Cleaning method

Abstract

A method for cleaning an article in which an active ingredient of a pesticide remains, comprising bringing a cleaning liquid composition with a pH of 10 or higher comprising an organic solvent in contact with the article.

Description

[Name of Document] Specification [Title of the Invention] CLEANING METHOD [Technical Field]

[0001] The present invention relates to a cleaning method. [Background Art]

[0002] Spraying machines are commonly used to spray pesticides. Pesticides usually remain in spraying machines used for spraying pesticides. The use of the spraying machine with pesticide residues may cause a problem due to unintentional spray of pesticide residues. Such problem includes, for example, pesticide residues in harvested agricultural products exceed the standard value, or phytotoxicity on crops may occur if the pesticide is a herbicide. Therefore, it is desirable that the spraying machine used for spraying pesticides is properly cleaned, but known cleaning methods are not always complete, and new cleaning methods are required. In general, examples of the method for cleaning a pesticide spraying machine include a method in which an active ingredient is inactivated by a redox reaction (Patent Literature 1), a method in which an active ingredient is inactivated with an acid or an alkali (Non-Patent Literature 1), a method of cleaning with a surfactant (Non-Patent Literature 2) and the like. [Citation List] [Patent Literature]

[0003] [Patent Literature 1] U.S. Patent No. 9,657,258 [Non-Patent Literature]

[0004] [Non-Patent Literature 1] Data Sheet of Valent Tank Cleaner Safety [Non-Patent Literature 2] Data Sheet of All Clear Safety [Summary of Invention] [Technical Problem]

[0005] The present invention aims to provide a novel method for cleaning an article in which an active ingredient of a pesticide remains. [Solution to Problem]

[0006] The present inventors have found that the use of a liquid composition with a high pH comprising an organic solvent enables effective cleaning of a pesticide residue from an article in which an active ingredient of a pesticide remains. The present invention includes the following [1] to

[11] .

[0007] [1] A method for cleaning an article in which an active ingredient of a pesticide remains, comprising bringing a cleaning liquid composition with a pH of 10 or higher comprising an organic solvent in contact with the article. [2] The method according to [1], wherein the article is a pesticide spraying machine. [3] The method according to [1], wherein the organic solvent is solvent naphtha. [4] The method according to [1], wherein the organic solvent is cyclohexanone. [5] The method according to [1], wherein the organic solvent is tetrahydrofuran. [6] The method according to [1], wherein the cleaning liquid composition comprises an inorganic alkali. [7] The method according to [1], wherein the cleaning liquid composition comprises an alkali metal hydroxide. [8] The method according to [1], wherein the cleaning liquid composition comprises an organic alkali. [9] The method according to [1], wherein the cleaning liquid composition comprises tetrabutylammonium hydroxide.

[10] A cleaning liquid composition comprising an organic solvent and tetrabutylammonium hydroxide.

[11] Use of the cleaning liquid composition with a pH of 10 or higher comprising an organic solvent for cleaning an article in which an active ingredient of a pesticide remains. [Effects of Invention]

[8000] The present invention enables effective cleaning of an article in which an active ingredient of a pesticide remains. [Description of Embodiments] A cleaning method of the present invention (hereinafter sometimes referred to as present method) includes bringing a cleaning liquid composition with a pH of 10 or higher comprising an organic solvent (hereinafter sometimes referred to as present composition) into contact with an article in which an active ingredient of a pesticide (hereinafter sometimes referred to as active ingredient) remains.

[0010] The article in which the active ingredient remains is an article which usually comes in contact with or adheres to a pesticide when using the pesticide, and examples of such article include pesticide spraying machines, protective clothings, goggles, gloves, stirring rods, measuring cups, pesticide containers (storage containers for pesticide distribution, and containers for temporarily storing a spray liquid used for pesticide spraying) and the like. When the article is a pesticide spraying machine, parts in which the active ingredient remains in the pesticide spraying machine are parts constituting the pesticide spraying machine, which usually come in contact with or adhere to a spray liquid, and examples thereof include tanks, pipes, hoses, O-rings, strainers, nozzles and the like. The material of the tank is generally polyethylene or polypropylene, the material of the hose is generally a synthetic rubber (for example, EPDM), polyurethane or polyvinyl chloride, and the materials of the pipe and strainer are generally stainless steel.

[0011] Examples of the organic solvent comprised in the present composition include aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d- limonene, pinene, heptane, hexadecane, etc.), aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), derivatives of alkylbenzenes, derivatives of alkylnaphthalenes, alkylnaphthalenes, tetrahydronaphthalenes, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2- dichloropropane, etc.), ketones (cyclohexanone, cyclopentanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate, isopropyl myristate, methyl octanate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactic acid esters (ethyl lactate, propyl lactate, etc.) and carbonic acid esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.)), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, dipropylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (<semantics>γ<annotation encoding="application / x-tex">\gamma< / annotation>< / semantics>-butyllactone, etc.), ethers (1,4- dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N, N-dimethylformamide, and fatty acid dimethylamides (N, N- dimethylacetamide, N, N-dimethyldecanamide, N, N- dimethyloctanamide, etc.)), alkylpyrrolidones (N- methylpyrrolidone, N-octyl-pyrrolidone, N-dodecyl- pyrrolidone, etc.), lactams (<semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-lactam, <semantics>β<annotation encoding="application / x-tex">\beta< / annotation>< / semantics>-lactam, <semantics>γ<annotation encoding="application / x-tex">\gamma< / annotation>< / semantics>-lactam, <semantics>δ<annotation encoding="application / x-tex">\delta< / annotation>< / semantics>- lactam, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanols (1-methoxy-2- propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (solvent naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefin, etc.), vegetable-derived oils (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil, and derivatives thereof, etc.), animal-derived oils (sardine oil, saury oil, whale oil, and derivatives thereof, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (acetic anhydride, etc.), 1,3-dimethyl-2-imidazolidinone and the like. In particular, solvent naphtha, cyclohexanone and tetrahydrofuran are preferable.

[0012] Solvent naphtha is an aromatic oil having a boiling point within a range of 120 to 300°C obtained by fractional distillation of coal-tar light oil, and examples of industrial products thereof include Aromatic 200, Aromatic 200ND, Aromatic 150, Aromatic 150ND and Aromatic 100 manufactured by ExxonMobil Chemical Company, general-purpose petroleum benzine and the like. The amount of the organic solvent comprised in the present composition is usually from 1 to <semantics>50%(v / v)<annotation encoding="application / x-tex">50\%(v / v)< / annotation>< / semantics>. Specific amount of the organic solvent in the present composition include <semantics>2%(v / v)<annotation encoding="application / x-tex">2\%(v / v)< / annotation>< / semantics>, <semantics>3%(v / v)<annotation encoding="application / x-tex">3\%(v / v)< / annotation>< / semantics>, <semantics>4%(v / v)<annotation encoding="application / x-tex">4\%(v / v)< / annotation>< / semantics>, <semantics>5%(v / v)<annotation encoding="application / x-tex">5\%(v / v)< / annotation>< / semantics>, <semantics>8%(v / v)<annotation encoding="application / x-tex">8\%(v / v)< / annotation>< / semantics>, <semantics>10%(v / v)<annotation encoding="application / x-tex">10\%(v / v)< / annotation>< / semantics>, <semantics>15%(v / v)<annotation encoding="application / x-tex">15\%(v / v)< / annotation>< / semantics>, <semantics>20%(v / v)<annotation encoding="application / x-tex">20\%(v / v)< / annotation>< / semantics>, <semantics>30%(v / v)<annotation encoding="application / x-tex">30\%(v / v)< / annotation>< / semantics> and <semantics>40%(v / v)<annotation encoding="application / x-tex">40\%(v / v)< / annotation>< / semantics>.

[0014] The pH of the present composition is 10 or more. The pH of the present composition is usually within a range of 10 to 15, and specifically 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14 and 14.5. The pH of the present composition is mainly determined by the amount of an alkali comprised in the present composition, namely, the concentration of the alkali in the present composition. The pH is measured by a conventional method using a test paper or an electric meter.

[0015] Examples of the alkali comprised in the present composition include an inorganic alkali and an organic alkali. Examples of the inorganic alkali include alkali metal hydroxides such as sodium hydroxide, potassium hydroxide and lithium hydroxide; alkali earth metal hydroxides such as calcium hydroxide and magnesium hydroxide; ammonia and the like. Examples of the organic alkali include amine and salts thereof, for example, ammonium salts such as tetrabutylammonium hydroxide, tributylmethylammonium hydroxide and choline hydroxide. In particular, sodium hydroxide, potassium hydroxide and tetrabutylammonium hydroxide are preferable.

[0016] The amount of the alkali comprised in the present composition is usually from 0.1 to 100 mM, and specifically 0.2 mM, 0.4 mM, 0.8 mM, 1 mM, 2 mM, 4 mM, 6 mM, 8 mM, 10 mM, 20 mM, 40 mM, 60 mM and 80 mM. When the alkali is sodium hydroxide, potassium hydroxide or tetrabutylammonium hydroxide, the amount is usually 0.1 mM or more, and when the alkali is ammonia, the amount is usually 40 mM or more. The amount of the alkali comprised in the present composition can also be expressed in terms of normality, and is usually from 0.03 to 2 N.

[0017] Preferable combinations of the organic solvent and the alkali in the present composition are listed below. The numerical value in parentheses after the organic solvent and the alkali mean the amount (concentration) comprised in the present composition, respectively, and each unit is % by volume <semantics>(v / v)<annotation encoding="application / x-tex">(v / v)< / annotation>< / semantics> for the organic solvent and mM for the alkali. Solvesso 200ND shown below is solvent naphtha manufactured by ExxonMobil. Solvesso 200ND (1, 2, 5) + sodium hydroxide (50, 100, 150, 200) Solvesso 200ND <semantics>(1,2,5)<annotation encoding="application / x-tex">(1, 2, 5)< / annotation>< / semantics> + potassium hydroxide <semantics>(50,100,150,150)<annotation encoding="application / x-tex">(50, 100, 150, 150)< / annotation>< / semantics> 200) Solvesso 200ND (1, 2, 5) + tetrabutylammonium hydroxide (50, 100, 150, 200) Solvesso 200ND (1, 2, 5) + ammonia (50, 100, 150, 200) Cyclohexanone (1, 2, 5) + potassium hydroxide (50, 100, 150, 200) Cyclohexanone <semantics>(1,2,5)<annotation encoding="application / x-tex">(1, 2, 5)< / annotation>< / semantics> + sodium hydroxide <semantics>(50,100,150,<annotation encoding="application / x-tex">(50, 100, 150,< / annotation>< / semantics> 200) Cyclohexanone (1, 2, 5) + tetrabutylammonium hydroxide (50, 100, 150, 200) Cyclohexanone <semantics>(1,2,5)+ammonia(50,100,150,200)<annotation encoding="application / x-tex">(1, 2, 5) + ammonia (50, 100, 150, 200)< / annotation>< / semantics> Tetrahydrofuran (1, 2, 5) + potassium hydroxide (50, 100, 30 150, 200) Tetrahydrofuran <semantics>(1,2,5)+sodium hydroxide (50,100,150,<annotation encoding="application / x-tex">(1, 2, 5) + \text{sodium hydroxide } (50, 100, 150,< / annotation>< / semantics> 200) Tetrahydrofuran <semantics>(1,2,5)+tetrabutylammonium hydroxide (50,5)<annotation encoding="application / x-tex">(1, 2, 5) + \text{tetrabutylammonium hydroxide } (50, 5)< / annotation>< / semantics> 100, 150, 200) Tetrahydrofuran <semantics>(1,2,5)+ammonia(50,100,150,200)<annotation encoding="application / x-tex">(1, 2, 5) + ammonia (50, 100, 150, 200)< / annotation>< / semantics>

[0018] In the present method, bringing the present composition into contact with the article includes both immersing the article itself in the present composition and placing the present composition inside the article. When the present composition is brought into contact with the article, the article may be brought into contact in a state where the present composition is flowing or the flow of the present composition stops. In either case, physical stimulation (friction, grinding, shaking) may be applied. The pressure during contact may be atmospheric pressure, or the pressure can be applied when the present composition is placed inside the article. The article is preferably rinsed with water before contact with the present composition.

[0019] When the article is a pesticide spraying machine, usually, a tank is located upstream, a hose and a pipe are located midstream in no particular order to each other, and a nozzle is located downstream. The above-mentioned upstream, midstream and downstream are usually the directions of the flow of the spray liquid when sprayed. The space through which the spray liquid moves when sprayed is called a spray line. In the present method, usually, the present composition is first present in the tank, and is discharged through the nozzle by natural fall or pressurization, and then the nozzle is closed, and the present composition allowed to stay the nozzle in the spray line for a certain period of time. The present composition is usually prepared by mixing a predetermined amount of an organic solvent and water, and an alkali in an amount that brings the pH 10 or more. In the present method, when the present composition is present in the tank, the present composition prepared in advance may be charged into the tank, or the present composition may be prepared inside the tank by charging an organic solvent, an alkali and water, respectively. Alternatively, the present composition can be prepared inside the tank by charging an organic solvent, an alkali-containing composition (premix formulation) and water, respectively. The order of charge of materials in the preparation of the present composition is not particularly limited, but water (part or all of the final required amount) is desirably present first. During preparation, agitation is usually performed to ensure that the ingredients are uniform.

[0020] When the organic solvent is water insoluble, it is possible to mix with a specific surfactant as an emulsifier to make it compatible with water. In this case, it is desirable to mix the organic solvent with the surfactant in advance.

