一种双电子转移卤素液流电池电解液及其应用

By introducing bromide and chloride ions under acidic conditions to form a stable interhalogen compound, bromide dichloride, the problems of low energy density and halogen ion corrosion in flow batteries are solved. This achieves dual electron transfer, improves the energy density and stability of the battery, and reduces costs.

CN116207315BActive Publication Date: 2026-07-17DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Filing Date
2021-12-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Flow batteries have low energy density, which is limited by the solubility of active materials and the number of electrons transferred, resulting in high costs. Halogen ions, such as elemental bromine, have problems with corrosivity, volatility, and diffusion. Furthermore, the transformation of halogen ions into elemental substances involves only one electron transfer, which limits the energy density.

Method used

By introducing bromide and chloride ions under acidic conditions, a relatively stable interhalogen compound, bromide dichloride, is formed, achieving two-electron transfer. By utilizing the characteristics of bromide and chloride ions, the energy density is increased while reducing corrosivity and volatility.

Benefits of technology

It achieves higher open-circuit voltage and energy density, reduces costs, improves coulombic efficiency and voltage efficiency, and has stable battery performance, featuring low cost and high energy density.

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Abstract

本申请公开了一种双电子转移卤素液流电池电解液及其应用,属于液流电池领域。所述电解液中同时采用了溴离子和氯离子作为活性物质。在酸性条件下,利用溴和氯之间的卤素相互作用,可以实现从溴离子到溴单质再到二氯化溴离子的可逆两电子转移反应,二氯化溴离子可以通过加入一定量的络合剂稳定。相比于溴的单电子转移反应,这种方法具有更高的开路电压和能量密度。利用所述方法组装的液流电池,能够获得较长的循环寿命和较高的电池效率。
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