Anti-dandruff and antipruritic shampoo containing plant formula and preparation method thereof

Abstract

The invention provides an anti-dandruff and anti-itching shampoo containing a plant formula and a preparation method thereof, and relates to the field of cosmetics. The raw materials of the shampoo include four phases, namely, A, B, C, and D. Among them, the C phase contains a hair conditioning agent, and the hair conditioning agent includes: ginseng root extract, chuanxiong root extract, polygonum multiflorum root extract, nasturtium flower extract, orientalis leaf extract, sophora flavescens root extract, ethanol, propylene glycol, black ganoderma lucidum extract, lindera striata root extract, crocus flower extract, panthenol, allantoin, methylparaben, DMDM ​​hydantoin, and bis(hydroxymethyl)imidazolidinyl urea. The shampoo prepared by compounding the raw materials has excellent anti-dandruff and anti-itching effects.

Description

Technical Field

[0001] The invention relates to the field of cosmetics, and in particular to an anti-dandruff and antipruritic shampoo containing a plant formula and a preparation method thereof. Background Art

[0002] Dandruff is a product of the metabolism of epidermal cells on the human head, which is usually caused by the destruction of the ecological balance of the scalp. At present, the methods for removing dandruff include the use of keratin peeling agents or cell growth inhibitors, but the above two drugs usually affect the balance of the epidermis and thus affect the hair quality, especially for sensitive skin. At present, the treatment of dandruff mostly adopts preventive measures, including the use of shampoos that can remove dandruff and relieve itching, so as to effectively regulate the scalp microenvironment and improve hair quality. Literature: Zi Yusha, Tang Xiaoqin, Chen Minghua. Research progress on the occurrence mechanism of dandruff and dandruff removal methods [J]. Guangdong Chemical Industry, 2020, 47(17):3. It proposes the use of antifungal ingredients (such as zinc pyrithione, active climbazole or OCT, etc.), repairing the scalp barrier (such as ceramide, niacinamide or surfactants, etc.), using mild surfactants or using conditioners that are not easy to accumulate.

[0003] However, the use of a single preparation to deal with dandruff and other problems is currently limited. Therefore, more researchers are preparing products such as shampoo by compounding various beneficial raw materials. For example, the literature: Cui Longhai. Research on the process and quality of anti-dandruff and antipruritic Chinese medicine compound [D]. Guangzhou University of Chinese Medicine, 2012. The content of four active ingredients, ferulic acid, quercetin, damipine, and matrine, was used as the optimization index to optimize the extraction process parameters of the compound. Another example is patent CN113230184A, which discloses a scalp composition for 1+1 cleaning of scalp and hair and a preparation method thereof. The composition comprises water and the following components in parts by weight: disodium lauryl sulfosuccinate, cocamide MEA, cocamidopropyl betaine, glycerol, glyceryl stearate, propylene glycol, polyquaternium-7, acrylic acid (ester) copolymer, sodium chloride, PEG-120 methyl glucose dioleate, PEG-7 glyceryl cocoate, PPG-3 octyl ether, guar hydroxypropyltrimethylammonium chloride, polyquaternium-10, essence, plant functional component, preservative, citric acid, panthenol, sodium hydroxide, DMDM ​​hydantoin, menthol, witch hazel extract, aloe extract, niacinamide, tocopherol acetate, pyridoxine HCl, piroctone olamine salt, allantoin and EDTA-disodium. The above composition can effectively remove scalp dirt and grease and promote hair follicle growth.