[0021] The time for which the present composition is allowed to stay in the spray line is usually 1 to 48 hours, preferably 4 to 12 hours, and more preferably 6 to 8 hours. The spray line may be pressurized during all or part of that time, and the pressure is usually within a range of 10 to 100 PSI, and preferably 30 to 50 PSI. Some pesticide spraying machines have a function of circulating the inclusion liquid by flowing it back from the downstream to the upstream of the spray line (recirculation), and recirculation may be performed during part or all of that time. When the present composition is allowed to stay in the spray line, the spray line may be filled with the present composition in its entirety, or may be partially filled with the present composition. For example, the hose may be completely filled, but the tank may be nearly empty. After the present composition is allowed to stay in the spray line for a certain period of time, the present composition is discharged through the nozzle by natural fall or by pressurization. Thereafter, the spray line may be optionally rinsed with running water.

[0023] After cleaning in the present method, the residual value of the active ingredient in the article is less than before cleaning. The level to be achieved varies depending on the contact time between the active ingredient and the article, and between the present composition and the article. The residual rate is usually 0.1 to 50% of the rate before cleaning, and specific cleaning levels include cases where the residual rate is 0.2%, 0.3%, 0.5%, 1%, 2%, 5%, 10%, 20%, 30%, and 40% of the rate before cleaning. These levels may be confirmed by chemical analysis or by bioassay using test organisms.

[0024] Examples of the pesticide spraying machine to be cleaned in the present method include a backpack carbon dioxide gas sprayer, a backpack power sprayer, a boom sprayer, a speed sprayer, pesticide spraying drone and the like. In particular, a boom sprayer is preferable. The boom sprayer may be self-propelled or towed by a tractor. The scale of the pesticide spraying machine is not particularly limited, but is usually 1 L to 10,000 L, preferably 200 to 5,000 L, and more preferably 1,000 to 3,000 L, based on the tank capacity.

