一种双一维纳米互穿结构的复合材料及其制备方法和应用

By using a composite material with an interpenetrating porous silicon nanowire and carbon nanotube structure, the stability problem of silicon-based anode materials caused by volume expansion in lithium-ion batteries has been solved, resulting in a high-capacity and long-life lithium-ion battery anode suitable for commercial applications.

CN116111076BActive Publication Date: 2026-07-17HUBEI WANRUN NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI WANRUN NEW ENERGY TECH CO LTD
Filing Date
2023-02-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-based anode materials suffer from structural instability due to volume expansion in lithium-ion batteries, affecting battery performance. Current technologies struggle to achieve a balance between high capacity, stability, and low cost for commercial application.

Method used

A double one-dimensional nano-interpenetrating structure is formed by porous silicon nanowires and carbon nanotubes. The silicon-carbon chemical bonds are used to buffer the volume expansion of carbon nanotubes, forming a stable SEI film. The composite material is then prepared by combining the carbon coating process.

Benefits of technology

It achieves high capacity and long lifespan for lithium-ion battery anodes, maintains battery performance stability by buffering volume expansion, and has a simple process, low cost, and is suitable for mass production.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供了一种双一维纳米互穿结构的复合材料及其制备方法,双一维纳米互穿结构的复合材料以硅纳米管和碳纳米管组成,由埃洛石经煅烧、酸洗以及铝热还原后与功能碳纳米管分散混合得到硅纳米线 / 碳纳米管双一维纳米互穿复合结构,其复合界面存在硅纳米线和碳纳米管之间的硅‑碳化学键结合,双一维纳米互穿复合结构的通过活性炭实现对复合结构包裹。在锂离子电池充放电过程中,双一维纳米互穿结构的复合材料作为电池负极能够利用其结构限域特性将硅基活性成分充放电引起的体积膨胀收缩抵消在结构内部,不引起整体的膨胀收缩以及应力集中,从而稳定电池负极的性能,获得高度可逆的充放电容量,大幅提高负极材料使用寿命。
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