A hydroxyl composition for preparing bio-based polyurethane and bio-based polyurethane

By using a specific hydroxyl composition to prepare bio-based polyurethane, the problem of insufficient fold resistance of bio-based polyurethane under low temperature conditions is solved, and a combination of high peel strength and excellent low temperature fold resistance is achieved.

CN115975149BActive Publication Date: 2025-03-25ZHEJIANG HUAFON SYNTHETIC RESIN
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Patent Information

Application Number
CN202310060994.5
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-01-16
Publication Date
2025-03-25
Estimated Expiration
2043-01-16

AI Technical Summary

Technical Problem

The existing bio-based polyurethane synthetic leather has poor fold resistance under low temperature conditions and cannot have high peel strength and excellent low temperature fold resistance.

Method used

Using a hydroxyl composition including vegetable oil polyol, bio-based polyol and chain extender, bio-based polyurethane with excellent low temperature resistance is prepared by defining the bio-based polyol as a bio-based polyether polyol and/or bio-based polyester polyol, and containing dimer acid and other dibasic acids in the polymeric monomer.

Benefits of technology

The excellent folding resistance and high peel strength of bio-based polyurethane under low temperature conditions have been achieved, and the problem that the prior art cannot have both of these properties.

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Abstract

The present invention provides a hydroxyl composition for preparing bio-based polyurethane and bio-based polyurethane. The hydroxyl composition comprises a combination of vegetable oil polyol, bio-based polyol and chain extender. The bio-based polyol comprises bio-based polyether polyol and / or bio-based polyester polyol, and the polymerized monomers of the bio-based polyester polyol comprise dimer acid and other dibasic acids except dimer acid. The above two polyols are matched within a specific range, so that the obtained hydroxyl composition is more suitable as component A of two-component bio-based polyurethane, and the combination with component B can make the synthesized bio-based polyurethane have both excellent low-temperature folding resistance and high peel strength.
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