一种硅掺杂石墨烯制备的赝电容性水系钙离子电池负极及其在水系钙离子电池中的应用

The pseudocapacitive aqueous calcium-ion battery anode was prepared by using silicon-doped graphene, which solved the problem of low energy density of graphene materials and achieved high energy and high power density calcium-ion storage, making it suitable for aqueous calcium-ion battery anodes.

CN116230840BActive Publication Date: 2026-07-17XIAN TECH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XIAN TECH UNIV
Filing Date
2023-03-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

When existing graphene materials are used as anode materials for calcium-ion batteries, their energy density is low and cannot meet the needs of practical applications.

Method used

A pseudocapacitive aqueous calcium-ion battery anode was prepared using silicon-doped graphene. Silicon-doped graphene was prepared by high-temperature pyrolysis of ethyl silicate and monolayer graphene under nitrogen protection. The graphene was then mixed with acetylene black and polyvinylidene fluoride and coated onto carbon paper to form the anode. Combined with a unique sintering process, a highly efficient pseudocapacitive calcium-ion storage material was formed.

Benefits of technology

It achieves high energy density and high power density calcium ion storage, has good Ca2+ adsorption and desorption properties, is suitable for aqueous calcium ion battery anodes, and has broad application prospects.

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Abstract

一种硅掺杂石墨烯制备的赝电容性水系钙离子电池负极及其在水系钙离子电池中的应用,将赝电容性钙离子电池负极材料、乙炔黑、聚偏氟乙烯按照质量比8:1:1加入到无水乙醇中,充分研磨后获得均匀浆料;将浆料涂覆在碳纸上,然后,在100℃、真空条件下干燥,裁剪得到赝电容性水系钙离子电池负极;所述电容性钙离子电池负极材料包括能容许组成钙盐的阳离子Ca2+可逆地化学吸附 / 脱附的硅掺杂石墨烯,且石墨烯为单层石墨烯、硅掺杂石墨烯的硅掺杂含量为2.68at%。优点是:该水系钙离子电池负极具有赝电容性,应用于水系钙离子电池,同时满足能量密度和功率密度双高的需要,是一种非常有前景的赝电容性钙离子存储负极材料。
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