一种颗粒堆积型电化学反应装置及其在电化学氧还原法制备过氧化氢中的应用

By designing an inverted U-shaped electrochemical reactor and a particle electrode bed, the problem of small three-phase reaction interface in traditional electrodes was solved, enabling efficient oxygen utilization and hydrogen peroxide production, which is applicable to the energy and environmental fields.

CN116265613BActive Publication Date: 2026-07-17DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Filing Date
2021-12-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The small gas-liquid-solid three-phase reaction interface of traditional gas diffusion electrodes results in low oxygen utilization and low efficiency of hydrogen peroxide production, making it difficult to rapidly produce large quantities of hydrogen peroxide.

Method used

Design an inverted U-shaped electrochemical reactor comprising a cathode and an anode reaction chamber. Use particle electrodes to fill the particle electrodes. The reactor is a three-phase reactor provided by a particle electrode bed. The particle electrodes are spherical or irregular in shape and have an appropriate filling height. Combined with an ion exchange membrane and a highly conductive electrode rod, a highly efficient gas-liquid-solid three-phase contact point is formed.

Benefits of technology

It improves oxygen utilization and hydrogen peroxide production efficiency, enabling efficient distributed hydrogen peroxide production, and is suitable for the energy and environmental sectors.

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Abstract

本申请公开了一种颗粒堆积型电化学反应装置及其在电化学氧还原法制备过氧化氢中的应用,属于电化学反应装置领域。该装置包括阴极反应室和阳极反应室,二者经连通部连通形成倒U型反应器;连通部内部径向方向设离子交换膜;阴极反应室的下部设置有阴极进气口和阴极进水口,上部设置有阴极出水口;阳极反应室的上部和下部分别设置有阳极进水口和阳极出水口;阴极反应室和阳极反应室内部分别设有与外电路连接的阴极和阳极;阴极反应室内装填有粒子电极。该装置中填装颗粒型气体扩散电极,利用颗粒在气体流动过程的再分散作用,有效提高电产过氧化氢过程中的氧气利用率,且粒子电极较大的面体比大幅提高了电化学还原氧气制备过氧化氢的效率。
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