用于中小型锅炉烟气处理的络合吸收及生物还原反应系统

By using a complexation absorption and bioreduction reaction system, Fe(II)EDTA and a single-column double-head MBfR reactor to treat flue gas from small and medium-sized boilers, the high cost and secondary pollution problems of flue gas denitrification treatment for small and medium-sized coal-fired industrial boilers have been solved, achieving efficient and environmentally friendly NOx removal.

CN116173682BActive Publication Date: 2026-07-17SUZHOU UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SUZHOU UNIV OF SCI & TECH
Filing Date
2023-03-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The denitrification treatment of flue gas from small and medium-sized coal-fired industrial boilers is characterized by high cost, large footprint, and secondary pollution. Traditional bioreactors suffer from complex structure, uneven distribution of pollutants, and packing blockage. Furthermore, the addition of organic carbon sources increases reaction costs and CO2 emissions.

Method used

A complexation absorption and bioreduction reaction system is adopted, including a complexation absorption system, a bioreduction system and an external circulation system. A single-column double-head MBfR reactor is used. NOx is absorbed by Fe(II)EDTA complexation and recycled in the bioreduction system. Zero-valent nano iron and methane are used as electron donors for the reduction reaction, avoiding the toxicity of external organic matter and oxygen to microorganisms.

Benefits of technology

It achieves efficient NOx absorption and reduction, reduces reaction costs, reduces pollutant emissions, conforms to the concept of environmental protection and sustainable economic development, and improves the stability and processing capacity of the reactor.

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Abstract

本发明属于生物法烟气脱硝处理技术领域,具体涉及一种用于中小型锅炉烟气处理的络合吸收及生物还原反应系统。其包括吸收烟气中NOx的络合吸收系统、还原络合产物的生物还原系统,以及连通络合吸收系统与生物还原系统的外循环系统,所述络合吸收系统是通过络合吸收液吸收NOx后排出合格气体,所述络合吸收系统产生的络合产物经所述生物还原系统还原后返回络合吸收系统循环使用,所述生物还原系统采用单柱双头MBfR。与现有技术相比具有如下优势:络合吸收速率快,效果好,吸收液可直接被生物还原;清洁环保,经济有效;可通过生物还原系统循环利用,菌群不与烟气直接接触,让体系拥有更好的NO去除性能和更大的处理负荷。
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