[0025] Examples of the active ingredients of pesticides in the present method include herbicides, fungicides, insecticides, safeners and the like. These active ingredients may be residues on the article, but independently, if the article is a pesticide spraying machine, they may also be sprayed by the spraying machine after cleaning. Examples of herbicides include the following: 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA-potassium, 2,3,6-TBA-sodium, 2,4-D, 2,4-D choline salt, 2,4-D-biproamine, 2,4-D-doboxyl, <semantics>2,4−D−2−ethylhexyl,2,4−D−3−butoxypropyl,2,4−D−ammonium,<annotation encoding="application / x-tex">2,4-D-2-ethylhexyl, 2,4-D-3-butoxypropyl, 2,4-D-ammonium,< / annotation>< / semantics> 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-diethylammonium, 2,4-D- dimethylammonium, 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-D-ethyl, 2,4-D-heptylammonium, 2,4-D-isobutyl, 2,4-D- isoctyl, 2,4-D-isopropyl, 2,4-D-isopropylammonium, 2,4-D- lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D- pentyl, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D- tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2- hydroxypropyl) ammonium), 2,4-D-trolamine, 2,4-DB, 2,4-DB choline salt, 2,4-DB-biproamine, 2,4-DB-butyl, 2,4-DB- dimethylammonium, 2,4-DB-isoctyl, 2,4-DB-potassium, 2,4-DB- sodium, acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, ACN (2-amino-3-chloronaphthalene-1,4-dione), alachlor, allidochlor, alloxydim, ametryn, amicarbazone, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor- methyl, aminocyclopyrachlor-potassium, aminopyralid, aminopyralid choline salt, aminopyralid-potassium, aminopyralid-tripromine, amiprophos-methyl, amitrole, anilofos, asulam, atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin-ethyl, bencarbazone, benfluralin, benfuresate, benquitrione, bensulfuron, bensulfuron-methyl, bensulide, bentazon, benthiocarb, benzfendizone, benzobicyclon, benzofenap, benzthiazuron, bialaphos, bicyclopyrone, bifenox, bipyrazone, bispyribac, bispyribac- sodium, bixlozone, broclozone, bromacil, bromobutide, bromofenoxim, bromoxynil, bromoxynil-octanoate, butachlor, butafenacil, butamifos, butralin, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chlomethoxyfen, chloramben, chloridazon, chlorimuron, chlorimuron-ethyl, chlorobromuron, chlorotoluron, chloroxuron, chlorpropham, chlorsulfuron, chlorthal-dimethyl, chlorthiamid, cinidon, cinidon-ethyl, cinmethylin, cinosulfuron, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, clopyralid choline salt, clopyralid-methyl, clopyralid-olamine, clopyralid-potassium, clopyralid-tris(2-hydroxypropyl)ammonium), cloransulam, cloransulam-methyl, cumyluron, cyanazine, cyclopyranil, cycloate, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cypyrafluone, daimuron, dalapon, dazomet, desmedipham, desmetryn, di-allate, dicamba, dicamba choline salt, dicamba-biproamine, dicamba-trolamine, dicamba- diglycolamine, dicamba-dimethylammonium, dicamba-diolamine, dicamba-isopropylammonium, dicamba-methyl, dicamba-olamine, dicamba-potassium, dicamba-sodium, dichlobenil, dichlorprop, dichlorprop choline salt, dichlorprop-biproamine, dichlorprop-etexyl, dichlorprop-butotyl, dichlorprop- dimethylammonium, dichlorprop-ethylammonium, dichlorprop- isoctyl, dichlorprop-methyl, dichlorprop-P, dichlorprop-P choline salt, dichlorprop-P-biproamine, dichlorprop-P-etexyl, dichlorprop-P-dimethylammonium, dichlorprop-potassium, dichlorprop-sodium, diclofop, diclofop-methyl, diclosulam, difenoxuron, difenzoquat, difenzoquat metilsulfate, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimepiperate, dinitramine, dinoseb, dinoterb, dioxopyritrione, diphenamid, diquat, diquat-dibromide, DSMA (disodium methylarsonate), dithiopyr, diuron, DNOC (2-methyl- 4,6-dinitrophenol), esprocarb, epyrifenacil, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethidimuron, ethofumesate, ethoxyfen-ethyl, ethoxysulfuron, etobenzanid, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P- ethyl, fenoxasulfone, fenpyrazone, fenquinotrione, fentrazamide, fenuron, feproxydim, flamprop-M, flazasulfuron, florasulam, florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, fluazolate, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloraminopyr, fluchloraminopyr-tefuryl, flufenacet, flufenoximacil, flufenpyr, flufenpyr-ethyl, flumetsulam, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron, fluoroglycofen-ethyl, flupoxam, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl-sodium, flurenol, fluridone, flurochloridone, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, flurtamone, flusulfinam, fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate choline salt, glyphosate- isopropylammonium, glyphosate-biproamine, glyphosate- ammonium, glyphosate-diammonium, glyphosate-potassium, glyphosate-sodium, glyphosate-trimesium, halauxifen, halauxifen-benzyl, halauxifen-methyl, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop- etotyl, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-etotyl, haloxyfop-P-methyl, hexazinone, icafolin, icafolin-methyl, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox- ammonium, imazamox-sodium, imazapic, imazapic-ammonium, imazapyr, imazapyr-ammonium, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr- ammonium, imazosulfuron, indanofan, indaziflam, indolauxipyr, indolauxipyr-cyanomethyl, iodosulfuron, iodosulfuron-methyl- sodium, iofensulfuron, iofensulfuron-sodium, ioxynil, ioxynil-octanoate, ipfencarbazone, iptriazopyrid, isoproturon, isouron, isoxaben, isoxachlortole, isoxaflutole, lactofen, lenacil, linuron, maleic hydrazide, MCPA (2-(4- chloro-2-methylphenoxy) acetic acid), MCPA choline salt, MCPA- biproamine, MCPA-etexyl, MCPA-butotyl, MCPA-butyl, MCPA- dimethylammonium, MCPA-diolamine, MCPA-ethyl, MCPA-isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-methyl, MCPA-olamine, MCPA-sodium, MCPA-trolamine, MCPB (4-(4-chloro-2- methylphenoxy) butanoic acid), MCPB choline salt, MCPB- biproamine, MCPB-ethyl, MCPB-methyl, MCPB-sodium, mecoprop, mecoprop choline salt, mecoprop-biproamine, mecoprop-2- ethylhexyl, mecoprop-dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-isoctyl, mecoprop-methyl, mecoprop-potassium, mecoprop-sodium, mecoprop-trolamine, mecoprop-P, mecoprop-P choline salt, mecoprop-P-2-ethylhexyl, mecoprop-P-dimethylammonium, mecoprop-P-isobutyl, mecoprop-P- potassium, mefenacet, mesosulfuron, mesosulfuron-methyl, mesotrione, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiozolin, methyldymron, metobromuron, metolachlor, metosulam, metoxuron, metproxybicyclone, metribuzin, metsulfuron, metsulfuron-methyl, molinate, monolinuron, naproanilide, napropamide, napropamide-M, naptalam, neburon, nicosulfuron, norflurazon, oleic acid, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat, paraquat-dichloride, pebulate, pelargonic acid, pendimethalin, penoxsulam, pentanochlor, pentoxazone, pethoxamid, phenisopham, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profluazol, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraquinate, pyraflufen-ethyl, pyrasulfotole, pyrazolynate, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriflubenzoxim, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, quizalofop, quizalofop- ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimisoxafen, rimsulfuron, saflufenacil, sethoxydim, EPTC (S-ethyl N, N-dipropylcarbamothioate), siduron, simazine, simetryn, S-metolachlor, MSMA (sodium hydrogen methylarsonate), sulcotrione, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, swep, TCA (2,2,2-trichloroacetic acid), TCA-ammonium, TCA-calcium, TCA- ethadyl, TCA-magnesium, TCA-sodium, tebutam, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbumeton, terbuthylazine, terbutryn, tetflupyrolimet, thaxtomin A, thenylchlor, thiazopyr, thidiazimin, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, tiafenacil, tiocarbazil, tolpyralate, topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, triclopyr-butotyl, triclopyr-ethyl, triclopyr- triethylammonium, tridiphane, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxazin, trifluralin, triflusulfuron, triflusulfuron-methyl, tripyrasulfone, tritosulfuron, vernolate, 4-(4-fluorophenyl-6-[(2-hydroxy-6- oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine- <semantics>3,5(2H,4H)<annotation encoding="application / x-tex">3,5(2H,4H)< / annotation>< / semantics>-dione, <semantics>2<annotation encoding="application / x-tex">2< / annotation>< / semantics>-chloro-N-<semantics>(1<annotation encoding="application / x-tex">(1< / annotation>< / semantics>-methyl-<semantics>1H<annotation encoding="application / x-tex">1H< / annotation>< / semantics>-tetrazol-<semantics>5<annotation encoding="application / x-tex">5< / annotation>< / semantics>-yl)-<semantics>3<annotation encoding="application / x-tex">3< / annotation>< / semantics>- (methylthio) -4-(trifluoromethyl) benzamide, 2-methyl-N-(5- <semantics>methyl−1,3,4−oxadiazol−2−yl)−3−(methanesulfonyl)−4−<annotation encoding="application / x-tex">methyl-1, 3, 4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-< / annotation>< / semantics> (trifluoromethyl)benzamide, and 1-{2-chloro-6-[(5- chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutane-1-one. Examples of safeners include the following: allidochlor, benoxacor, cloquintocet, cloquintocet- mexyl, cyometrinil, cyprosulfamide, dichlormid, dicyclonone, dimepiperate, disulfoton, daimuron, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, furilazole, fluxofenim, hexim, isoxadifen, isoxadifen-ethyl, Jiecaowan, Jiecaoxi, mecoprop, mefenpyr, mefenpyr-ethyl, mefenpyr- diethyl, mephenate, metcamifen, oxabetrinil, 1,8-naphthalic anhydride, 1,8-octamethylene diamine, AD-67 (4- <semantics>(dichloroacetyl)−1−oxa−4−azaspiro[4.5]decane)<annotation encoding="application / x-tex">(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane)< / annotation>< / semantics>, MCPA <semantics>(2−(4−<annotation encoding="application / x-tex">(2-(4-< / annotation>< / semantics> chloro-2-methylphenoxy) acetic acid), CL-304415 (4-carboxy- 3,4-dihydro-2H-1-benzopyran-4-acetic acid), CSB (1-bromo-4- [(chloromethyl)sulfonyl]benzene), DKA-24 (2,2-dichloro-N-[2- oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide), MG191 <semantics>(2−(dichloromethyl)−2−methyl−1,3−dioxolane),MG−838(2−<annotation encoding="application / x-tex">(2-(dichloromethyl)-2-methyl-1,3-dioxolane), MG-838 (2-< / annotation>< / semantics> propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate), PPG- <semantics>1292(2,2−dichloro−N−(1,3−dioxan−2−ylmethyl)−N−(2−<annotation encoding="application / x-tex">1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-< / annotation>< / semantics> propenyl)acetamide), R-28725 (3-(dichloroacetyl)-2,2- <semantics>dimethyl−1,3−oxazolidine)<annotation encoding="application / x-tex">dimethyl-1, 3-oxazolidine)< / annotation>< / semantics>, <semantics>R−29148<annotation encoding="application / x-tex">R-29148< / annotation>< / semantics> (3-(<semantics>dichloroacetyl)−2,2,5−<annotation encoding="application / x-tex">dichloroacetyl)-2, 2, 5-< / annotation>< / semantics> <semantics>trimethyl−1,3−oxazolidine)<annotation encoding="application / x-tex">trimethyl-1,3-oxazolidine)< / annotation>< / semantics>, and <semantics>TI−35<annotation encoding="application / x-tex">TI-35< / annotation>< / semantics> (1- (dichloroacetyl) azepane). Examples of insecticides include the following: abamectin, acephate, acequinocyl, acetamiprid, acetoprole, acrinathrin, acynonapyr, afidopyropen, afoxolaner, alanycarb, aldicarb, allethrin, alpha- cypermethrin, alpha-endosulfan, aluminium phosphide, amitraz, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotin, bark of Celastrus angulatus, bendiocarb, benfluthrin, benfuracarb, bensultap, benzoximate, benzpyrimoxan, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bilobalide, bioallethrin, bioresmethrin, bistrifluron, borax, boric acid, broflanilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, calcium cyanide, calcium phosphide, carbaryl, carbofuran, carbosulfan, cartap hydrochloride, cartap, cevadine, chinomethionat, chlorantraniliprole, chlordane, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chloropicrin, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine, clothianidin, concanamycin A, coumaphos, cryolite, cyanophos, cyantraniliprole, cyclaniliprole, cyclobutrifluram, cycloprothrin, cycloxaprid, cyenopyrafen, cyetpyrafen, cyflumetofen, cyfluthrin, cyhalodiamide, cyhalothrin, cyhexatin, cypermethrin, cyphenothrin, cyproflanilide, cyromazine, dazomet, deltamethrin, demeton-S-methyl, diafenthiuron, Diatomaceous earth, diazinon, dichlorvos, dicloromezotiaz, dicofol, dicrotophos, diflovidazin, diflubenzuron, dimefluthrin, dimethoate, dimethylvinphos, dimpropyridaz, dinotefuran, disodium octaborate, disulfoton, DNOC (2-methyl-4,6-dinitrophenol), doramectin, dried leaves of Dryopteris filix-mas, emamectin-benzoate, empenthrin, endosulfan, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate, epsilon-metofluthrin, epsilon- momfluorothrin, esfenvalerate, ethiofencarb, ethion, ethiprole, ethoprophos, etofenprox, etoxazole, extract of Artemisia absinthium, extract of Cassia nigricans, extract of clitoria ternatea, extract of Pyrethrum, extract of Symphytum officinale, extracts or simulated blend of Chenopodium ambrosioides, extract of Tanacetum vulgare, extract of Urtica dioica, extract of Viscum album, famphur, fenamiphos, fenazaquin, fenbutatin oxide, fenitrothion, fenmezoditiaz, fenobucarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flometoquin, flonicamid, fluacrypyrim, fluazaindolizine, fluazuron, flubendiamide, fluchlordiniliprole, flucycloxuron, flucythrinate, fluensulfone, flufenoprox, flufenoxuron, flufiprole, flumethrin, flupentiofenox, fluopyram, flupyroxystrobin, flupyradifurone, flupyrimin, fluralaner, fluvalinate, fluxametamide, formetanate, fosthiazate, furamethrin, furathiocarb, gamma-cyhalothrin, ginkgolide A, ginkgolide B, ginkgolide C, ginkgolide J, ginkgolide M, GS-omega / kappa HXTX-Hvla peptide, halfenprox, halofenozide, heptafluthrin, heptenophos, hexaflumuron, hexythiazox, potassium salt of hop beta acid, hydramethylnon, hydroprene, imicyafos, imidacloprid, imidaclothiz, imiprothrin, indazapyroxamet, indoxacarb, isocycloseram, isofenphos, isoflualanam, isoprocarb, isopropyl-O- (methoxyaminothiophosphoryl) salicylate, isoxathion, ivermectin, kadethrin, kappa-tefluthrin, kappa-bifenthrin, kinoprene, lambda-cyhalothrin, ledprona, lenoremycin, lepimectin, lime sulfur, lotilaner, lufenuron, machine oil, malathion, mecarbam, meperfluthrin, metaflumizone, metam, methamidophos, methidathion, methiocarb, methomyl, methoprene, methoxychlor, methoxyfenozide, methyl bromide, metofluthrin, metolcarb, metoxadiazone, mevinphos, milbemectin, milbemycin oxime, mivorilaner, modoflaner, momfluorothrin, monocrotophos, moxidectin, naled, extract of Azadirachta indica, nicofluprole, nicotine, nicotine-sulfate, nitenpyram, novaluron, noviflumuron, oil of the seeds of Chenopodium anthelminticum, omethoate, oxamyl, oxazosulfyl, oxydemeton-methyl, parathion, parathion-methyl, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet, phosphamidon, phosphine, phoxim, piperflanilide, pirimicarb, pirimiphos-methyl, potassium cyanide, prallethrin, profenofos, profluthrin, propargite, propetamphos, propoxur, propylene glycol alginate, prothiofos, pyflubumide, pymetrozine, pyraclofos, pyrethrins, pyridaben, pyridalyl, pyridaphenthion, pyrifluquinazone, pyrimidifen, pyriminostrobin, pyriprole, pyriproxyfen, quinalphos, resmethrin, rotenone, ryanodine, sarolaner, seed extract of Schoenocaulon spp., selamectin, sigma-cypermethrin, silafluofen, sodium borate, sodium cyanide, sodium metaborate, spidoxamat, spinetoram, spinosad, spirodiclofen, spiromesifen, spiropidion, spirotetramat, sulfiflumin, sulfluramid, sulfotep, sulfoxaflor, sulfur, sulfuryl fluoride, tartar emetic, tau-fluvalinate, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temephos, terbufos, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460, tetrachlorantraniliprole, tetrachlorvinphos, tetradifon, tetramethrin, tetramethylfluthrin, tetraniliprole, theta-cypermethrin, thiacloprid, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, thiosultap-disodium, thiosultap-monosodium, tigolaner, tioxazafen, tolfenpyrad, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, trifluenfuronate, triflumezopyrim, triflumuron, trimethacarb, tyclopyrazoflor, umifoxolaner, vamidothion, veratridine, wood extract of Quassia amara, XMC (3,5-dimethylphenyl N- methylcarbamate), xylylcarb, zeta-cypermethrin, zinc phosphide, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N- ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923- <semantics>37−7<annotation encoding="application / x-tex">37-7< / annotation>< / semantics>), <semantics>4−[5−(3,5−dichlorophenyl)−5−(trifluoromethyl)−4,5−<annotation encoding="application / x-tex">4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-< / annotation>< / semantics> dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3- yl) benzamide <semantics>(1241050−20−3)<annotation encoding="application / x-tex">(1241050-20-3)< / annotation>< / semantics>, 3-methoxy-N-<semantics>(5−{5−10000000000000000000000000000000000<annotation encoding="application / x-tex">(5-\{5-10000000000000000000000000000000000< / annotation>< / semantics> (trifluoromethyl) -5-[3-(trifluoromethyl) phenyl] -4,5-dihydro- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>1,2-oxazol-3-yl\}indan-1-yl)propanamide (1118626-57-5), 2-({2- fluoro-4-methyl-5-<semantics>[(2,2,2−<annotation encoding="application / x-tex">[(2,2,2-< / annotation>< / semantics> trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2- <semantics>trifluoroethyl)−1,3−thiazolidin−4−one(1445683−71−5),N−<annotation encoding="application / x-tex">trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5), N-< / annotation>< / semantics> <semantics>[(1S,2S)−2−(2,4−dichlorophenyl)cyclobutyl]−2−<annotation encoding="application / x-tex">[(1S, 2S)-2-(2, 4-dichlorophenyl) cyclobutyl]-2-< / annotation>< / semantics> (trifluoromethyl)pyridine-3-carboxamide, N-{4-chloro-3-[(1- cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4- <semantics>(methanesulfonyl)−3−(1,1,2,2,2−pentafluoroethyl)−1H−pyrazole−<annotation encoding="application / x-tex">(methanesulfonyl) -3 - (1, 1, 2, 2, 2 - pentafluoroethyl) -1H-pyrazole-< / annotation>< / semantics> <semantics>3−carboxamide(1400768−21−9),N−[3−chloro−1−(pyridin−3−yl)−<annotation encoding="application / x-tex">3-carboxamide (1400768-21-9), N-[3-chloro-1-(pyridin-3-yl)-< / annotation>< / semantics> 1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83- 2), <semantics>N−[4−chloro−2−(pyridin−3−yl)−1,3−thiazol−5−yl]−N−ethyl−3−<annotation encoding="application / x-tex">N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-< / annotation>< / semantics> (methanesulfonyl)propanamide, 1,4-dimethyl-2-[2-(pyridin-3- yl)-2H-indol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09- 3), <semantics>2−isopropyl−5−[(3,4,4−trifluoro−3−buten−1−yl)sulfonyl]−<annotation encoding="application / x-tex">2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-< / annotation>< / semantics> 1,3,4-thiadiazole (2058052-95-0), <semantics>N−({2−fluoro−4−[(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)−2−(2S,3S)<annotation encoding="application / x-tex">N-(\{2-\text{fluoro}-4-[(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)-2-(2S,3S)< / annotation>< / semantics> hydroxy-3-(3,4,5-trichlorophenyl)-3- (trifluoromethyl)pyrrolidin-1- yl]phenyl}methyl)cyclopropanecarboxamide, 7-fluoro-N-[1- (methylsulfanyl) -2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H- indazole-4-carboxamide, 7-fluoro-N-[1-(methanesulfinyl)-2- methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4- carboxamide, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan- <semantics>2−y1]−2−(pyridin−3−y1)−2H−indazole−4−carboxamide,N−[1−<annotation encoding="application / x-tex">2-y1]-2-(pyridin-3-y1)-2H-indazole-4-carboxamide, N-[1-< / annotation>< / semantics> (difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4- carboxamide, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)- 10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7), Bacillus thuringiensis Cry1Ab protein, Bacillus thuringiensis CrylAc protein, Bacillus thuringiensis Cry1Fa protein, Bacillus thuringiensis Cry1A.105 protein, Bacillus thuringiensis Cry2Ab protein, Bacillus thuringiensis Vip3A protein, Bacillus thuringiensis mCry3A protein, Bacillus thuringiensis Cry3Ab protein, Bacillus thuringiensis Cry3Bb protein, Bacillus thuringiensis Cry34Ab1 / Cry35Ab1 protein, insecticidal protein Tma12 derived from Tactaria macrodonata, insecticidal protein IPD083 derived from Adiantum spp., and insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa. Examples of fungicides include the following: acibenzolar-S-methyl, aldimorph, ametoctradin, aminopyrifen, amisulbrom, ammonium salts of phosphorous acid, anilazine, azaconazole, azoxystrobin, basic copper sulfate, benalaxyl, benalaxyl-M, benodanil, benomyl, benthiavalicarb, benthiavalicarb-isopropyl, benzovindiflupyr, binapacryl, biphenyl, bitertanol, bixafen, blasticidin-S, Bordeaux mixture, boscalid, bromothalonil, bromuconazole, bupirimate, calcium salts of phosphorous acid, captafol, captan, carbendazim, carboxin, carpropamid, chinomethionat, chitin, chloroinconazide, chloroneb, chlorothalonil, chlozolinate, colletochlorin B, copper(II) acetate, copper(II) hydroxide, copper oxychloride, copper(II) sulfate, coumoxystrobin, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dichlobentiazox, dichlofluanid, diclocymet, diclomezine, dicloran, diethofencarb, difenoconazole, diflumetorim, dimethachlone, dimethirimol, dimethomorph, dimoxystrobin, diniconazole, diniconazole-M, dinocap, dipotassium hydrogenphosphite, dipymetitrone, dithianon, dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt, dodemorph, dodine, edifenphos, enoxastrobin, epoxiconazole, etaconazole, ethaboxam, ethirimol, etridiazole, extract of Melaleuca alternifolia, extract of Reynoutria sachalinensis, extract of the cotyledons of lupine plantlets ("BLAD"), extract of Allium sativum, extract of Equisetum arvense, extract of Tropaeolum majus, famoxadone, fenamidone, fenaminstrobin, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpicoxamid, fenpropidin, fenpropimorph, fenpyrazamine, fentin acetate, fentin chloride, fentin hydroxide, ferbam, ferimzone, florylpicoxamid, fluazinam, flubeneteram, fludioxonil, flufenoxadiazam, flufenoxystrobin, fluindapyr, flumetylsulforim, flumorph, fluopicolide, fluopimomide, fluopyram, fluoroimide, fluoxapiprolin, fluoxastrobin, fluoxytioconazole, fluquinconazole, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, fluxapyroxad, folpet, fosetyl, fosetyl-aluminium, fuberidazole, furalaxyl, furametpyr, quazatine, hexaconazole, hymexazole, imazalil, imibenconazole, iminoctadine, iminoctadine triacetate, iminoctadine trialbesilate, inpyrfluxam, iodocarb, ipconazole, ipfentrifluconazole, ipflufenoquin, iprobenfos, iprodione, iprovalicarb, isofetamid, isoflucypram, isoprothiolane, isopyrazam, isotianil, kasugamycin, kresoxim-methyl, laminarin, leaves and bark of Quercus, mancozeb, mandestrobin, mandipropamid, maneb, mefentrifluconazole, mepanipyrim, mepronil, meptyldinocap, metalaxyl, metalaxyl-M, metarylpicoxamid, metconazole, methasulfocarb, metiram, metominostrobin, metrafenone, metyltetraprole, mineral oils, myclobutanil, naftifine, extract of Azadirachta indica, nuarimol, octhilinone, ofurace, orysastrobin, oxadixyl, oxathiapiprolin, oxine-copper, oxolinic acid, oxpoconazole, oxpoconazole fumarate, oxycarboxin, oxytetracycline, pefurazoate, penconazole, pencycuron, penflufen, penthiopyrad, phenamacril, phosphorous acid, phthalide, picarbutrazox, picoxystrobin, piperalin, polyoxins, potassium hydrogencarbonate, potassium dihydrogenphosphite, probenazole, prochloraz, procymidone, propamidine, propamocarb, propiconazole, propineb, proquinazid, prothiocarb, prothioconazole, pydiflumetofen, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyrapropoyne, pyraziflumid, pyrazophos, pyribencarb, pyributicarb, pyridachlometyl, pyrifenox, pyrimethanil, pyrimorph, pyriofenone, pyrisoxazole, pyroquilon, Quillaja extract, quinconazole, quinofumelin, quinoxyfen, quintozene, saccharin, saccharin sodium, saccharin potassium, saccharin calcium, saccharin ammonium, saccharin salt, aponins of Chenopodium quinoa, seboctylamine, sedaxane, silthiofam, simeconazole, sodium hydrogencarbonate, sodium salts of phosphorous acid, spiroxamine, streptomycin, sulfur, tebuconazole, tebufloquin, teclofthalam, tecnazene, terbinafine, tetraconazole, thiabendazole, thifluzamide, thiophanate, thiophanate-methyl, thiram, thymol, tiadinil, tolclofos-methyl, tolfenpyrad, tolprocarb, tolylfluanid, triadimefon, triadimenol, triazoxide, triclopyricarb, tricyclazole, tridemorph, trifloxystrobin, triflumizole, triforine, triticonazole, validamycin, valifenalate, vinclozolin, yellow mustard powder, zineb, zinc thiazole, ziram, zoxamide, 3- <semantics>(difluoromethyl)−N−methoxy−1−methyl−N−[(1R)−1−methyl−2−1]<annotation encoding="application / x-tex">(difluoromethyl) - N - methoxy - 1 - methyl - N - [(1R) - 1 - methyl - 2 - 1]< / annotation>< / semantics> (2,4,6-trichlorophenyl)ethyl]pyrazole-4-carboxamide (1639015- <semantics>48−7<annotation encoding="application / x-tex">48-7< / annotation>< / semantics>), <semantics>3−(difluoromethyl)−N−methoxy−1−methyl−N−[(1S)−1−<annotation encoding="application / x-tex">3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-< / annotation>< / semantics> methyl-2-(2,4,6-trichlorophenyl)ethyl]pyrazole-4-carboxamide <semantics>(1639015−49−8)<annotation encoding="application / x-tex">(1639015-49-8)< / annotation>< / semantics>, 3-<semantics>(difluoromethyl)−1−methyl−N−(1,1,3−<annotation encoding="application / x-tex">(difluoromethyl)-1-methyl-N-(1,1,3-< / annotation>< / semantics> trimethylindan-4-yl)pyrazole-4-carboxamide (141573-94-6), 3- <semantics>(difluoromethyl)−N−[(3R)−7−fluoro−1,1,3−trimethylindan−4−yl]−<annotation encoding="application / x-tex">(difluoromethyl) - N - [(3R) - 7 - fluoro - 1, 1, 3 - trimethylindan - 4 - yl] -< / annotation>< / semantics> 1-methylpyrazole-4-carboxamide (1513466-73-3), <Formule mathématique disponible dans le document PDF, Math available in the PDF document>N'-[4-({3-[(4- chlorophenyl) methyl] <semantics>−1<annotation encoding="application / x-tex">-1< / annotation>< / semantics>, 2, 4-thiadiazol-5-yl<semantics>}<annotation encoding="application / x-tex">\}< / annotation>< / semantics>oxy) <semantics>−2<annotation encoding="application / x-tex">-2< / annotation>< / semantics>, 5- dimethylphenyl]-N-ethyl-N-methylmethaneimideamide (1202781- 91-6), <semantics>N′−{4−[(4,5−dichlorothiazol−2−yl)oxy]−2,5−yl)<annotation encoding="application / x-tex">N' - \{4 - [(4, 5 - dichlorothiazol - 2 - yl) oxy] - 2, 5 - yl)< / annotation>< / semantics> dimethylphenyl}-N-ethyl-N-methylmethaneimideamide (929908-57- 6), <semantics>N′−(2,5−dimethyl−4−phenoxyphenyl)−N−ethyl−N−<annotation encoding="application / x-tex">N' - (2, 5-dimethyl-4-phenoxyphenyl) - N-ethyl-N-< / annotation>< / semantics> methylmethaneimideamide <semantics>(1052688−31−9)<annotation encoding="application / x-tex">(1052688-31-9)< / annotation>< / semantics>, <semantics>N′−[5−chloro−4−(2−<annotation encoding="application / x-tex">N'-[5-chloro-4-(2-< / annotation>< / semantics> fluorophenoxy) -2-methylphenyl] -N-ethyl-N- methylmethaneimideamide <semantics>(2055589−28−9)<annotation encoding="application / x-tex">(2055589-28-9)< / annotation>< / semantics>, <semantics>N′−[2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chloro−4−(2−chlo<annotation encoding="application / x-tex">N'-[2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chloro-4-(2-chlo< / annotation>< / semantics> fluorophenoxy) -5-methylphenyl] -N-ethyl-N- methylmethaneimideamide <semantics>(2055756−21−1)<annotation encoding="application / x-tex">(2055756-21-1)< / annotation>< / semantics>, N'-<semantics>(2−chloro−4−<annotation encoding="application / x-tex">(2-chloro-4-< / annotation>< / semantics> phenoxy-5-methylphenyl)-N-ethyl-N-methylmethaneimideamide <semantics>(2062599−39−5)<annotation encoding="application / x-tex">(2062599-39-5)< / annotation>< / semantics>, N'-<semantics>[4−(1−hydroxy−1−phenyl−2,2,2−<annotation encoding="application / x-tex">[4-(1-hydroxy-1-phenyl-2,2,2-< / annotation>< / semantics> trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N- methylmethaneimideamide (2101814-55-3), <semantics>N′−[5−bromo−6−(1−bromo−6)]<annotation encoding="application / x-tex">N'-[5-bromo-6-(1-bromo-6)]< / annotation>< / semantics> methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N- methylmethaneimideamide <semantics>(1817828−69−5)<annotation encoding="application / x-tex">(1817828-69-5)< / annotation>< / semantics>, <semantics>4−(2−bromo−4−<annotation encoding="application / x-tex">4-(2-bromo-4-< / annotation>< / semantics> fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H- <semantics>pyrazole−5−amine(1362477−26−6)<annotation encoding="application / x-tex">pyrazole-5-amine(1362477-26-6)< / annotation>< / semantics>, <semantics>2−[6−(3−fluoro−4−6)]<annotation encoding="application / x-tex">2-[6-(3-fluoro-4-6)]< / annotation>< / semantics> methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97- 5), ethyl <semantics>(2Z)−3<annotation encoding="application / x-tex">(2Z)-3< / annotation>< / semantics>-amino-2-cyano-3-phenylacrylate <semantics>(39491−78−6)<annotation encoding="application / x-tex">(39491-78-6)< / annotation>< / semantics>, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3- nitropyridine-2-amine (1446247-98-8), <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-[3-(4-chloro-2- fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3- pyridinemethanol (1229605-96-2), <semantics>(αS)−[3−(4−chloro−2−<annotation encoding="application / x-tex">(\alpha S) - [3-(4-chloro-2-< / annotation>< / semantics> fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3- pyridinemethanol (1229606-46-5), <semantics>(αR)−[3−(4−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro−2−chloro<annotation encoding="application / x-tex">(\alpha R) - [3 - (4 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro} - 2 - \text{chloro}< / annotation>< / semantics> fluorophenyl)-5-(2,4-difluorophenyl)-4-isoxazolyl]-3- pyridinemethanol <semantics>(1229606−02−3)<annotation encoding="application / x-tex">(1229606-02-3)< / annotation>< / semantics>, <semantics>5−(4−chlorobenzyl)−2−<annotation encoding="application / x-tex">5-(4-chlorobenzyl)-2-< / annotation>< / semantics> chloromethyl-2-methyl-1-<semantics>(1H−1,2,4−triazol−1−<annotation encoding="application / x-tex">(1H-1,2,4-triazol-1-< / annotation>< / semantics> ylmethyl)cyclopentanol <semantics>(1394057−11−4)<annotation encoding="application / x-tex">(1394057-11-4)< / annotation>< / semantics>, <semantics>(1R,2S,5S)−5−(4−11−4)<annotation encoding="application / x-tex">(1R, 2S, 5S)-5-(4-11-4)< / annotation>< / semantics> chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanol (1801930-06-2), (1S,2R,5R)-5-(4- chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl) cyclopentanol <semantics>(1801930−07−3)<annotation encoding="application / x-tex">(1801930-07-3)< / annotation>< / semantics>, <semantics>(1R,2R,5R)−5−(4−1801930−07−3)<annotation encoding="application / x-tex">(1R, 2R, 5R)-5-(4-1801930-07-3)< / annotation>< / semantics> chlorobenzyl) -2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl) cyclopentanol <semantics>(1801919−53−8)<annotation encoding="application / x-tex">(1801919-53-8)< / annotation>< / semantics>, <semantics>(1S,2S,5S)−5−(4−8)<annotation encoding="application / x-tex">(1S, 2S, 5S)-5-(4-8)< / annotation>< / semantics> chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanol <semantics>(1801919−54−9)<annotation encoding="application / x-tex">(1801919-54-9)< / annotation>< / semantics>, <semantics>(1R,2R,5S)−5−(4−9)<annotation encoding="application / x-tex">(1R, 2R, 5S)-5-(4-9)< / annotation>< / semantics> chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanol <semantics>(1801919−55−0)<annotation encoding="application / x-tex">(1801919-55-0)< / annotation>< / semantics>, <semantics>(1S,2S,5R)−5−(4−5)<annotation encoding="application / x-tex">(1S, 2S, 5R)-5-(4-5)< / annotation>< / semantics> chlorobenzyl) -2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl) cyclopentanol <semantics>(1801919−56−1)<annotation encoding="application / x-tex">(1801919-56-1)< / annotation>< / semantics>, <semantics>(1R,2S,5R)−5−(4−1)<annotation encoding="application / x-tex">(1R, 2S, 5R)-5-(4-1)< / annotation>< / semantics> chlorobenzyl)-2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl) cyclopentanol <semantics>(1801919−57−2)<annotation encoding="application / x-tex">(1801919-57-2)< / annotation>< / semantics>, <semantics>(1S,2R,5S)−5−(4−<annotation encoding="application / x-tex">(1S, 2R, 5S)-5-(4-< / annotation>< / semantics> chlorobenzyl) -2-chloromethyl-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanol (1801919-58-3), 2-chloromethyl-5-(4- fluorobenzyl) <semantics>−2<annotation encoding="application / x-tex">-2< / annotation>< / semantics>-methyl-1-<semantics>(1H−1,2,4<annotation