一种硼铁混合精矿中硼和铁的分离回收方法

By combining microwave heat treatment with a mixture of reducing agent and sodium salt, the problem of low selectivity in the separation of boron and iron in boron-iron mixed concentrate has been solved, achieving efficient and low-cost separation and recovery of boron and iron, which is suitable for electric arc furnace steelmaking raw materials.

CN116200594BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2022-03-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing smelting methods for boron-iron mixed concentrates, the selectivity and recovery rate of boron and iron separation are not high. Traditional pyrometallurgical processes suffer from low activity of boron-rich slag and high cost and long time of sodium reduction process.

Method used

A mixture of microwave heat treatment, reducing agent, and sodium salt was used to treat boron-iron mixed concentrate. This was followed by leaching and magnetic separation. The microwave heat treatment temperature and composition ratio were controlled to achieve highly selective separation of boron and iron.

Benefits of technology

It achieves highly selective conversion and effective separation of boron and iron, reduces production costs, is environmentally friendly, and is suitable for the requirements of raw materials for electric arc furnace steelmaking.

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Abstract

本发明属于冶金领域,具体涉及一种硼铁混合精矿中硼和铁的分离回收方法,将包含硼铁混合精矿、还原剂、钠盐的混合料进行微波热处理,随后将得到的热处理产物进行浸出、磁选处理,得到富硼液和直接还原铁粉;所述的混合料中,还原剂与硼铁混合精矿的质量比为(0.10‑0.20):1;添加剂钠盐中钠元素与硼铁混合精矿的质量比为(0.04‑0.10):1;微波热处理的温度为600~900℃。本发明研究发现,创新地将硼铁混合精矿、还原剂、钠盐的混合料在微波下热处理,进一步通过成分的比例以及微波热处理温度参数的联合控制,能够实现协同,能够调控目标反应的选择性,可以基于全新的反应机制对硼‑铁物相进行高选择性、温和转型转化,还利于后续硼和铁的高选择性分离。
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