[0004] Another example is patent CN114469771A discloses a multifunctional anti-dandruff refreshing shampoo and a preparation method thereof, the shampoo comprises the following components in weight percentage: anionic surfactant 5-20%, cocamidopropyl betaine 1-10%, cocamide MEA 0.5-2%, anti-dandruff agent 0.1-1%, auxiliary anti-dandruff agent 0-2%, moisturizing agent 0-5%, hair conditioner 0-1%, thickener 0-2%, citric acid 0.05-0.4%, essence 0-2%, cooling agent 0-1%, preservative 0.00075-0.0015%, pure water supplemented to 100%, anti-dandruff agent is selected as at least one of piroctone olamine salt and piroctone olamine. On the basis of maintaining the moisture of the scalp, it can also play a barrier protection role, less stimulation to the scalp, maintain the acid-base balance of the scalp, and also has the effect of removing dandruff and relieving itching, keeping the scalp healthy.

[0005] However, existing shampoos with pure Chinese medicine formulas have poor effects or slow effects, while pure chemical shampoos are more irritating to the scalp and may even damage the scalp tissue, posing safety issues. In addition, long-term use of some shampoos will affect the balance of the epidermis and hair quality, thereby damaging the health of the scalp.

[0006] In view of the problems that the related anti-dandruff and anti-itching drugs or shampoos in the prior art affect the balance of the epidermis and hair quality, as well as the poor anti-dandruff and anti-itching effects, it is very necessary to find an anti-dandruff and anti-itching shampoo containing a plant formula and a preparation method thereof. Summary of the invention

[0007] The present invention aims at the problems existing in the prior art and provides an anti-dandruff and anti-itching shampoo containing a plant formula and a preparation method thereof. The prepared shampoo has excellent anti-dandruff and anti-itching effects through compounding of various raw materials.

[0008] To achieve the above purpose, the technical solution adopted by the present invention is as follows:

[0009] The present invention provides a shampoo, the raw materials of which include phase A, phase B, phase C and phase D;

[0010] The phase A comprises: a surfactant;

[0011] The phase B comprises: cocamide MEA, glycerin, microcrystalline cellulose, sodium benzoate, and stearamidopropyl dimethylamine;

[0012] The phase C comprises: hair conditioner, guar hydroxypropyltrimonium chloride, citric acid, polyquaternium-10, sodium acetate, sodium chloride, sodium chloride, and isopropyl alcohol;

[0013] The phase D comprises: hydrogenated castor oil, sodium methyl cocoyl taurate, cocamidopropyl betaine, lauric acid, phenoxyethanol, dimethicone, trideceth-3, trideceth-10, benzyl alcohol, tocopherol, laureth-16, polyquaternium-52, phenoxyethanol, methylparaben, glycerin, 1,3-propylene glycol, sodium isostearyl lactylate, dichlorobenzyl alcohol, sodium chloride, and ethylhexylglycerin;

[0014] The hair conditioning agent includes: ginseng root extract, chuanxiong root extract, polygonum multiflorum root extract, nasturtium flower extract, oriental arborvitae leaf extract, sophora flavescens root extract, ethanol, propylene glycol, black ganoderma lucidum extract, lindera stigmata root extract, saffron flower extract, panthenol, allantoin, methylparaben, DMDM ​​hydantoin, and bis(hydroxymethyl)imidazolidinyl urea.

[0015] Further, the shampoo, in parts by weight, the phase A comprises: 130-140 parts of surfactant;

[0016] The phase B comprises: 10-13 parts of cocamide MEA, 0.20-0.30 parts of glycerin, 0.01-0.05 parts of microcrystalline cellulose, 0.01-0.04 parts of sodium benzoate, and 2.50-3.50 parts of stearamidopropyl dimethylamine;

[0017] The phase C comprises: 5-15 parts of hair conditioner, 2.5-2.9 parts of guar hydroxypropyltrimonium chloride, 1-1.8 parts of citric acid, 0.8-0.91 parts of polyquaternium-10, 0.01-0.03 parts of sodium acetate, 0.01-0.03 parts of sodium chloride, and 0.01 parts of isopropyl alcohol;