encoding="application / x-tex">(1H-1,2,4< / annotation>< / semantics>-triazol-1- ylmethyl)cyclopentanol (1394057-13-6), (1R,2S,5S)-2- chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)cyclopentanol(1801930−08−4),(1S,2R,5R)−2−<annotation encoding="application / x-tex">1-ylmethyl) cyclopentanol (1801930-08-4), (1S, 2R, 5R) -2-< / annotation>< / semantics> chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)cyclopentanol(1801930−09−5),(1R,2R,5R)−2−<annotation encoding="application / x-tex">1-ylmethyl) cyclopentanol (1801930-09-5), (1R, 2R, 5R) -2-< / annotation>< / semantics> chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)<annotation encoding="application / x-tex">1-ylmethyl)< / annotation>< / semantics> cyclopentanol (1638898-08-4), (1S,2S,5S)-2- chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)cyclopentanol(1638898−10−8),(1R,2R,5S)−2−<annotation encoding="application / x-tex">1-ylmethyl) cyclopentanol (1638898-10-8), (1R, 2R, 5S) -2-< / annotation>< / semantics> chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)cyclopentanol(1638898−13−1),(1S,2S,5R)−2−<annotation encoding="application / x-tex">1-ylmethyl) cyclopentanol (1638898-13-1), (1S, 2S, 5R) -2-< / annotation>< / semantics> chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)cyclopentanol(1638898−16−4),(1R,2S,5R)−2−<annotation encoding="application / x-tex">1-ylmethyl) cyclopentanol (1638898-16-4), (1R, 2S, 5R) -2-< / annotation>< / semantics> chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- 1-ylmethyl)cyclopentanol (1638898-20-0), (1S,2R,5S)-2- chloromethyl-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol- <semantics>1−ylmethyl)<annotation encoding="application / x-tex">1-ylmethyl)< / annotation>< / semantics> cyclopentanol (1638898-24-4), methyl=3-[(4- chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol- 1-ylmethyl)cyclopentanecarboxylate (1791398-02-1), <semantics>methyl=(1R,2S,3S)−3−[(4−chlorophenyl)methyl]−2−hydroxy−1−1−1−2−2−2−2−2−2−2<annotation encoding="application / x-tex">methyl = (1R, 2S, 3S) - 3 - [(4-chlorophenyl)methyl] - 2 - hydroxy - 1 - 1 - 1 - 2 - 2 - 2 - 2 - 2 - 2 - 2< / annotation>< / semantics> methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate <semantics>(2080743−90−2)<annotation encoding="application / x-tex">(2080743-90-2)< / annotation>< / semantics>, methyl=<semantics>(1S,2R,3R)−3−[(4−chlorophenyl)methyl]−<annotation encoding="application / x-tex">(1S, 2R, 3R)-3-[(4-chlorophenyl)methyl]-< / annotation>< / semantics> 2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanecarboxylate (2080743-91-3), <semantics>methyl=(1R,2R,3R)−3−[(4−chlorophenyl)methyl]−2−hydroxy−1−1−1−1−2−2−2−2−2−2<annotation encoding="application / x-tex">methyl = (1R, 2R, 3R) - 3 - [(4-chlorophenyl)methyl] - 2 - hydroxy - 1 - 1 - 1 - 1 - 2 - 2 - 2 - 2 - 2 - 2< / annotation>< / semantics> methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate <semantics>(2080743−92−4)<annotation encoding="application / x-tex">(2080743-92-4)< / annotation>< / semantics>, methyl=<semantics>(1S,2S,3S)−3−[(4−chlorophenyl)methyl]−<annotation encoding="application / x-tex">(1S, 2S, 3S)-3-[(4-chlorophenyl)methyl]-< / annotation>< / semantics> <semantics>2−hydroxy−1−methyl−2−(1H−1,2,4−triazol−1−<annotation encoding="application / x-tex">2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-< / annotation>< / semantics> ylmethyl)cyclopentanecarboxylate (2080743-93-5), <semantics>methyl=(1R,2R,3S)−3−[(4−chlorophenyl)methyl]−2−hydroxy−1−1−1−1−2−2−2−2−2−2<annotation encoding="application / x-tex">methyl = (1R, 2R, 3S) - 3 - [(4-chlorophenyl)methyl] - 2 - hydroxy - 1 - 1 - 1 - 1 - 2 - 2 - 2 - 2 - 2 - 2< / annotation>< / semantics> methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate <semantics>(2080743−94−6)<annotation encoding="application / x-tex">(2080743-94-6)< / annotation>< / semantics>, methyl=<semantics>(1S,2S,3R)−3−[(4−chlorophenyl)methyl]−<annotation encoding="application / x-tex">(1S, 2S, 3R)-3-[(4-chlorophenyl)methyl]-< / annotation>< / semantics> <semantics>2−hydroxy−1−methyl−2−(1H−1,2,4−triazol−1−<annotation encoding="application / x-tex">2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-< / annotation>< / semantics> ylmethyl)cyclopentanecarboxylate (2080743-95-7), <semantics>methyl=(1R,2S,3R)−3−[(4−chlorophenyl)methyl]−2−hydroxy−1−1−1−1−2−2−2−2−2−2<annotation encoding="application / x-tex">methyl = (1R, 2S, 3R) - 3 - [(4-chlorophenyl)methyl] - 2 - hydroxy - 1 - 1 - 1 - 1 - 2 - 2 - 2 - 2 - 2 - 2< / annotation>< / semantics> methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanecarboxylate <semantics>(2081061−22−3)<annotation encoding="application / x-tex">(2081061-22-3)< / annotation>< / semantics>, methyl=<semantics>(1S,2R,3S)−3−[(4−chlorophenyl)methyl]−<annotation encoding="application / x-tex">(1S, 2R, 3S)-3-[(4-chlorophenyl)methyl]-< / annotation>< / semantics> <semantics>2−hydroxy−1−methyl−2−(1H−1,2,4−triazol−1−<annotation encoding="application / x-tex">2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-< / annotation>< / semantics> ylmethyl)cyclopentanecarboxylate <semantics>(2081061−23−4)<annotation encoding="application / x-tex">(2081061-23-4)< / annotation>< / semantics>, <semantics>1−(2,4−<annotation encoding="application / x-tex">1-(2,4-< / annotation>< / semantics> <semantics>difluorophenyl)−2−(1H−1,2,4−triazol−1−yl)−1−[1−(4−bromo−2,6−<annotation encoding="application / x-tex">difluorophenyl) -2 - (1H-1, 2, 4-triazol-1-yl) -1 - [1-(4-bromo-2, 6-< / annotation>< / semantics> <semantics>difluorophenoxy)<annotation encoding="application / x-tex">difluorophenoxy)< / annotation>< / semantics> cyclopropyl]ethanol (2019215-86-0), 1-(2,4- difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6- <semantics>difluorophenoxy)<annotation encoding="application / x-tex">difluorophenoxy)< / annotation>< / semantics> cyclopropyl]ethanol (2019215-84-8), 1-[2-(1- chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H- <semantics>imidazole−5−carbonitrile(2018316−13−5),1−[2−(1−<annotation encoding="application / x-tex">imidazole-5-carbonitrile (2018316-13-5), 1-[2-(1-< / annotation>< / semantics> chlorocyclopropyl) -3-(2,3-difluorophenyl) -2-hydroxypropyl]- <semantics>1H−imidazole−5−carbonitrile<annotation encoding="application / x-tex">1H-imidazole-5-carbonitrile< / annotation>< / semantics> (2018317-25-2), <semantics>2−[6−(4−imidazole−5−carbonitrile]<annotation encoding="application / x-tex">2-[6-(4-imidazole-5-carbonitrile]< / annotation>< / semantics> bromophenoxy) -2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4- <semantics>triazol−1−yl)propan−2−ol(2082661−43−4),2−[6−(4−4)]<annotation encoding="application / x-tex">triazol-1-yl)propan-2-ol (2082661-43-4), 2-[6-(4-4)]< / annotation>< / semantics> chlorophenoxy) -2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4- <semantics>triazol−1−yl)<annotation encoding="application / x-tex">triazol-1-yl)< / annotation>< / semantics> propan-2-ol (2082660-27-1), <semantics>methyl=(2−methyl−5−<annotation encoding="application / x-tex">methyl=({2-methyl-5-}< / annotation>< / semantics> <semantics>[1−(4−methoxy−2−methylphenyl)−1H−pyrazol−3−<annotation encoding="application / x-tex">[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-< / annotation>< / semantics> <semantics>yl]phenyl}methyl)carbamate(1605879−98−8),2−<annotation encoding="application / x-tex">yl]phenyl\}methyl)carbamate (1605879-98-8), 2-< / annotation>< / semantics> <semantics>(difluoromethyl)−N−[1,1,3−trimethyl−2,3−dihydro−1H−inden−4−1]<annotation encoding="application / x-tex">(difluoromethyl) - N - [1, 1, 3 - trimethyl - 2, 3 - dihydro - 1H - inden - 4 - 1]< / annotation>< / semantics> yl]pyridine-3-carboxamide (1616239-21-4), 2-(difluoromethyl)- <semantics>N−[(3R)−1,1,3−trimethyl−2,3−dihydro−1H−inden−4−yl]pyridine−3−<annotation encoding="application / x-tex">N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-< / annotation>< / semantics> carboxamide <semantics>(1616239−33−8)<annotation encoding="application / x-tex">(1616239-33-8)< / annotation>< / semantics>, <semantics>2−(difluoromethyl)−N−[3−ethyl−<annotation encoding="application / x-tex">2-(difluoromethyl)-N-[3-ethyl-< / annotation>< / semantics> 1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide <semantics>(1847460−02−9)<annotation encoding="application / x-tex">(1847460-02-9)< / annotation>< / semantics>, 2-<semantics>(difluoromethyl)−N−[(3R)−3−ethyl−1,1−<annotation encoding="application / x-tex">(difluoromethyl)-N-[(3R)-3-ethyl-1,1-< / annotation>< / semantics> dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide <semantics>(1952305−97−3)<annotation encoding="application / x-tex">(1952305-97-3)< / annotation>< / semantics>, 2-<semantics>(difluoromethyl)−N−[3−propyl−1,1−dimethyl−1]<annotation encoding="application / x-tex">(difluoromethyl)-N-[3-propyl-1,1-dimethyl-1]< / annotation>< / semantics> 2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05- 2), <semantics>2−(difluoromethyl)−N−[(3R)−3−propyl−1,1−dimethyl−2,3−<annotation encoding="application / x-tex">2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-< / annotation>< / semantics> dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1), <semantics>(2E,3Z)−5−{[1−(4−chlorophenyl)−1H−pyrazol−3−yl]oxy}−2−(2E,3Z)−5−{[1−(4−chlorophenyl)−1H−pyrazol−3−yl]oxy}−2−(2E,3Z)−5−{[1−(4−chlorophenyl)−1H−pyrazol−3−yl<annotation encoding="application / x-tex">(2E, 3Z) - 5 - \{ [1 - (4 - chlorophenyl) - 1H - pyrazol - 3 - yl] oxy \} - 2 - (2E, 3Z) - 5 - \{ [1 - (4 - chlorophenyl) - 1H - pyrazol - 3 - yl] oxy \} - 2 - (2E, 3Z) - 5 - \{ [1 - (4 - chlorophenyl) - 1H - pyrazol - 3 - yl< / annotation>< / semantics> <semantics>(methoxyimino)−N,3−dimethylpent−3−enamide(1445331−27−0),<annotation encoding="application / x-tex">(methoxyimino) - N, 3-dimethylpent - 3-enamide (1445331-27-0),< / annotation>< / semantics> <semantics>(2E,3Z)−5−{[1−(2,4−dichlorophenyl)−1H−pyrazol−3−yl]oxy}−2−(2E,3Z)−5−{[1−(2,4−dichlorophenyl)−1H−pyrazol−3−yl]oxy}−2−(2E,3Z)−5−{[1−(2,4−dichlorophenyl)−1H−p<annotation encoding="application / x-tex">(2E, 3Z) - 5 - \{ [1 - (2, 4 - dichlorophenyl) - 1H - pyrazol - 3 - yl] oxy \} - 2 - (2E, 3Z) - 5 - \{ [1 - (2, 4 - dichlorophenyl) - 1H - pyrazol - 3 - yl] oxy \} - 2 - (2E, 3Z) - 5 - \{ [1 - (2, 4 - dichlorophenyl) - 1H - p< / annotation>< / semantics> (methoxyimino) -N, 3-dimethylpent-3-enamide (1445331-54-3), 5- chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl)ethyl]amino}-6- methylpyrimidine <semantics>(1605340−92−8)<annotation encoding="application / x-tex">(1605340-92-8)< / annotation>< / semantics>, N-[1-benzyl-1,3- dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-04- 9), <semantics>N−[(1S)−1−benzyl−1,3−dimethylbutyl]−8−fluoroquinoline−3−<annotation encoding="application / x-tex">N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-< / annotation>< / semantics> carboxamide, N-[1-benzyl-3,3,3-trifluoro-1-methylpropyl]-8- fluoroquinoline-3-carboxamide <semantics>(2132414−00−5)<annotation encoding="application / x-tex">(2132414-00-5)< / annotation>< / semantics>, N-[(1S)-1- benzyl-3,3,3-trifluoro-1-methylpropyl]-8-fluoroquinoline-3- carboxamide <semantics>(2132414−01−6)<annotation encoding="application / x-tex">(2132414-01-6)< / annotation>< / semantics>, N-<semantics>[(1R)−1−benzyl−1,3−<annotation encoding="application / x-tex">[(1R)-1-benzyl-1,3-< / annotation>< / semantics> dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06- 1), <semantics>4,4<annotation encoding="application / x-tex">4,4< / annotation>< / semantics>-dimethyl-2-(<semantics>{4−[5−(trifluoromethyl)−1,2,4<annotation encoding="application / x-tex">\{4-[5-(trifluoromethyl)-1,2,4< / annotation>< / semantics>-oxadiazol- <semantics>3−y1<annotation encoding="application / x-tex">3-y1< / annotation>< / semantics>]phenyl}methyl)isoxazolidin-3-one (2098918-25-1), 5,5- <semantics>dimethyl−2−(4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-}< / annotation>< / semantics> yl]phenyl}methyl) isoxazolidin-3-one (2098918-26-2), N-ethyl- <semantics>2−methyl−N−(4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-}< / annotation>< / semantics> yl]phenyl}methyl)propanamide, <semantics>N1<annotation encoding="application / x-tex">N_{1}< / annotation>< / semantics>2-dimethoxy-<semantics>N2<annotation encoding="application / x-tex">N_{2}< / annotation>< / semantics>-({4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenyl}methyl)propanamide, <semantics>N<annotation encoding="application / x-tex">N< / annotation>< / semantics>-methoxy-<semantics>N<annotation encoding="application / x-tex">N< / annotation>< / semantics>-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)cyclopropanecarboxamide, N-methoxy-N'- <semantics>methyl−N−({4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">methyl-N-(\{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-< / annotation>< / semantics> yl]phenyl}methyl)urea, <semantics>N′<annotation encoding="application / x-tex">N'< / annotation>< / semantics>-ethyl-N-methoxy-N-({4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea, <semantics>N,N′<annotation encoding="application / x-tex">N, N'< / annotation>< / semantics>-dimethoxy-<semantics>N−({4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">N-(\{4-[5-(trifluoromethyl)-1, 2, 4-oxadiazol-3-< / annotation>< / semantics> yl]phenyl}methyl)urea, N-acetyl-2-(ethanesulfonyl)-N-[2- (methoxycarbonyl) -4-(trifluoromethoxy) phenyl]-4- <semantics>(trifluoromethyl)<annotation encoding="application / x-tex">(trifluoromethyl)< / annotation>< / semantics> benzamide <semantics>(2043675−28−9)<annotation encoding="application / x-tex">(2043675-28-9)< / annotation>< / semantics>, <semantics>3−(4−bromo−7−4)<annotation encoding="application / x-tex">3-(4-bromo-7-4)< / annotation>< / semantics> fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2- yl)carbonyl]-L-alaninate, 3-(7-bromoindol-1-yl)butan-2-yl N- [(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate, 3- (7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4- methoxypyridin-2-yl)carbonyl]-L-alaninate, 3-(3,5- dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4- methoxypyridin-2-yl)carbonyl]-L-alaninate, 3-(3,5- dichloropyridin-2-yl) butan-2-yl <semantics>N−{[3−(acetoxymethoxy)−4−<annotation encoding="application / x-tex">N-\{[3-(acetoxymethoxy)-4-< / annotation>< / semantics> methoxypyridin-2-yl]carbonyl}-L-alaninate, (1S)-1-[1- (naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4- methoxypyridin-2-yl)carbonyl]-L-alaninate, (1S)-1-[1- (naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4- methoxypyridin-2-yl)carbonyl]-L-alaninate, (1S)-1-[1- <semantics>(naphthalen−1−yl)<annotation encoding="application / x-tex">(naphthalen-1-yl)< / annotation>< / semantics> cyclopropyl]ethyl N-<semantics>{[3−(acetoxymethoxy)−4−<annotation encoding="application / x-tex">\{[3-(acetoxymethoxy)-4-< / annotation>< / semantics> methoxypyridin-2-yl]carbonyl}-L-alaninate, N-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)cyclopropanecarboxamide, N-allyl-N-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>yl]phenyl}methyl)acetamide, N-allyl-N-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)propanamide, <semantics>N−({4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">N-(\{4-[5-(trifluoromethyl)-< / annotation>< / semantics> 1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide, 3,3,3- trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4- oxadiazol-3-yl]phenyl}methyl)propanamide, 3,3,3-trifluoro-N- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenyl}methyl)propanamide, <semantics>3,3,3<annotation encoding="application / x-tex">3,3,3< / annotation>< / semantics>-trifluoro-N-(<semantics>{2,3<annotation encoding="application / x-tex">\{2,3< / annotation>< / semantics>- difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenyl}methyl)propanamide, <semantics>N−({2,3−difluoro−4−[5−4]}<annotation encoding="application / x-tex">N-(\{2,3-difluoro-4-[5-4]\}< / annotation>< / semantics> (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)butaneamide, <semantics>N<annotation encoding="application / x-tex">N< / annotation>< / semantics>-methoxy-<semantics>N<annotation encoding="application / x-tex">N< / annotation>< / semantics>-methyl-<semantics>N′<annotation encoding="application / x-tex">N'< / annotation>< / semantics>-({4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea, <semantics>N,N−diethyl−N′−({4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">N, N-diethyl-N'-(\{4-[5-(trifluoromethyl)-1, 2, 4-oxadiazol-3-< / annotation>< / semantics> yl]phenyl}methyl)urea, N-methyl-N'-(<semantics>{4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">\{4-[5-(trifluoromethyl)-< / annotation>< / semantics> <semantics>1,2,4<annotation