一种基于萘甲胺的准二维钙钛矿光电探测器及其制备方法

By adding MACl to the precursor solution and using antisolvent regulation, a highly crystalline quasi-two-dimensional perovskite photodetector was prepared, which solved the problems of uneven crystallinity and phase distribution in polycrystalline thin films and improved the performance of the photodetector.

CN115915872BActive Publication Date: 2026-07-17JILIN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2022-11-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The difficulty in preparing high-quality quasi-two-dimensional perovskite polycrystalline thin films leads to less than ideal performance of perovskite photodetectors, especially when the crystallization is poor and the phase distribution is uneven, which affects photon absorption and carrier transport.

Method used

A quasi-two-dimensional perovskite photodetector based on naphthylamine was prepared by solution method. The crystallinity and phase composition of the polycrystalline thin film were improved by adding an appropriate amount of MACl to the precursor solution and using antisolvent control. The device structure consists of ITO conductive glass, PEDOT:PSS anode buffer layer, quasi-two-dimensional perovskite polycrystalline thin film, C60/BCP cathode buffer layer and Ag cathode.

Benefits of technology

A highly crystalline quasi-two-dimensional perovskite polycrystalline thin film was achieved, which improved the current response capability and photoelectric conversion efficiency of the photodetector, exhibiting performance comparable to that of solar cells, with good current output and photoelectric conversion capability.

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Abstract

一种基于萘甲胺的准二维钙钛矿光电探测器及其制备方法,属于钙钛矿光电器件技术领域。器件依次由ITO导电玻璃阳极、PEDOT:PSS阳极缓冲层、准二维钙钛矿多晶薄膜、C60 / BCP阴极缓冲层、Ag阴极组成。钙钛矿材料为(NMA)2MA3Pb4I13,结晶后具有典型的准二维钙钛矿结构,由无机骨架和萘甲胺(NMA)间隔阳离子交替堆叠而成,其中无机骨架为4层[PbI4]2‑八面体紧密排布而成。本发明通过在前驱体溶液中加入适量的MACl并在旋涂中使用反溶剂调控(NMA)2MA3Pb4I13多晶薄膜的生长,有效提高了其结晶度,明确其相组成,并获得了电流响应可与太阳能电池相媲美的光电探测器。
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