[0018] The phase D comprises: 3.00-4.00 parts of hydrogenated castor oil, 3.00-4.50 parts of sodium methyl cocoyl taurate, 2.00-3.00 parts of cocamidopropyl betaine, 0.30-0.80 parts of lauric acid, 0.10-0.25 parts of phenoxyethanol, 11.00-12.00 parts of polydimethylsiloxane, 0.30-0.44 parts of trideceth-3, 0.30-0.45 parts of trideceth-10, 0.05-0.12 parts of benzyl alcohol, 0.00 0.2 parts of tocopherol, 0.45-0.52 parts of laureth-16, 0.30-0.35 parts of polyquaternium-52, 0.10-0.15 parts of phenoxyethanol, 0.05-0.10 parts of methylparaben, 0.35-0.55 parts of glycerin, 0.15-0.25 parts of 1,3-propylene glycol, 0.15-0.25 parts of sodium isostearyl lactylate, 0.10-0.15 parts of dichlorobenzyl alcohol, 4.00-6.00 parts of sodium chloride, 0.05-0.08 parts of ethylhexylglycerin.

[0019] Preferably, the shampoo, measured by weight, comprises: 133 parts of surfactant;

[0020] The phase B comprises: 12.00 parts of cocamide MEA, 0.25 parts of glycerin, 0.03 parts of microcrystalline cellulose, 0.03 parts of sodium benzoate, and 3.00 parts of stearamidopropyl dimethylamine;

[0021] The phase C comprises: 10 parts of hair conditioner, 2.70 parts of guar hydroxypropyltrimonium chloride, 1.50 parts of citric acid, 0.91 parts of polyquaternium-10, 0.02 parts of sodium acetate, 0.02 parts of sodium chloride, and 0.01 parts of isopropyl alcohol;

[0022] The phase D includes: 3.50 parts of hydrogenated castor oil, 3.50 parts of sodium methyl cocoyl taurate, 2.31 parts of cocamidopropyl betaine, 0.50 parts of lauric acid, 0.15 parts of phenoxyethanol, 11.41 parts of dimethicone, 0.36 parts of trideceth-3, 0.36 parts of trideceth-10, 0.09 parts of benzyl alcohol, 0.0002 parts of tocopherol, 0.47 parts of laureth-16, 0.31 parts of polyquaternium-52, 0.13 parts of phenoxyethanol, 0.07 parts of methylparaben, 0.47 parts of glycerin, 0.20 parts of 1,3-propylene glycol, 0.20 parts of sodium isostearyl lactylate, 0.13 parts of dichlorobenzyl alcohol, 5.00 parts of sodium chloride, and 0.06 parts of ethylhexylglycerin.

[0023] Furthermore, the weight ratio of phases A, B, C, and D in the present invention is 1:1:1:1.

[0024] Furthermore, the surfactant in phase A includes sodium laureth sulfate and / or sodium lauryl sulfate.

[0025] Furthermore, the hair conditioning agent comprises, by weight: 0.40-0.60 parts of ginseng root extract, 0.10-0.50 parts of chuanxiong root extract, 0.10-0.50 parts of polygonum multiflorum root extract, 0.10-0.50 parts of nasturtium flower extract, 0.10-0.40 parts of orientalis leaf extract, 0.10-0.40 parts of sophora flavescens root extract, 0.10-0.40 parts of ethanol, 0.10-0.30 parts of propylene glycol, 0.10-0.20 parts of black ganoderma lucidum extract, 0.05-0.10 parts of lindera serrata root extract, 0.02-0.05 parts of crocus flower extract, 0.02-0.03 parts of panthenol, 0.02-0.03 parts of allantoin, 0.02-0.03 parts of methylparaben, 0.01 parts of DMDM ​​hydantoin, 0.01 parts of bis(hydroxymethyl)imidazolidinyl urea.

