一种隔离膜及其制备方法与化学电池

By attaching a nanofiber layer to the surface of a porous polyolefin separator, the problems of short circuits and poor wettability of polyolefin separators under extreme conditions are solved, resulting in a separator with high efficiency in liquid absorption and retention and good heat resistance, thus improving the overall performance of lithium-ion batteries.

CN116207439BActive Publication Date: 2026-07-17SHANGHAI ENERGY NEW MATERIALS TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI ENERGY NEW MATERIALS TECHNOLOGY CO LTD
Filing Date
2023-03-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyolefin separators are prone to causing internal short circuits in batteries under extreme conditions, and have poor wettability to electrolytes, affecting the performance and lifespan of lithium-ion batteries.

Method used

A nanofiber layer is attached to the surface of a porous polyolefin membrane using an electrospinning process. The high porosity of the nanofiber layer is formed by the combination of polyamide and PVA binder in the spinning solution, which enhances the mechanical strength and heat resistance of the membrane and improves the wettability of the electrolyte.

Benefits of technology

It improves the heat resistance of the separator and the liquid absorption and retention performance of the electrolyte, enhances the charge and discharge capacity and cycle performance of lithium-ion batteries, improves mechanical strength, shortens electrolyte diffusion time, and reduces thermal shrinkage rate.

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Abstract

本申请实施例提供一种隔离膜及其制备方法与化学电池,涉及化学电池领域。隔离膜包括基材层和附着于基材层至少一侧表面上的纳米纤维层,基材层和纳米纤维层之间的剥离强度为50N / m以上,基材层为多孔聚烯烃类隔膜,纳米纤维层是由纳米纤维构成且纳米纤维之间具有空隙,纳米纤维是由纺丝液固化形成,纺丝液含有聚酰胺、PVA粘合剂和溶剂,且以聚酰胺、PVA粘合剂的总重量为100份计算,聚酰胺的重量份数为50.0~98.0份,PVA粘合剂的重量为2.0~50.0份。隔离膜具有高孔隙率,高耐热等特性;且浸润性好,具有高效吸液和良好保液性能。
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