encoding="application / x-tex">1, 2, 4< / annotation>< / semantics>-oxadiazol-<semantics>3<annotation encoding="application / x-tex">3< / annotation>< / semantics>-yl]phenyl}methyl)urea, <semantics>1<annotation encoding="application / x-tex">1< / annotation>< / semantics>-(<semantics>{4<annotation encoding="application / x-tex">\{4< / annotation>< / semantics>-[<semantics>5<annotation encoding="application / x-tex">5< / annotation>< / semantics>- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)pyrrolidin-2-one, 1-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)piperidin-2-one, <semantics>4−({4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">4-(\{4-[5-(trifluoromethyl)-< / annotation>< / semantics> <semantics>1,2,4<annotation encoding="application / x-tex">1, 2, 4< / annotation>< / semantics>-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one, <semantics>2−({4−[5−<annotation encoding="application / x-tex">2-(\{4-[5-< / annotation>< / semantics> (trifluoromethyl) -1, 2, 4-oxadiazol-3- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>yl]phenyl}methyl)isoxazolidin-3-one, 3,3-dimethyl-1-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- yl]phenyl}methyl)piperidin-2-one, <semantics>2−({4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">2-(\{4-[5-(trifluoromethyl)-< / annotation>< / semantics> <semantics>1,2,4<annotation encoding="application / x-tex">1, 2, 4< / annotation>< / semantics>-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one, 1- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>yl]phenyl}methyl)azepan-2-one, 4,4-dimethyl-1-({4-[5- (trifluoromethyl) -1,2,4-oxadiazol-3- yl]phenyl}methyl)pyrrolidin-2-one, 5-methyl-1-({4-[5- (trifluoromethyl) -1, 2, 4-oxadiazol-3- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>yl]phenyl}methyl)pyrrolidin-2-one, ethyl 1-({4-[5- (trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H- pyrazole-4-carboxylate, N-methyl-1-(<semantics>{4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">\{4-[5-(trifluoromethyl)-< / annotation>< / semantics> 1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4- carboxamide, <semantics>N−propyl−1−({4−[5−(trifluoromethyl)−1,2,4−<annotation encoding="application / x-tex">N-propyl-1-(\{4-[5-(trifluoromethyl)-1,2,4-< / annotation>< / semantics> oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide, N- <semantics>methoxy−1−({4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−<annotation encoding="application / x-tex">methoxy-1-(\{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-< / annotation>< / semantics> yl]phenyl}methyl)-1H-pyrazole-4-carboxamide, N-methoxy-N- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3- yl]phenyl}methyl)-1H-pyrazole-4-carboxamide, N,N-dimethyl-1- <semantics>({4−[5−(trifluoromethyl)−1,2,4−oxadiazol−3−yl]phenyl}methyl)−<annotation encoding="application / x-tex">(\{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl\}methyl)-< / annotation>< / semantics> <semantics>1H−1,2,4−triazole−3−amine,N−methyl−4−[5−(trifluoromethyl)−<annotation encoding="application / x-tex">1H-1,2,4-triazole-3-amine, N-methyl-4-[5-(trifluoromethyl)-< / annotation>< / semantics> 1,2,4-oxadiazol-3-yl]benzamide, methyl 2-[2-chloro-4-(4- chlorophenoxy) phenyl] -2-hydroxy-3-(1H-1,2,4-triazol-1- yl)propanoate, ethyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]- <semantics>2−hydroxy−3−(1H−1,2,4−triazol−1−yl)<annotation encoding="application / x-tex">2-hydroxy-3-(1H-1,2,4-triazol-1-yl)< / annotation>< / semantics> propanoate, methyl <semantics>2−[2−1]<annotation encoding="application / x-tex">2-[2-1]< / annotation>< / semantics> (trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H- <semantics>1,2,4<annotation encoding="application / x-tex">1, 2, 4< / annotation>< / semantics>-triazol-<semantics>1<annotation encoding="application / x-tex">1< / annotation>< / semantics>-yl) propanoate, <semantics>1<annotation encoding="application / x-tex">1< / annotation>< / semantics>-<semantics>(2,3<annotation encoding="application / x-tex">(2, 3< / annotation>< / semantics>-dimethylpyridin-<semantics>5<annotation encoding="application / x-tex">5< / annotation>< / semantics>-yl) - 4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, 1-[2- (difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3- dimethyl-3,4-dihydroisoquinoline, <semantics>2,2<annotation encoding="application / x-tex">2,2< / annotation>< / semantics>-difluoro-N-<semantics>[6−({[1−(1−(1−(1−(1−(1−(1−(1−(1−(1−(1−(1−(1−(1<annotation encoding="application / x-tex">[6-(\{[1-(1-(1-(1-(1-(1-(1-(1-(1-(1-(1-(1-(1-(1< / annotation>< / semantics> methyl-1H-tetrazol-5-yl)benzoimidazol-2- <semantics>yl]oxy}methyl)pyridin−2−yl]−2−phenoxyacetamide,1−[2−(1−<annotation encoding="application / x-tex">yl]oxy\}methyl)pyridin-2-yl]-2-phenoxyacetamide, 1-[2-(1-< / annotation>< / semantics> chlorocyclopropyl) -3-(3-chloro-2-fluorophenyl) -2- hydroxypropyl]-1H-imidazole-5-carbonitrile, ethyl 1-[(4-{[2- (trifluoromethyl)-1,3-dioxoran-2-yl]methoxy}phenyl)methyl]- <semantics>1H<annotation encoding="application / x-tex">1H< / annotation>< / semantics>-pyrazole-4-carboxylate, ethyl <semantics>1−[(4−{[(1Z)−2−ethoxy−3,3,3−ethy]})]<annotation encoding="application / x-tex">1-[(4-\{[(1Z)-2-\text{ethoxy}-3,3,3-\text{ethy}]\})]< / annotation>< / semantics> trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4- carboxylate, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2- (2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4- carboxamide, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2- (3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4- carboxamide, <semantics>6<annotation encoding="application / x-tex">6< / annotation>< / semantics>-chloro-N-[2-(2-chloro-methylphenyl)-2,2- difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5- methylpyridazine-4-carboxamide, 2-[cyano(2,6-difluoropyridin- 4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methyl-4- carboxamide, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N- <semantics>(spiro[3.4] octan−1−yl)−5−methyl−4−carboxamide,2−[cyano(2,6−<annotation encoding="application / x-tex">(\text{spiro}[3.4]\text{ octan}-1-\text{yl})-5-\text{methyl}-4-\text{carboxamide}, 2-[\text{cyano}(2,6-< / annotation>< / semantics> <semantics>difluoropyridin−4−yl)<annotation encoding="application / x-tex">difluoropyridin-4-yl)< / annotation>< / semantics> amino]-N-hexyl-5-methyl-4-carboxamide, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2- dimethylcyclobutyl)-5-methyl-4-carboxamide, 2-[(2- methoxyacetyl) (2,6-difluoropyridin-4-yl)amino]-N-(2,2- dimethylcyclobutyl)-5-methyl-4-carboxamide, 2-[(2- methylpropanoyl) (2,6-difluoropyridin-4-yl)amino]-N-(2,2- dimethylcyclobutyl)-5-methyl-4-carboxamide, 2-[(2,6- difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5- methyl-4-carboxamide, <semantics>2−{[(oxetan−3−yl)carbonyl](2,6−<annotation encoding="application / x-tex">2-\{[(oxetan-3-yl)carbonyl](2,6-< / annotation>< / semantics> <semantics>difluoropyridin−4−yl)<annotation encoding="application / x-tex">difluoropyridin-4-yl)< / annotation>< / semantics> amino}-N-(2,2-dimethylcyclobutyl)-5- methyl-4-carboxamide, <semantics>2−{[(oxolan−3−yl)carbonyl](2,6−<annotation encoding="application / x-tex">2-\{[(oxolan-3-yl)carbonyl](2,6-< / annotation>< / semantics> difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5- methyl-4-carboxamide, <semantics>2−{[(oxan−4−yl)carbonyl](2,6−<annotation encoding="application / x-tex">2-\{[(oxan-4-yl)carbonyl](2,6-< / annotation>< / semantics> <semantics>difluoropyridin−4−yl)<annotation encoding="application / x-tex">difluoropyridin-4-yl)< / annotation>< / semantics> amino<semantics>}−N−(2,2−dimethylcyclobutyl)−5−<annotation encoding="application / x-tex">\}-N-(2,2-dimethylcyclobutyl)-5-< / annotation>< / semantics> methyl-4-carboxamide, 5-[5-(difluoromethyl)-1,3,4-oxadiazol- <semantics>2−y1]−N−[1−(2−fluorophenyl)ethyl]pyrimidine−2−amine,5−[5−<annotation encoding="application / x-tex">2-y1]-N-[1-(2-fluorophenyl)ethyl]pyrimidine-2-amine, 5-[5-< / annotation>< / semantics> <semantics>(difluoromethyl)−1,3,4−oxadiazol−2−yl]−N−[1−(2,6−<annotation encoding="application / x-tex">(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-< / annotation>< / semantics> difluorophenyl)ethyl]pyrimidine-2-amine, 5-[5- <semantics>(difluoromethyl)−1,3,4−oxadiazol−2−yl]−N−[1−(3,5−<annotation encoding="application / x-tex">(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-< / annotation>< / semantics> difluorophenyl)ethyl]pyrimidine-2-amine, 5-[5- (difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin- <semantics>3−y1<annotation encoding="application / x-tex">3-y1< / annotation>< / semantics>) ethyl]pyrimidine-2-amine, <semantics>5−[5−(difluoromethyl)−1,3,4−<annotation encoding="application / x-tex">5-[5-(difluoromethyl)-1,3,4-< / annotation>< / semantics> oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidine- 2-amine, <semantics>5−[5−(difluoromethyl)−1,3,4−oxadiazol−2−yl]−N−[1−<annotation encoding="application / x-tex">5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-< / annotation>< / semantics> (2,6-difluorophenyl)cyclopropyl]pyrimidine-2-amine, 5-[5- <semantics>(difluoromethyl)−1,3,4−oxadiazol−2−yl]−N−[1−(2−fluoro−3−<annotation encoding="application / x-tex">(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-< / annotation>< / semantics> methoxyphenyl)cyclopropyl]pyrimidine-2-amine, 5-[5- <Formule mathématique disponible dans le document PDF, Math available in the PDF document>(difluoromethyl) -1, 3, 4-oxadiazol-2-yl] -2-{[1-(2,6- difluorophenyl)cyclopropyl]oxy}pyrimidine, 3-[3-(3- cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4- dimethylphenyl) methyl] <semantics>−5<annotation encoding="application / x-tex">-5< / annotation>< / semantics>, <semantics>6<annotation encoding="application / x-tex">6< / annotation>< / semantics>-dihydro<semantics>−4<annotation encoding="application / x-tex">-4< / annotation>< / semantics>H-1, <semantics>2<annotation encoding="application / x-tex">2< / annotation>< / semantics>, <semantics>4<annotation encoding="application / x-tex">4< / annotation>< / semantics>-oxadiazine, <semantics>(5S)<annotation encoding="application / x-tex">(5S)< / annotation>< / semantics>- 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]- <semantics>5−[(2,4−dimethylphenyl)methyl]−5,6−dihydro−4H−1,2,4−<annotation encoding="application / x-tex">5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-< / annotation>< / semantics> oxadiazine, <semantics>3−[3−(3−chloro−2−fluorophenoxy)−6−<annotation encoding="application / x-tex">3-[3-(3-chloro-2-fluorophenoxy)-6-< / annotation>< / semantics> methylpyridazin-<semantics>4−y1<annotation encoding="application / x-tex">4-y1< / annotation>< / semantics>]-5-[(<semantics>4−bromo−2−methylphenyl<annotation encoding="application / x-tex">4-bromo-2-methylphenyl< / annotation>< / semantics>)methyl]-5,6- <semantics>dihydro−4H−1,2,4−oxadiazine,3−[3−(3−chloro−2−fluorophenoxy)−<annotation encoding="application / x-tex">dihydro-4H-1,2,4-oxadiazine,3-[3-(3-chloro-2-fluorophenoxy)-< / annotation>< / semantics> 6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]- 5,6-dihydro-4H-1,2,4-oxadiazine, (5S)-3-[3-(3-chloro-2- fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4- methylphenyl) methyl] <semantics>−5<annotation encoding="application / x-tex">-5< / annotation>< / semantics>, <semantics>6<annotation encoding="application / x-tex">6< / annotation>< / semantics>-dihydro<semantics>−4<annotation encoding="application / x-tex">-4< / annotation>< / semantics>H-1, <semantics>2<annotation encoding="application / x-tex">2< / annotation>< / semantics>, <semantics>4<annotation encoding="application / x-tex">4< / annotation>< / semantics>-oxadiazine, <semantics>(5R)<annotation encoding="application / x-tex">(5R)< / annotation>< / semantics> <semantics>−3<annotation encoding="application / x-tex">-3< / annotation>< / semantics>- <semantics>[3−(3−chloro−2−fluorophenoxy)−6−methylpyridazin−4−yl]−5−[(2−in−4−yl)]<annotation encoding="application / x-tex">[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-in-4-yl)]< / annotation>< / semantics> chloro-4-methylphenyl) methyl]-5,6-dihydro-4H-1,2,4- oxadiazine, <semantics>N−((2S)−1−{3−[2−(5−fluoro−2−methoxyphenyl)−2−<annotation encoding="application / x-tex">N-((2S)-1-\{3-[2-(5-fluoro-2-methoxyphenyl)-2-< / annotation>< / semantics> hydroxyethyl] <semantics>−5−[(E)−1−(isopropoxyimino)ethyl]−2,6−dioxo−3,6−<annotation encoding="application / x-tex">-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-< / annotation>< / semantics> dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2- methylpropanamide, <semantics>N−((2S)−1−{3−[2−(5−fluoro−2−1)]}<annotation encoding="application / x-tex">N-((2S)-1-\{3-[2-(5-fluoro-2-1)]\}< / annotation>< / semantics> methoxyphenyl) <semantics>−2<annotation encoding="application / x-tex">-2< / annotation>< / semantics>-hydroxyethyl] <semantics>−5<annotation encoding="application / x-tex">-5< / annotation>< / semantics>-[(E) <semantics>−1<annotation encoding="application / x-tex">-1< / annotation>< / semantics>- (isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)- <semantics>y1<annotation encoding="application / x-tex">y1< / annotation>< / semantics>}-3-methylbutan-2-<semantics>y1<annotation encoding="application / x-tex">y1< / annotation>< / semantics>)-2,2-dimethylpropanamide, N-((2S)-1- <semantics>{3−[2−(5−fluoro−2−methoxyphenyl)−2−hydroxyethyl]−5−[(E)−1−<annotation encoding="application / x-tex">\{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-< / annotation>< / semantics> (isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)- <semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>}propan-2-<semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>)-2-methylpropanamide, N-((2S)-1-{3-[2-(2- methoxyphenyl) <semantics>−2<annotation encoding="application / x-tex">-2< / annotation>< / semantics>-hydroxyethyl] <semantics>−5<annotation encoding="application / x-tex">-5< / annotation>< / semantics>-[(E) <semantics>−1<annotation encoding="application / x-tex">-1< / annotation>< / semantics>- (isopropoxyimino) ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)- <semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>}propan-2-<semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>)-2-methylpropanamide, N-((2S)-1-{3-[2-(5- fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1- (isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)- <semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>}propan-2-<semantics>yl<annotation encoding="application / x-tex">yl< / annotation>< / semantics>)-2-methylpropanamide, methyl ({5-[1-(2,6- difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2- methylphenyl}methyl)carbamate, methyl ({5-[1-(2,6-difluoro-4- cyclopropylphenyl)-1H-pyrazol-3-yl]-2- methylphenyl<semantics>}<annotation encoding="application / x-tex">\}< / annotation>< / semantics>methyl)carbamate, methyl (<semantics>{5−[1−(2,6−difluoro−4−<annotation encoding="application / x-tex">\{5-[1-(2,6-difluoro-4-< / annotation>< / semantics> methoxyphenyl)-1H-pyrazol-3-yll-2- methylphenyl<semantics>}<annotation encoding="application / x-tex">\}< / annotation>< / semantics>methyl)carbamate, methyl (Z)-2-(5-cyclopentyl-2- methylphenoxy) <semantics>−3<annotation encoding="application / x-tex">-3< / annotation>< / semantics>-methoxyprop-2-enoate, methyl (Z) <semantics>−2<annotation encoding="application / x-tex">-2< / annotation>< / semantics>-(5- cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate, methyl <semantics>(Z)−2−[(3−isopropyl−1H−pyrazol−1−yl)−2−methylphenoxy)−3−<annotation encoding="application / x-tex">(Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy)-3-< / annotation>< / semantics> methoxyprop-2-enoate, <semantics>1−(4,5−dimethyl−1H−benzoimidazol−1−yl)−<annotation encoding="application / x-tex">1-(4,5-dimethyl-1H-benzoimidazol-1-yl)-< / annotation>< / semantics> 4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, 1-(4,5- dimethyl-1H-benzoimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl- 3,4-dihydroisoquinoline, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4- difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, 1-(6,7- dimethylpyrazolo[1,5-a]pyridin-3-yl)-fluoro-3,3- dimethylisoquinolin-<semantics>4(3H)<annotation encoding="application / x-tex">4(3H)< / annotation>< / semantics>-one, and methyl <semantics>(2Z)<annotation encoding="application / x-tex">(2Z)< / annotation>< / semantics>-3-methoxy-2- <semantics>[(4−methyl[1,1′−biphenyl]−3−yl)oxy]prop−2−enoate.<annotation encoding="application / x-tex">[(4-methyl[1,1'-biphenyl]-3-yl)oxy]prop-2-enoate.< / annotation>< / semantics>