[0026] Preferably, the hair conditioner comprises, by weight: 0.50 parts of ginseng root extract, 0.30 parts of chuanxiong root extract, 0.30 parts of polygonum multiflorum root extract, 0.30 parts of nasturtium flower extract, 0.25 parts of orientalis leaf extract, 0.25 parts of sophora flavescens root extract, 0.25 parts of ethanol, 0.20 parts of propylene glycol, 0.10 parts of black ganoderma lucidum extract, 0.07 parts of lindera serrata root extract, 0.03 parts of saffron flower extract, 0.02 parts of panthenol, 0.02 parts of allantoin, 0.02 parts of methylparaben, 0.01 parts of DMDM ​​hydantoin, and 0.01 parts of bis(hydroxymethyl)imidazolidinyl urea.

[0027] Furthermore, the raw materials also include preservatives, fragrances, and colorants.

[0028] Preferably, the preservative comprises one or more of piroctone olamine salt, DMDM ​​hydantoin and hexamidine di(hydroxyethylsulfonate) salt, the fragrance comprises (daily) fragrance, and the colorant comprises caramel color.

[0029] Furthermore, in the hair conditioner, the weight ratio of the Chuanxiong extract, the Nasturtium flower extract, the Sophora flavescens extract and the Crocus sativus extract is 0.1-0.5:0.1-0.5:0.1-0.4:0.02-0.05, preferably 0.3:0.3:0.25:0.03.

[0030] Furthermore, the weight ratio of the hair conditioner, guar hydroxypropyltrimethylammonium chloride and stearamidopropyl dimethylamine is 5-15:2.5-3.5:2.5-3.5, preferably 10:2.7:3.

[0031] Furthermore, the present invention also provides a method for preparing the above-mentioned shampoo, comprising the following steps:

[0032] (1) Mix the raw materials of phase A, stir and heat them, add the raw materials of phase B after they are completely dissolved, and keep the temperature constant to obtain material A;

[0033] (2) Pre-disperse the phase C raw material and water until there are no lumps, homogenize, add to material A, stir at a constant temperature, and cool down; add the phase D raw material, stir evenly until there are no solid particles, and cool to obtain.

[0034] In some specific embodiments, the method for preparing the shampoo comprises the following steps:

[0035] (1) After the surfactant and water are mixed, the mixture is stirred and heated, and after the surfactant is completely dissolved, cocamide MEA, glycerin, microcrystalline cellulose, sodium benzoate, stearamidopropyl dimethylamine and water are added, and the temperature is kept constant to obtain material A;

[0036] (2) Pre-disperse hair conditioner, guar hydroxypropyltrimonium chloride, citric acid, polyquaternium-10, sodium acetate, sodium chloride, isopropyl alcohol and water until there are no lumps, homogenize, add to material A, stir at a constant temperature, and cool; add hydrogenated castor oil, sodium methyl cocoyl taurate, cocamidopropyl betaine, lauric acid, phenoxyethanol, dimethicone, trideceth-3, trideceth-10, benzyl alcohol, ethylhexylglycerin, tocopherol, laureth-16, polyquaternium-52, phenoxyethanol, methylparaben, glycerin, 1,3-propylene glycol, sodium isostearyl lactylate, dichlorobenzyl alcohol, sodium chloride, preservatives, fragrance, colorant and water, stir evenly until there are no solid particles, and cool to obtain the mixture.

[0037] Furthermore, the heating temperature in step (1) is 80-85°C.

[0038] Furthermore, the constant temperature time in step (1) is 15 minutes.

[0039] Furthermore, the cooling temperature in step (2) is below 40°C.

[0040] Furthermore, the constant temperature time in step (2) is 30 minutes, and the amount of water added in the pre-dispersion is 20 times the total mass of the phase C raw material.

