一种烷基锂改性层状双金属氢氧化物催化剂的制备方法和应用

By modifying layered bimetallic hydroxides (LDHs) with alkyl lithium to control their hydrogen-oxygen ratio and metal ion valence state, an amorphous structure is formed, which solves the problems of precious metal scarcity and insufficient active sites, and realizes a highly efficient and stable OER catalyst suitable for the energy field.

CN116334649BActive Publication Date: 2026-07-17ANHUI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ANHUI UNIV
Filing Date
2023-02-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The scarcity and high cost of precious metals in existing water electrolysis oxygen evolution electrocatalysts limit their large-scale application. Furthermore, the active sites of traditional layered bimetallic hydroxides (LDHs) are not sufficiently exposed, resulting in low OER activity and cumbersome preparation processes, making it difficult to meet practical needs.

Method used

The method of modifying layered bimetallic hydroxide (LDH) with alkyl lithium involves mixing LDH with n-butyllithium solution, centrifuging with n-hexane and ethanol, and freeze-drying to adjust the hydrogen-oxygen ratio and metal ion valence state, thereby forming an amorphous structure and improving OER activity.

Benefits of technology

A highly efficient, stable, and low-cost OER catalyst was prepared, which has better performance than ruthenium oxide catalysts, has a long lifespan, is suitable for the energy field, uses widely distributed raw materials, and has a simple and scalable preparation method.

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Abstract

本发明公开了一种烷基锂改性层状双金属氢氧化物(LDH)催化剂的制备方法及应用:将层状双金属氢氧化物(LDH)溶于烷基锂中加热,2天后用正己烷和乙醇分别离心水洗,冷冻干燥,得到烷基锂改性的层状双金属氢氧化物(LDH)催化剂。本发明制备的催化剂,在电催化析氧中,具有比贵金属催化剂更好的催化性能,更好的稳定性。可以有效调控层状双金属氢氧化物(LDH)的氢氧比和金属离子价态,该催化剂的制备方法使具有晶态的层状双金属氢氧化物(LDH)转变为特殊的非晶结构,同时制备所使用的层状双金属氢氧化物原料价格低廉,分布广泛,制备过程简便,可以广泛应用各种层状双金属氢氧化物(LDH)的电催化处理,具有明显的应用扩展前景。
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