[0026] Examples of the active ingredient that may remain in the article and are effectively cleaned by the present method include epiriphenal and butafenacil. When the article is a pesticide spraying machine, examples of the active ingredient that is sprayed by the pesticide spraying machine after cleaning by the present method include glyphosate-potassium, dicamba-diglycolamine, 2,4-D-triethanolamine and clethodim.

[0027] The pesticide to be sprayed by the pesticide spraying machine before or after cleaning by the present method is usually a pesticide formulation that is mixed with water to prepare a spray liquid. The formulation type of such formulation is preferably a suspension concentrate, an oil dispersion, a wettable powder, a water dispersible granule, a granule, an oil-in-water emulsion, a water-in-oil emulsion, a soluble liquid and an emulsifiable concentrate. The formulation type of epyrifenacil, butafenacil and clethodim is preferably an emulsifiable concentrate, and the formulation type of glyphosate-potassium, dicamba- diglycolamine and 2,4-D triethanolamine is preferably a soluble liquid.

[0028] In the present method, the present composition may be used in combination with an existing cleaning agent. Examples of the cleaning agent that can be used in combination include surfactants, hydrogen peroxide, sodium chlorate and the like. Examples of surfactants include carboxylic acids: fatty acid salts (octanoate, decanoate, laurate, myristate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylates (laureth-3- carboxylate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-(carboxymethyl)-<semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>- (dodecyloxy)poly(oxyethylene) salt, etc.), N-acylsarcosine salts (N-lauroylsarcosine salt, etc.), N-acylglutamates (N- lauroylglutamate, etc.), and polycarboxylates (polyacrylate, polyvinyl acetate, comb polymer of polyacid salt, and derivatives thereof), sulfonates: alkylsulfonic acids and salts thereof (dodecyl sulfonate, etc.), alpha-olein sulfonates (alkene (C14-18) hydroxysulfonate, alkapolyene (C12- 20) hydroxysulfonate, alkene (C14-18) hydroxysulfonate, alkene (C12-20) hydroxysulfonate, tetradecene-1-sulfonate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>- olefin (C14-16) sulfonate, etc.), alkylbenzene sulfonates (decylbenzene sulfonate, dodecylbenzene sulfonate, tridecylbenzene sulfonate, diphenyl sulfonate, etc.), alkyl naphthalene sulfonates (naphthalene sulfonate, 6-methyl-2- naphthalene sulfonate, dibutyl naphthalene sulfonate, 2,2'- dinaphthylmethane-6,6'-disulfonate, diisopropyl naphthalene sulfonate, triisopropyl naphthalene sulfonate, 1-isopropyl-2- naphthalene sulfonate, etc.), sulfosuccinic acids, monoalkyl sulfosuccinates, dialkyl sulfosuccinates (di(2-ethylhexyl) sulfosuccinate, etc.), N-methyl-N-acyltaurin salts (methyl oleoyl taurate, etc.), lignin sulfonates, alkylphenol sulfonates, naphthalenesulfonate-formaldehyde condensates, benzimidazolesulfonates and derivatives thereof; sulfuric acid esters: alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, diethanol lauryl sulfate, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfuric acid and salts thereof (laureth-3 sulfate, polyoxyethylene monotridecyl ether sulfuric acid, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>- sulfo-<semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>-hydroxyalkyl (C6-10) ether poly(oxyethylene) salt, etc.), polyoxyethylene alkyl phenyl ether sulfates (poly(oxyethylene)2-decylphenyl ether sulfosuccinate, poly(oxyethylene)3-decylphenyl ether sulfosuccinate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-sulfo- <semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salt, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite waste liquor, and derivatives thereof; phosphoric acid esters: alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-phosphono-<semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>- butoxypoly(oxyethylene), etc.), polyoxyethylene alkyl phenyl ether phosphates <semantics>(α−(dinonylphenyl)−ω−<annotation encoding="application / x-tex">(\alpha-(dinonylphenyl)-\omega-< / annotation>< / semantics> hydroxypoly(oxyethylene)phosphate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-(dodecylphenyl)-<semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>- hydroxypoly (oxyethylene) phosphate, <semantics>α<annotation encoding="application / x-tex">\alpha< / annotation>< / semantics>-(nonylphenyl) -<semantics>ω<annotation encoding="application / x-tex">\omega< / annotation>< / semantics>- hydroxypoly(oxyethylene)phosphate, etc.), polyoxypropylenealkyl ether phosphates, and derivatives thereof; alcohols: aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octylcresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharide, starch, starch derivative, sucrose, alkylpolyglucoside, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), and synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); amides: alkanolamides (fatty acid alkanolamides (lauric acid diethanolamide, etc.), fatty acid glucamides (alkoxylated propylene oxide fatty acid glucamide, etc.), alkoxylated amides (polyoxyethyleneoleic acid amide, polyoxyethylenesteric acid amide, etc.), and synthetic polymers (polyvinylpyrrolidone, etc.), amines: alkoxylated amines (polyoxyethylene oleyl amine, <semantics>α,α′−[(9−octadecenylimino)di−2,1−ethanediyl]bis(ω−<annotation encoding="application / x-tex">\alpha, \alpha' - [(9-\text{octadecenylimino}) \text{di} - 2, 1-\text{ethanediyl}] \text{bis} (\omega -< / annotation>< / semantics> hydroxy) polyoxyethylene, etc.); esters: fatty acid esters (fatty acid ester of polyol, monoglyceride, phospholipid, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearic acid diester, etc.), sorbitan fatty acid esters (sorbitan oleic acid monoester, etc.), glucose esters, cellulose esters, etc.), and synthetic polymers (vinyl acetate copolymer, polymethacrylic acid, copolymer of methacrylic acid and methacrylic acid ester, etc.); ethers: alcohol ethoxylates (aliphatic alcohol ethoxylate (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate), etc.), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyryl phenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzyl biphenol alcohol ethoxylate, etc.), alcohol propoxylates (aliphatic alcohol propoxylate, alkylphenol propoxylate, arylalkylphenol propoxylate, etc.), and block polymers (block copolymer of polyethylene oxide and polypropylene oxide, polyethylene oxide block polymer, polypropylene oxide block polymer, block polymer of alkanol, polyethylene oxide and polypropylene oxide, etc.); ether esters: polyoxyethylene fatty acid esters (polyoxyethylene castor oil ester, polyoxyethylenestearic acid ester, polyoxyethylene beef tallow fatty acid ester, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleic acid ester, polyoxyethylene sorbitan trioleic acid ester, polyoxyethylene sorbitan monolauric acid ester, polyoxyethylene sorbitan stearic acid ester, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil ester, etc.), and polyoxypropylene fatty acid amine esters; carboxylic acids: undecafluorohexanoic acids; and the like. [Examples] Hereinafter, the present invention will be described by way of Examples, but the present invention is not limited to these Examples. "%" and "parts" mentioned below mean weight % and weight part, respectively unless otherwise specified. The methods for preparing cleaning liquid compositions used in Test Examples are shown below. Cleaning Liquid Composition 1 for Comparison Valent Tank Cleaner (aqueous solution of 15-30% sodium hydroxide and 1-5% Surfactant Blend, manufactured by Valent U.S.A. Corp.) was diluted 100 times with water to obtain a comparative cleaning liquid composition 1 (hereinafter referred to as comparative cleaning liquid composition 1). The pH of the comparative cleaning liquid composition 1 was 12.7. Liquid Composition 2 for Comparison A mixture (hereinafter referred to as mixture X) of 7.9 parts of Phenylsulfonat CAL (70% n-C12 alkylbenzene sulfonate calcium salt (in isobutanol), manufactured by Clariant), 7.9 parts of Emulsogen TS 290 (2,4,6-tri-(1-phenylethyl)-phenol polyglycol ether comprising 29 mol of ethylene oxide, manufactured by Clariant) and 84.2 parts of Aromatic 200 ND Fluid (also known as Solvesso 200 ND, Solvent Naphtha (Petroleum), Heavy Aromatic, manufactured by ExxonMobil Corporation) was obtained. The mixture X was mixed with water to obtain a cleaning liquid composition 2 for comparison (hereinafter referred to as comparative cleaning liquid composition 2). The concentration of the mixture X in the comparative cleaning liquid composition 2 was <semantics>5%(v / v)<annotation encoding="application / x-tex">5\%(v / v)< / annotation>< / semantics>. The pH of the comparative cleaning liquid composition 2 was 8.1. Liquid Composition 3 for Comparison Cyclohexanone was mixed with water to obtain a cleaning liquid composition 3 for comparison (hereinafter referred to as comparative cleaning liquid composition 3). The concentration of cyclohexanone in the comparative cleaning liquid composition 3 was <semantics>5%(v / v)<annotation encoding="application / x-tex">5\%(v / v)< / annotation>< / semantics>. The pH of the comparative cleaning liquid composition 3 was 8.0. Liquid Composition 4 for Comparison An aqueous solution of 150 mM tetrabutylammonium hydroxide was prepared as a cleaning liquid composition 4 for comparison (hereinafter referred to as comparative cleaning liquid composition 4). The pH of the comparative cleaning liquid composition 4 was 13.3. Cleaning Liquid Composition 1 of the Present Invention Valent Tank Cleaner, a mixture X, and water were mixed in a volume ratio of 1:5:94 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 1). The pH of the present cleaning liquid composition 1 was 12.7. Cleaning Liquid Composition 2 of the Present Invention An aqueous solution of 157.9 mM tetrabutylammonium hydroxide was mixed with cyclohexanone in a volume ratio of 95:5 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 2). The concentration of tetrabutylammonium hydroxide in the present cleaning liquid composition 2 was 150 mM, and the pH of the present cleaning liquid composition 2 was 13.3. Cleaning Liquid Composition 3 of the Present Invention Valent Tank Cleaner, cyclohexanone, and water were mixed in a volume ratio of 1:5:94 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 3). The pH of the present cleaning liquid composition 3 is shown in Table 4. Cleaning Liquid Composition 4 of the Present Invention An aqueous solution of 157.9 mM tetrabutylammonium hydroxide and a mixture X were mixed in a volume ratio of 95:5 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 4). The pH of the present cleaning liquid composition 4 is shown in Table 8. Cleaning Liquid Composition 5 of the Present Invention Valent Tank Cleaner, tetrahydrofuran, and water were mixed in a volume ratio of 1:5:94 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 5). The pH of the present cleaning liquid composition 5 is shown in Table 8. Cleaning Liquid Composition 6 of the Present Invention An aqueous solution of 157.9 mM tetrabutylammonium hydroxide, tetrahydrofuran, and water were mixed in a volume ratio of 95:5 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 6). The pH of the present cleaning liquid composition 6 is shown in Table 8. Cleaning Liquid Composition 7 to 9 of the Present Invention An aqueous solution of sodium hydroxide (50, 100, or 200 mM) and a mixture X were mixed in a volume ratio of 95:5 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 7 to 9, respectively). The pH of the present cleaning liquid composition 7 to 9 are shown in Table 9. Cleaning Liquid Composition 10 of the Present Invention An aqueous solution of 50 mM tetrabutylammonium hydroxide and cyclohexanone were mixed in a volume ratio of 95:5 to obtain a cleaning liquid composition of the present invention (hereinafter referred to as present cleaning liquid composition 10). The pH of the present cleaning liquid composition 10 is shown in Table 9.

