld), Fusarium oxysporum, Fusarium oxysporum f.sp. vasinfectum, Fusarium pallidoroseum ((Cooke) Sacc.), Fusarium semitectum, Fusarium solani, Fusarium solani f.sp. glycines, Fusarium verticillioides ((Sacc.) Nirenberg), Gibberella zeae, Glomerella tucumanensis ((Speg.) V. Arx & E. Müll.), Helminthosporium maydis (Y. Nisik. & C. Miyake), Kabatiella zeae, Lasiodiplodia theobromae ((Pat.) Griffon & Maubl.), Leptosphaeria sacchari (Van Breda de Haan), Macrophomina phaseolina, Marasmius sacchari (Wakker), Microsphaera diffusa (Cooke & Peck), Mycovellosiella koepkei ((W. Krüger) Deighton), Myrothecium roridum (Tode ex Fr.), Nigrospora oryzae ((Berk. & Broome) Petch), Pantoea ananatis (Serrano), Penicillium digitatum, Penicillium oxalicum (Currie & Thom), Penicillium spp., Peronosclerospora sorghi ((Weston & Uppal) CGShaw), Peronospora manshurica ((Naum.) Syd. Ex Gaum), Phaeocytostroma sacchari ((Ellis & Everh.) B. Sutton), Phaeosphaeria maydis ((Henn.) Rane), Phakopsora gossypii ((Lagerh.) Hirats.), Phakopsora meibomiur (Arthkopsora) Phakopsora, Arthur pachyrhizi, Phialophora gregata f. sp. sojae (Kobayashi et al.), Phoma sorghina ((Sacc.) Boerema, Dorenbosch, & Van Oesteren), Phoma spp., Phomopsis phaseoli f. sp. meridionalis, Phomopsis sojae (Lehman.), Physoderma maydis ((Additional) Additional), Physopella zeae ((Mains) GB Cummins & Ramachar), Phytophthora sojae (oaufmann & Gerdemann), Puccinia kuehnii ((W. Orüger) EJ Butler), Puccinia me P. Sydoc. (Syd.). Puccinia polysora (Underw.), Puccinia sorghi (Schwein.), Pythium aphanidermatum ((Edson) Fitzp.), Pythium spp., Ramularia areola (Atk.), Rhizoctonia solani, Rhizoctonia spp., Rhizopus nigricans (Ehr.), Rhizopus spp., Rhizoferi stoloni. ((Ehrenb.:Fr.) Vuill.), Rosellinia. Petition 870250008816, of 03 / 02 / 2025, p. 33 / 43 29 / 30 spp., Sclerotinia sclerotiorum ((Lib.) de Bary.), Sclerotium rolfsii (Sacc.), Septoria glycines (Hemmi), Sphacelotheca reiliana, Spiroplasma kunkelli (Whitcomb), Stenocarpella macrospora ((Earle) Sutton), Stenocarpella (Bella) may (Bella) BC. Sutton), Thanatephorus cucumeris, Thielaviopsis basicola ((Berk. & Broome) Ferraris), Ustilaginoidea virens ((Cooke) Takahasi), Verticillium dahliae (Keb.). Control test of Asian rust disease (Phakopsora pachyrhizi) in soybean crop. Rio Verde - GO. Safra 2023 / 2024.

