一种锌离子电池用水 / 有机混合电解液

By introducing formamide into an aqueous zinc-ion battery to form a water/formamide mixed electrolyte, the problems of zinc anode corrosion, low-temperature solidification, and poor stability of cathode materials are solved, achieving high safety and high cycle stability of zinc-ion batteries.

CN116130802BActive Publication Date: 2026-07-17DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Filing Date
2021-11-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing aqueous zinc-ion batteries suffer from problems such as dendritic corrosion of the zinc negative electrode, electrolyte solidification at low temperatures, and poor cycle stability of the positive electrode material. Furthermore, the introduction of organic electrolytes increases flammability.

Method used

A water/formamide mixed electrolyte is used. By adding an appropriate amount of formamide to the zinc salt aqueous solution, a non-flammable mixed electrolyte is formed, which improves the stability of the zinc negative electrode, lowers the solidification point of the electrolyte, and improves the cycle stability of the positive electrode material.

Benefits of technology

Stable operation of zinc-ion batteries at room temperature and low temperature was achieved, zinc dendrite formation was suppressed, and battery safety and cycle stability were improved.

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Abstract

本发明公开了一种水系锌离子电池电解液,所述电解液包括锌盐和溶剂,所述溶剂包括水和甲酰胺。所述甲酰胺占溶剂的质量百分比为10‑60%。本发明通过在锌盐的水溶液中添加适量的甲酰胺构成水 / 有机混合电解液,在保证电解液不可燃的前提下有效提高了锌负极的稳定性,降低了电解液的凝固点,实现了‑40℃下可逆的锌沉积溶解,提高了正极材料的循环稳定性,从而改善了锌离子电池在室温、低温下的循环性能。
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