一种苯乙烯-马来酸酐-丙烯腈共聚物及其制备方法

By combining bulk polymerization and suspension polymerization, and using specific dispersion stabilizers to protect maleic anhydride, the problems of low conversion rate and large solvent consumption in the synthesis of styrene-maleic anhydride-acrylonitrile copolymers are solved, achieving efficient and environmentally friendly copolymer preparation.

CN116396420BActive Publication Date: 2026-07-17SHINE POLYMER (ZHUHAI) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHINE POLYMER (ZHUHAI) CO LTD
Filing Date
2021-12-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the synthesis of styrene-maleic anhydride-acrylonitrile copolymer has problems such as low reaction conversion rate, large amount of organic solvent used, complicated post-processing, and easy hydrolysis of maleic anhydride.

Method used

A combination of bulk polymerization and suspension polymerization is employed, using a specific aqueous solution of dispersant stabilizer to protect maleic anhydride from hydrolysis, controlling reaction temperature and time to form stable particles, avoiding mass and heat transfer difficulties caused by high viscosity, and reducing the use of organic solvents.

Benefits of technology

It achieves high-conversion copolymer synthesis, avoids the difficulties in mass and heat transfer and organic solvent treatment caused by high viscosity, protects the acid anhydride groups, and the process is environmentally friendly and economical.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种苯乙烯‑马来酸酐‑丙烯腈共聚物及其制备方法。制备方法包括以下步骤:将引发剂和链转移剂混合,再加入单体马来酸酐、苯乙烯、丙烯腈反应得到本体聚合预聚物;将去离子水和分散稳定剂混合得到分散稳定剂溶液,滴加到本体聚合预聚物中,反应得到共聚物溶液;共聚物溶液过滤干燥得到所述的共聚物。本发明结合了本体聚合和悬浮聚合二者优势,克服了本体聚合后期粘度大传质传热困难以及有机溶剂难以处理的问题,同时保护了马来酸酐中酸酐基团不易水解,反应过程容易控制且不消耗大量有机溶剂经济环保。
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