[64] In order to evaluate the efficiency and agronomic practicability of the product CCABPF22 (fenpropimorph 350 g.l-1 + prothioconazole 90 g.l-1 + fluxapyroxad 60 g.l-1), sprayed on soybean (Glycine max L.) crops for the control of Asian soybean rust (Phakopsora pachyrhizi), an experiment was installed in the field of MRE Pesquisas, located in Rio Verde - GO, at Rua Henriqueta Assunção nº 70, in the 2023 / 2024 growing season. Each plot consisted of 15.0 m2 (3.0 m x 5.0 m). The statistical design used was randomized blocks, with seven treatments and four replications. Three foliar applications were carried out on the soybean crop with the following treatments: Control, CABPF22, Fox Xpro, Tebuconazole, Prothioconazole and Metconazole were applied at the concentrations and doses indicated in Table 1. Applications were made to soybean crops using a CO2-pressurized sprayer, with a spray volume of 100 L ha-1 for all treatments. The experiment was conducted between February 26, 2024, and April 2, 2024. Treatments were applied on February 26, 2024, March 9, 2024, and March 21, 2024, as shown in Table 2. Results were evaluated prior to treatment application and 12 days after the first, second, and third applications (12 DA1A, 12 DA2A, and 12 DA3A). Harvesting Petition 870250008816, dated 03 / 02 / 2025, pages 34 / 43 30 / 30 was evaluated in 5.0 m2 per plot, on 11 / 04 / 2024, with the data transformed into kg.ha-1. The data were subjected to analysis of variance using the F-test and the differences between the treatment means were compared using Tukey's test at 5%, with data transformed into (x+k)A1 / 2 with k = 1.0. Based on the results obtained in this research and the conditions under which it was conducted, it can be concluded that the product CCABPF22 (fenpropimorph 350 g.l-1 + prothioconazole 90 g.l-1 + fluxapyroxad 60 g.l-1) contributed to the control of Asian Soybean Rust (Phakopsora pachyrhizi) in the area where the experiment was conducted. The application of CCABPF22, at a dose of 1.0 L.ha-1, showed efficacy greater than 84.7% based on the AUDPC of all evaluations performed in the study, with superior results observed compared to the standard products of the experiment.The productivity corresponding to the area where CCABPF22 was applied showed an increase of 37% compared to the control (representing 13.5 sacks of soybeans, equivalent to R$1,890.00 if considering R$140.00 / sack) and 8% more compared to the Fox Xpro product, a market reference (representing 3.6 sacks of soybeans, equivalent to R$504.00 if considering R$140.00 / sack). The CCABPF22 product demonstrated agronomic practicability and can be recommended for Integrated Management of Asian Soybean Rust (Phakopsora pachyrhizi) in soybean cultivation.

Claims

1. FUNGICIDAL COMPOSITION, characterized by comprising FENPROPIMORF, FLUXAPYROXAD and PROTHIOCONAZOLE in synergistically effective amounts.

2. FUNGICIDAL COMPOSITION, according to claim 1, characterized in that the active ingredients are present in the following weight proportions: FENPROPIMORF, as active ingredient 1, FLUXAPYROXADE, as active ingredient 2, and PROTHIOCONAZOLE, as active ingredient 3, in proportions ranging from 1:100 to 100:

1.

3. FUNGICIDAL COMPOSITION, according to claim 1, characterized in that the preferred proportions of the active ingredients are FENPROPIMORF, FLUXAPYROXAD and PROTHIOCONAZOLE, in the ratio of 52:6:3 to 25:18:12 for the control of Phakopsora pachyrhizi.

4. FUNGICIDAL COMPOSITION, according to claim 1, characterized in that the preferred proportions are 52:6:3 to 25:18:12 for the control of Phakopsora pachyrhizi.

5. FUNGICIDAL COMPOSITION, according to any of the preceding claims, characterized in that it is intended for the control of selected fungi from the group consisting of Phakopsora pachyrhizi, Septoria glycines, Colletotrichum truncatum and Corynespora cassiicola.

6. FUNGICIDAL COMPOSITION, according to claim 4, characterized by the fact that it is applied to the foliage of plants in quantities of 50g to 1000g per hectare. Petition 870250008816, dated 03 / 02 / 2025, page 36 / 43 2 / 2 7. USE OF THE FUNGICIDAL COMPOSITION, as claimed in claim 1, characterized by protecting plants against fungal infestations.

8. USE OF THE FUNGICIDAL COMPOSITION, as per claim 6, characterized in that the composition is applied to soybean, corn, and cotton crops.

9. A METHOD FOR CONTROLLING FUNGI, characterized in that it includes the application of the pesticide composition, as claimed in claim 1, to the foliage or growing environment of plants.

10. A METHOD FOR CONTROLLING FUNGI, according to claim 8, characterized in that the application is carried out on selected plants from the group consisting of soybeans, corn, cotton and citrus.