[0041] The technical effects achieved by the present invention are:

[0042] The present invention adopts natural plant raw materials, such as ginseng root extract, chuanxiong root extract, polygonum multiflorum root extract and nasturtium extract, etc., and uses them together with raw materials A, B, C, D and other phases. The shampoo finally prepared has good anti-dandruff and antipruritic effects. BRIEF DESCRIPTION OF THE DRAWINGS

[0043] Figure 1 The dandruff grade of the shampoo in Example 1 is shown below;

[0044] Figure 2 The dandruff grade of the shampoo in Example 2 is shown below;

[0045] Figure 3 The dandruff grade of the shampoo in Example 3 is shown below;

[0046] Figure 4 The dandruff grade of the shampoo in Example 4 is shown below;

[0047] Figure 5 The following is the dandruff level when the shampoo in Example 5 is used. DETAILED DESCRIPTION

[0048] The following describes the embodiments of the present invention through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and the details in this specification can also be modified or changed in various ways based on different viewpoints and applications without departing from the spirit of the present invention.

[0049] Before further describing the specific embodiments of the present invention, it should be understood that the scope of protection of the present invention is not limited to the specific embodiments described below; it should also be understood that the terms used in the examples of the present invention are for describing specific embodiments rather than for limiting the scope of protection of the present invention.

[0050] When the embodiment gives a numerical range, it should be understood that, unless otherwise specified in the present invention, the two endpoints of each numerical range and any numerical value between the two endpoints can be selected. Unless otherwise defined, all technical and scientific terms used herein have the same meanings as those of ordinary skill in the art to which the present invention belongs.

[0051] It is worth noting that the PANAX GINSENG root extract, LIGUSTICUM CHUANXIONG root extract, POLYGONUM MULTIFLORUM root extract, TROPAEOLUM MAJUS flower extract, PLATYCLADUS ORIENTALIS leaf extract, SOPHORAANGUSTIFOLIA root extract, GANODERMA ATRUM extract, LINDERASTRYCHNIFOLIA root extract, CROCUS SATIVUS flower extract, DICTAMNUSDASYCARPUS root extract, and MENTHA ARVENSIS extract used in the present invention are all purchased from Junli (Guangdong) Biotechnology Co., Ltd., and the remaining raw materials are all common commercially available products, so their sources are not specifically limited.

[0052] The formula of the shampoo corresponding to Examples 1-5 is shown in Table 1:

[0053] Table 1 The formula of the shampoo in Examples 1-5 (unit: part)

[0054]

[0055]

[0056]

[0057] Comparative Example 1

[0058] The only difference from Example 1 is that no hair conditioner is added, and instead, equal amounts of guar hydroxypropyltrimethylammonium chloride and stearamidopropyl dimethylamine are added, that is, the total amounts of guar hydroxypropyltrimethylammonium chloride and stearamidopropyl dimethylamine in the shampoo are 5 parts and 5 parts, respectively.

[0059] Comparative Example 2

[0060] The only difference from Example 1 is that guar hydroxypropyltrimonium chloride is not added, and an equal amount of hair conditioner and stearamidopropyl dimethylamine are added instead, that is, the total amounts of hair conditioner and stearamidopropyl dimethylamine in the shampoo are 6.7 parts and 3.3 parts, respectively.

[0061] Comparative Example 3

[0062] The only difference from Example 1 is that stearamidopropyl dimethylamine is not added, and an equal amount of hair conditioner and guar hydroxypropyltrimonium chloride are added instead, that is, the total amounts of hair conditioner and guar hydroxypropyltrimonium chloride in the shampoo are 6.7 parts and 3.3 parts, respectively.

[0063] Comparative Example 4

[0064] The only difference from Example 1 is that the weight ratio of Chuanxiong extract, Nasturtium extract, Sophora flavescens extract and Crocus sativus extract is 0.05:0.7:0.05:0.5 (that is, the weight portions of the four added to the shampoo are approximately 0.01 parts, 0.17 parts, 0.01 parts and 0.13 parts respectively).

[0065] Comparative Example 5

[0066] The only difference from Example 1 is that the ginseng root extract is replaced by an equal amount of Dictamni root extract, and the nasturtium flower extract is replaced by an equal amount of peppermint extract.

