一种可回收形状记忆液晶环氧树脂及其制备方法和应用

By preparing liquid crystal epoxy resin and utilizing transesterification dynamic covalent bonds, the problem of uncontrollable lubrication performance of traditional lubricating materials in harsh environments has been solved, realizing intelligent lubrication and material recycling, and exhibiting good mechanical and self-lubricating properties.

CN116284685BActive Publication Date: 2026-07-17LANZHOU INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LANZHOU INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Filing Date
2023-04-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional lubricating materials are difficult to control and adjust in harsh environments, and have poor mechanical properties, making them difficult to recycle.

Method used

Using liquid crystal epoxy resin as the base material, shape memory liquid crystal epoxy resin containing transesterification dynamic covalent bonds is prepared through thiol-epoxy click reaction. The lubrication performance is regulated by the crystalline-amorphous transformation of the mesocrystalline unit, and the material is recycled through transesterification dynamic covalent bonds.

Benefits of technology

It achieves intelligent control of lubrication performance, requires no additional lubricant, has good mechanical properties and self-lubricating properties, and the material is recyclable and suitable for use in a wide temperature range.

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Abstract

本发明涉及润滑材料技术领域,提供了一种可回收形状记忆液晶环氧树脂及其制备方法和应用。本发明以液晶环氧单体和多硫醇类化合物为主要原料,通过硫醇‑环氧点击反应制备含有酯交换动态共价键的形状记忆液晶环氧树脂,利用介晶单元的晶态和非晶态之间的动态转换,可以实现对其润滑性能的调控。而且,利用酯交换动态共价键,可以实现液晶环氧树脂的回收,回收后再制备的材料依旧具有良好的自润滑性能;本发明提供的液晶环氧树脂还具有较好的机械性能,在智能润滑材料领域具有广阔的应用前景。
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