一种协同回收废磷酸铁锂电池与废三元锂离子电池正极粉的方法

By using a synergistic leaching method with nitric acid and acetate as leaching agents, the problems of high energy consumption and high reagent costs in lithium-ion battery recycling have been solved, achieving efficient and low-cost recovery of valuable metals, simplifying the process and reducing pollutant emissions.

CN115954574BActive Publication Date: 2026-07-17XIANGTAN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIANGTAN UNIV
Filing Date
2023-01-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Among existing lithium-ion battery recycling methods, pyrometallurgical recycling is energy-intensive and emits polluting gases, while wet recycling consumes oxidants or reducing agents, resulting in high costs, increased production costs, and environmental pollution.

Method used

Nitric acid and acetate were used as leaching agents. Through synergistic action, the divalent iron in lithium iron phosphate was oxidized and the high-valent metal in lithium nickel cobalt manganese oxide was reduced to generate nitric oxide to improve utilization. Subsequently, a mixed salt solution of lithium, cobalt, nickel and manganese and solid iron phosphate were obtained by pH adjustment and co-precipitation. Finally, a carbonizing agent was added to obtain lithium carbonate.

Benefits of technology

It enables low-cost and high-efficiency recovery of valuable metals such as lithium, cobalt, nickel, and manganese, simplifies the process, reduces production costs, improves leaching efficiency, and reduces pollutant emissions.

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Abstract

本发明公开一种协同回收废磷酸铁锂电池与废三元锂离子电池正极粉的方法,涉及废锂电池资源循环技术领域。将废磷酸铁锂电池正极粉、废三元锂离子电池正极粉与水混合制成浆料,加入硝酸和乙酸盐作为浸出剂,使磷酸铁锂中的二价铁被氧化,同时生成一氧化氮,一氧化氮使镍钴锰酸锂中的镍、钴、锰被还原,从而获得锂、钴、镍、锰的混合盐溶液和磷酸铁固体,混合盐溶液通过湿法分离,得到镍钴锰三元前驱体材料和碳酸锂。本发明可协同处理废磷酸铁锂电池与废三元锂离子电池,无需消耗氧化还原药剂,即可实现废锂离子电池中有价金属的浸出回收,工艺简单,运行成本低,原料适用性强,有助于产业化应用。
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