[0067] Wherein, the preparation method of the shampoo in Examples 1-3 comprises the following steps:

[0068] (1) After the surfactant and water are mixed, the mixture is stirred and heated to 80°C. After the surfactant is completely dissolved, cocamide MEA, glycerin, microcrystalline cellulose, sodium benzoate, stearamidopropyl dimethylamine and water are added and the mixture is kept at a constant temperature for 15 minutes to obtain material A;

[0069] (2) Pre-disperse hair conditioner, guar hydroxypropyltrimonium chloride, citric acid, polyquaternium-10, sodium acetate, sodium chloride, isopropyl alcohol and water (the amount of water added is 20 times the total mass of the above raw materials) until there are no lumps, homogenize for 3 minutes, add to material A, stir at a constant temperature for 30 minutes, and cool to below 40°C; add hydrogenated castor oil, sodium methyl cocoyl taurate, cocamidopropyl betaine, lauric acid, phenoxyethanol, polydimethylsiloxane, trideceth-3, trideceth-10, benzyl alcohol, ethylhexylglycerin, tocopherol, laureth-16, polyquaternium-52, phenoxyethanol, methylparaben, glycerin, 1,3-propylene glycol, sodium isostearyl lactylate, dichlorobenzyl alcohol, sodium chloride, preservatives, fragrance, colorant and water, stir evenly until there are no solid particles, and cool to obtain the mixture.

[0070] The preparation methods of the shampoos in Examples 4-5 and the control examples are the same as those in Examples 1-3, with the raw materials being deleted and replaced according to the formula.

[0071] 1. Study on the Itch Threshold Test of Histamine Phosphate

[0072] Experimental animals: guinea pigs, half male and half female, weighing 250-400 g;

[0073] Test method: The dorsum of the right hind paw of the guinea pig was shaved one day before the test, and the guinea pigs were randomly divided into 11 groups, with 5 in each group. Except for the blank group, 0.2 mL / 100 g of the shampoo in each example of the present invention was applied to the shaved area in the other groups, and the blank group was applied with an equal amount of physiological saline. After 2 consecutive days, on the third day, histamine phosphate was dripped into the depilated area until the guinea pig turned back and licked its right hind paw. The total amount of histamine phosphate administered was calculated as the itch threshold, and the results were statistically recorded in Table 2.

[0074] Table 2 Effects of shampoo on the itch threshold of histamine phosphate in guinea pigs

[0075] Examples Itch threshold (μg) Example 1 210.5±65.7** Example 2 216.0±69.5** Example 3 225.5±72.4** Example 4 220.5±70.9** Example 5 213.0±78.3** Comparative Example 1 165.5±84.2* Comparative Example 2 184.5±88.6* Comparative Example 3 198.0±80.0** Comparative Example 4 185.5±63.5** Comparative Example 5 173.0±75.2* Blank Group 56.5±22.6

[0076] (Compared with the blank group, *: p < 0.05; **: p < 0.01).

[0077] According to the results in Table 2, the shampoo of the present invention can significantly increase the itch threshold of histamine phosphate on guinea pigs compared with the blank group, indicating that the shampoo of the present invention has a significant antipruritic effect. In comparison, the antipruritic effect of the shampoo in the control example is weaker than that of the product of the present invention.

[0078] 2. Research on anti-dandruff and anti-itching in the population

[0079] The "10-level evaluation method for sticky dandruff" is used for evaluation, and the specific indicators are as follows:

[0080] (1) Level 0: no dandruff;

[0081] (2) Grade 1-2: small pieces of powdery grayish-white rough scales;

[0082] (3) Grade 3-4: small to medium chips;

[0083] (4) Grade 5-6: Large, thin flakes loosely connected on the scalp;

[0084] (5) Grade 7-8: Adhesive flakes;

[0085] (6) Grade 9-10: Thick white to yellow scales that are tightly attached to the scalp.

