一种基于绿色回收锡泥制备高性能H2S气体传感器的方法

By preparing Ni/S-SnO2 sensitive materials through acid washing and solvothermal activation of tin sludge, the problems of tin oxide recovery and H2S sensing material application were solved, realizing efficient and low-cost utilization of tin resources and improvement of gas sensor performance.

CN115728359BActive Publication Date: 2026-07-17SHENZHEN AIDUOKE SENSOR TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN AIDUOKE SENSOR TECH CO LTD
Filing Date
2022-11-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to efficiently recover tin oxides from tin sludge and apply them to H2S sensing materials. Furthermore, the preparation process is complex and costly, which is not conducive to industrial production, and the tin resource shortage problem is serious.

Method used

Sulfur-containing SnO2 materials were prepared by activating tin mud through acid washing combined with solvothermal method, and Ni/S-SnO2 sensitive materials were prepared by surface modification of metallic Ni for use in low-concentration H2S gas sensors.

Benefits of technology

This technology enables the green recycling of tin oxides, reduces enterprise costs, improves the sensitivity of H2S gas sensors, aligns with the concept of green development, and enhances the porosity and surface area of ​​the material.

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Abstract

本发明涉及一种基于绿色回收锡泥制备高性能H2S气体传感器的方法,属于气体传感器与环境保护技术领域。本发明所述方法首先将锡泥置于盐酸溶液中反应得S‑SnO2;将S‑SnO2均匀分散在十二烷基苯磺酸钠溶液中后进行溶剂热反应,将干燥后的沉淀物保温得到活化后的S‑SnO2;通过自组装方法在活化后的S‑SnO2表面上沉积掺杂镍纳米颗粒;将所得表面沉积有Ni纳米颗粒的S‑SnO2材料涂在叉指电极上组成H2S气体传感器。本发明通过溶剂热法对得到的锡氧化物进行了活化处理,得到的敏感材料具有多孔、表面积大的特点。过渡金属表面修饰有利于增加SnO2的表面氧空位浓度。而表面氧空位作为气敏材料与吸附氧以及目标气体反应的主要活性位点,其浓度的提高能够显著增强SnO2基气敏材料的敏感性能。
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