A symmetrical solid oxide fuel cell material and method of making the same

CN116314877BActive Publication Date: 2026-08-28UNIV OF SCI & TECH LIAONING
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Patent Information

Application Number
CN202310111134.X
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-02-14
Publication Date
2026-08-28
Estimated Expiration
2043-02-14

AI Technical Summary

Technical Problem

双钙钛矿结构Sr2TiFeO6-δ材料做为固体氧化物电池阴极材料取得了很好的结果,作为固体氧化物燃料电池阳极时出现了结构不稳定的问题

Benefits of technology

[0011]1)本发明采用固相法合成了单相的双钙钛矿氧化物Sr2Ti0.8Ni0.2FeO6-δ,该材料在空气中为纯相的双钙钛矿结构,在还原气氛中可原位脱溶出Ni-Fe合金纳米粒子,且具有良好的烧结性能。

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Abstract

This invention relates to a symmetrical solid oxide fuel cell material and its preparation method. The fuel cell material has a double perovskite structure and the molecular formula Sr₂Ti. 0.8 Ni 0.2 FeO 6‑δ This invention synthesizes single-phase Sr₂Ti using a solid-state method. 0.8 Ni 0.2 FeO 6‑δ This material exhibits a pure-phase double perovskite structure in air, and can in-situ desorb Ni-Fe alloy nanoparticles in a reducing atmosphere. The electrode material of this invention possesses excellent oxygen desorption and hydrogen reduction properties. The Sr₂Ti of this invention... 0.8 Ni 0.2 FeO 6‑δ Materials and Electrolytes La 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 3‑δ It has good chemical compatibility. Based on La 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 3‑δ Electrolyte, Sr2Ti 0.8 Ni 0.2 FeO 6‑δ The symmetrical cell with electrodes exhibited good polarization impedance results in both air and hydrogen atmospheres. 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 3‑δ The electrolyte-supported single cell achieved a maximum output power density of 800 mW / cm² when using hydrogen as fuel. ‑2 When propane is used as fuel, the maximum power density reaches 705 mW / cm³. ‑2 It exhibited good output performance. Research shows that Sr2Ti... 0.8 Ni 0.2 FeO 6‑δ The sample is a promising symmetric solid oxide fuel cell electrode material.
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Citation Information

Patent Citations

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