[0086] Test population: volunteers with dandruff ≥ grade 3;

[0087] Test method: Randomly divide into 5 groups, 3 people in each group, use the shampoo of Examples 1-5 of the present invention respectively, male wash hair once a day, female wash hair once every two days, observe the dandruff level at the end of the 0th week and the 4th week (efficacy observation index: observe the dandruff attached to the scalp and the hair within 4 cm above the hair root in the area to grade), the statistical results are as follows Figure 1-5 shown.

[0088] according to Figure 1-5 The results show that the shampoos in various embodiments of the present invention all have good anti-dandruff effects.

[0089] Finally, it should be noted that the above content is only used to illustrate the technical solution of the present invention, rather than to limit the scope of protection of the present invention. Simple modifications or equivalent substitutions of the technical solution of the present invention by ordinary technicians in this field do not deviate from the essence and scope of the technical solution of the present invention.

Claims

1. A shampoo, characterized in that: The raw material is made of phase A, phase B, phase C and phase D; The phase A is composed of the following ingredients by weight: 697.3 parts of water, 105 parts of sodium laureth sulfate and 45 parts of water, 28 parts of sodium lauryl sulfate and 12 parts of water; The phase B is composed of the following ingredients: 12 parts of cocamide MEA, 4.7 parts of water, 0.25 parts of glycerin, 0.03 parts of microcrystalline cellulose and 0.03 parts of sodium benzoate, 3 parts of stearamidopropyl dimethylamine; Phase C is composed of the following ingredients: 10 parts of hair conditioner, 2.7 parts of guar hydroxypropyltrimonium chloride and 0.3 parts of water, 1.5 parts of citric acid, 0.91 parts of polyquaternium-10, 0.05 parts of water, 0.02 parts of sodium acetate, 0.02 parts of sodium chloride and 0.01 parts of isopropyl alcohol; The D phase is composed of the following ingredients: 15 parts of water, 3.5 parts of hydrogenated castor oil, 3.5 parts of sodium methyl cocoyl taurate, 2.31 parts of cocamidopropyl betaine, 0.50 parts of lauric acid, 0.15 parts of phenoxyethanol and 0.04 parts of ethylhexylglycerin, 11.41 parts of dimethicone, 5.76 parts of water, 0.36 parts of trideceth-3, 0.36 parts of trideceth-10, 0.09 parts of benzyl alcohol, 0.02 parts of ethylhexylglycerin and 0.0002 parts of glycerin. 1 part tocopherol, 12.03 parts water, 0.47 parts laureth-16, 0.31 parts polyquaternium-52, 0.13 parts phenoxyethanol and 0.07 parts methylparaben, 0.47 parts glycerin, 0.2 parts 1,3-propylene glycol, 0.2 parts sodium isostearyl lactylate and 0.13 parts dichlorobenzyl alcohol, 5 parts sodium chloride, 0.4 parts piroctone olamine salt, 4 parts fragrance, 2 parts DMDM ​​hydantoin, 0.8 parts hexamidine di (hydroxyethyl sulfonic acid) salt, 0.4 parts caramel color; The hair conditioner is composed of the following ingredients: 7.37 parts of water, 0.5 parts of ginseng root extract, 0.3 parts of Chuanxiong root extract, 0.3 parts of Polygonum multiflorum root extract, 0.3 parts of Nasturtium flower extract, 0.25 parts of Platycladus orientalis leaf extract, 0.25 parts of Sophora flavescens root extract, 0.25 parts of ethanol, 0.2 parts of propylene glycol, 0.1 parts of Ganoderma lucidum extract, 0.07 parts of Linderae umbellata root extract, 0.03 parts of Crocus sativus flower extract, 0.02 parts of panthenol, 0.02 parts of allantoin, 0.02 parts of methylparaben, 0.01 parts of DMDM ​​hydantoin and 0.01 parts of bis(hydroxymethyl)imidazolidinyl urea.

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