一种金属硒化物 / 碳复合电极材料及其制备方法与应用

The metal selenide/carbon composite electrode material prepared by electrospinning and a two-step calcination process solves the problems of volume expansion and low conductivity of traditional lithium-ion battery anode materials, achieving simple and efficient synthesis and excellent electrochemical performance.

CN116314764BActive Publication Date: 2026-07-17XUZHOU NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XUZHOU NORMAL UNIVERSITY
Filing Date
2023-02-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional lithium-ion battery anode materials, such as metal selenides, suffer from volume expansion and low conductivity, resulting in poor capacity and short cycle life. Existing synthesis methods are complex and time-consuming.

Method used

Metal selenide/carbon composite electrode materials were prepared by electrospinning combined with a two-step calcination process. The carbon nanofiber network structure was formed by electrospinning, and metal selenide nanoparticles were uniformly dispersed on its surface, which simplified the synthesis process and improved the conductivity.

Benefits of technology

We have achieved efficient preparation of metal selenide/carbon composite materials with good conductivity and stable cycle performance, which improves the rate performance and cycle life of lithium-ion batteries.

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Abstract

一种金属硒化物 / 碳复合电极材料及其制备方法和应用,该方法包括以下步骤:将高分子聚合物和有机配体分散在溶剂中,并在设定温度下搅拌以形成静电纺丝前驱体溶液,接着进行静电纺丝,得到有机配体 / 高分子聚合物纳米纤维膜;将纳米纤维膜在含目标金属的金属盐和有机配体溶液中浸泡,洗涤,烘干,生成金属有机框架化合物 / 高分子聚合物纳米纤维膜;将纤维膜在一定条件下进行预煅烧后,加入硒粉混合研磨,随后在保护气体下进行硒化‑碳化处理,得到目标金属硒化物 / 碳复合电极材料。该合成方法简便,重复性好,成本低廉,适合规模化生产;所制备出的复合电极材料提高了活性物质的利用率,将其用于锂离子电池负极材料时,显示出良好的电化学性能。
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