锂二次电池用正极活性材料、包含其的正极和锂二次电池

By doping or coating lithium nickel cobalt manganese oxides with metal compounds and controlling the grain size, nickel-based lithium composite metal oxide monomer particles were prepared, solving the problem of poor lifespan characteristics of NCMs at high voltages and achieving stable and efficient performance of batteries at high voltages.

CN116154148BActive Publication Date: 2026-07-17LG ENERGY SOLUTION LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LG ENERGY SOLUTION LTD
Filing Date
2018-11-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium nickel cobalt manganese oxide (NCM) cathode active materials have poor lifespan characteristics at high voltages, leading to rapid deterioration of battery performance and failing to meet the requirements for stable use at high voltages.

Method used

Nickel-based lithium composite metal oxide monomer particles are prepared by doping them in the crystal lattice or coating them with a specific metal compound, controlling the metal content between 2500ppm and 6000ppm, and calcining them at temperatures above 960℃ to form grains of 180nm to 300nm, thereby reducing the reaction interface with the electrolyte.

Benefits of technology

It improves the lifespan characteristics and structural stability of lithium secondary batteries under high voltage, reduces side reactions, and enhances the high-voltage performance and high-temperature lifespan characteristics of the batteries.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及一种锂二次电池用正极活性材料、包含其的正极和锂二次电池,所述正极活性材料包含镍基锂复合金属氧化物单体颗粒,其中,所述单体颗粒包含多个晶粒和掺杂在所述单体颗粒的晶格中的金属M,所述金属M是选自由Al、Ti、Mg、Zr、W、Y、Sr、Co、Si、Mg、Na、Cu、Fe、Ca和B组成的组的一种或多种金属,其中,所述单体颗粒的平均粒径D50为3.5μm以上至8μm以下。
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