[0031] The method for preparing an epirifenacil 55 g / L emulsifiable concentrate used in Test Example is shown below. 5.39 Parts of epirifenacil, 7.5 parts of Phenylsulfonat CAL (70% n-C12 alkylbenzene sulfonate calcium salt (in isobutanol), manufactured by Clariant), 7.5 parts of Emulsogen TS 290 <semantics>(2,4,6−tri−(1−phenylethyl)−phenolpolyglycol<annotation encoding="application / x-tex">(2,4,6-tri-(1-phenylethyl)-phenol polyglycol< / annotation>< / semantics> ether comprising 29 mol of ethylene oxide, manufactured by Clariant) and 79.61 parts of Aromatic 200 ND Fluid (Solvent Naphtha (Petroleum), Heavy Aromatic, manufactured by ExxonMobil Corporation) were thoroughly mixed to obtain an epirifenacil 55 g / L emulsifiable concentrate.

[0032] The method for preparing a butafenacil 50 g / L emulsifiable concentrate used in Test Example is shown below. 4.9 Parts of butafenacil, 7.5 parts of Phenylsulfonat CAL (70% n-C12 alkylbenzene sulfonate calcium salt (in isobutanol), manufactured by Clariant), 7.5 parts of Emulsogen TS 290 (2,4,6-tri-(1-phenylethyl)-phenol polyglycol ether comprising 29 mol of ethylene oxide, manufactured by Clariant) and 80.1 parts of Aromatic 200 ND Fluid (Solvent Naphtha (Petroleum), Heavy Aromatic, manufactured by ExxonMobil Corporation) were thoroughly mixed to obtain a butafenacil 50 g / L emulsifiable concentrate. Test Example 1 An EPDM hose having an inner diameter of 3 / 4 inches (HORIZON 200PSI W.P. Lot. 10.20.50B, manufactured by Good Year) cut into a length of 15 cm was filled with a liquid (epirifenacil concentration: 143 ppm, 20 g / ha, concentration assumed to be about 140 L / ha of spray volume) prepared by mixing an epirifenacil 55 g / L emulsifiable concentrate with a water dilution of 1% Agri-Dex (paraffin-based petroleum + polyol fatty acid ester + polyethoxylated polyol fatty acid ester emulsifier, Helena Agri-Enterprises, manufactured by LLC), followed by being left to stand at 30°C for 24 hours to obtain a plurality of contaminated hoses. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 24 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.25% volume of Induce (alkyl aryl polyoxyalkane ether + alkanolamide + dimethylsiloxane + fatty acid, Helena Agri-Enterprises, manufactured by LLC) assumed to be the spray liquid for the subsequent process was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 1. The cleaning effect is expressed by low phytotoxicity in Table 1. By cleaning with the cleaning liquid composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0034] [Table 1] [Image disponible dans le document PDF, Image available in the PDF document]

[0035] Test Example 2 A plurality of contaminated hoses were obtained in the same manner as in Test Example 1. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 48 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax (clethodim of 116 g / L, manufactured by Valent) and 1% volume of Agri-Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 2. The cleaning effect is expressed by low phytotoxicity in Table 2. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0036] [Table 2] [Image disponible dans le document PDF, Image available in the PDF document]

[0037] Test Example 3 A plurality of contaminated hoses were obtained in the same manner as in Test Examples 1 and 2. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 24 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri- Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 3. The cleaning effect is expressed by low phytotoxicity in Table 3. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0038] [Table 3] [Image disponible dans le document PDF, Image available in the PDF document]

[0039] Test Example 4 An EPDM hose having an inner diameter of 3 / 4 inches (HORIZON 200PSI W.P. Lot. 10.20.50B, manufactured by Good Year) cut into a length of 15 cm was filled with a liquid (butafenacil concentration: 143 ppm, 20 g / ha, concentration assumed to be about 140 L / ha of spray volume) prepared by mixing an butafenacil 50 g / L emulsifiable concentrate with a water dilution of 1% Agri-Dex (paraffin-based petroleum + polyol fatty acid ester + polyethoxylated polyol fatty acid ester emulsifier, manufactured by Helena Agri-Enterprises, LLC), followed by being left to stand at 30°C for 24 hours to obtain a plurality of contaminated hoses. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 14 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri- Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 4. The cleaning effect is expressed by low phytotoxicity in Table 4. By cleaning with the cleaning liquid composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0040] [Table 4] [Image disponible dans le document PDF, Image available in the PDF document] [Image disponible dans le document PDF, Image available in the PDF document]

[0041] Test Example 5 A plurality of contaminated hoses were obtained in the same manner as in Test Example 4. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 14 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri-Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of soybean in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 5. The cleaning effect is expressed by low phytotoxicity in Table 5. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0042] [Table 5] [Image disponible dans le document PDF, Image available in the PDF document] [Image disponible dans le document PDF, Image available in the PDF document]

[0043] Test Example 6 An EPDM hose having an inner diameter of 3 / 4 inches (HORIZON 200PSI W.P. Lot. 10.20.50B, manufactured by Good Year) cut into a length of 15 cm was filled with a liquid (dicamba acid concentration: 4000 ppm, 560 g / ha, concentration assumed to be about 140 L / ha of spray volume) prepared by mixing a XtendiMax (350 g / L of Dicamba, present as diglycolamine salt, manufactured by Monsanto Corp.) with a water dilution of 0.5% volume Intact (includes polyethylene glycol, choline chloride, guar gum and surfactant, manufactured by Precision Laboratories Corp.) and a water dilution of 0.25% volume of Induce (alkyl aryl polyoxyalkane ether + alkanolamide + dimethylsiloxane + fatty acid, Helena Agri-Enterprises, manufactured by LLC), followed by being left to stand at 30°C for 24 hours to obtain a plurality of contaminated hoses. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 14 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri-Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 4. The cleaning effect is expressed by low phytotoxicity in Table 6. By cleaning with the cleaning liquid composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0044] [Table 6] [Image disponible dans le document PDF, Image available in the PDF document] Test Example 7 A plurality of contaminated hoses were obtained in the same manner as in Test Example 6. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 14 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri-Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 7. The cleaning effect is expressed by low phytotoxicity in Table 7. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0046] [Table 7] [Image disponible dans le document PDF, Image available in the PDF document]

[0047] Test Example 8 A plurality of contaminated hoses were obtained in the same manner as in Test Examples 1 to 3. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 24 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri- Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 8. The cleaning effect is expressed by low phytotoxicity in Table 8. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced.

[0048] [Table 8] [Image disponible dans le document PDF, Image available in the PDF document]

[0049] Test Example 9 A plurality of contaminated hoses were obtained in the same manner as in Test Examples 1 to 3. After rinsing the inside of the hoses with tap water for 20 seconds, a prescribed cleaning liquid composition was filled into the hoses as a cleaning process, followed by being left to stand at 30°C for 24 hours. The cleaning liquid composition was removed from the hoses, and the inside of the hoses was rinsed again with tap water for 20 seconds. Then, a water dilution of 0.83% volume of SelectMax and 1% volume of Agri- Dex assumed to be sprayed in the subsequent step was filled into the hoses, followed by being left to stand at 30°C for 1 hour. The contents were sprayed over the foliage of American cotton plants in the cotyledon stage grown in pots at a spray volume of 15 gallons / acre (about 140 L / ha). The herbicidal effect 7 days after spraying was visually evaluated [0 (no effect) - 100 (completely withered)]. The results are shown in Table 9. The cleaning effect is expressed by low phytotoxicity in Table 9. By washing with the liquid washing composition of the present invention, the phytotoxicity on cotton plants was significantly reduced. [Table 9] [Image disponible dans le document PDF, Image available in the PDF document] [Image disponible dans le document PDF, Image available in the PDF document] [Industrial Applicability]

[0051] According to the present invention, it is possible to 5 effectively clean an article in which a pesticide remains.

Claims

1. A method for cleaning an article in which an active ingredient of a pesticide remains, comprising bringing a cleaning liquid composition with a pH of 10 or higher comprising an organic solvent in contact with the article.

2. The method according to claim 1, wherein the article is a pesticide spraying machine.

3. The method according to claim 1, wherein the organic solvent is solvent naphtha.

4. The method according to claim 1, wherein the organic solvent is cyclohexanone.

5. The method according to claim 1, wherein the organic solvent is tetrahydrofuran.

6. The method according to claim 1, wherein the cleaning liquid composition comprises an inorganic alkali.

7. The method according to claim 1, wherein the cleaning liquid composition comprises an alkali metal hydroxide.

8. The method according to claim 1, wherein the cleaning liquid composition comprises an organic alkali.

9. The method according to claim 1, wherein the cleaning liquid composition comprises tetrabutylammonium hydroxide.

10. A cleaning liquid composition comprising an organic solvent and tetrabutylammonium hydroxide.

11. Use of the cleaning liquid composition with a pH of 10 or higher comprising an organic solvent for cleaning an article in which an active ingredient of a pesticide remains.