一种高电压锂离子电池

By using a specific ratio of fluorinated cyclic carbonates, unsaturated hydrocarbon phosphate compounds, boron-containing lithium salt additives, trinitrile compounds, and cyclic carboxylic anhydrides in high-voltage lithium-ion batteries, a stable interfacial film is formed, solving the problems of gas generation and insufficient cycle life at high temperatures, and achieving battery stability and long-term reliability at high voltages.

CN116454381BActive Publication Date: 2026-07-17SHENZHEN CAPCHEM TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN CAPCHEM TECH CO LTD
Filing Date
2023-04-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing high-voltage lithium-ion batteries suffer from gas generation at high temperatures and insufficient cycle life, which severely degrades battery performance and lifespan, especially in electric vehicle applications.

Method used

A non-aqueous electrolyte containing fluorinated cyclic carbonates, phosphate compounds with unsaturated hydrocarbon groups, and boron-containing lithium salt additives is used. Trinitronic compounds and cyclic carboxylic anhydrides are combined as second additives to adjust their proportion and liquid retention coefficient in the non-aqueous electrolyte, forming a dense and stable interfacial film that inhibits the dissolution of the positive electrode active material and the decomposition of the electrolyte.

Benefits of technology

It effectively improves the cycle life of lithium-ion batteries, suppresses gas generation at high temperatures, ensures the stability and performance of batteries at high voltages, and meets the long-term reliability requirements of electric vehicles for batteries.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure BDA0004174978240000021
    Figure BDA0004174978240000021
  • Figure BDA0004174978240000071
    Figure BDA0004174978240000071
  • Figure BDA0004174978240000122
    Figure BDA0004174978240000122
Patent Text Reader

Abstract

为克服现有高电压锂离子电池存在高温产气和循环寿命不足的问题,本发明提供了一种锂离子电池,包括正极、负极和非水电解液,所述非水电解液包括非水有机溶剂、添加剂和锂盐,所述添加剂包括氟代环状碳酸酯、含有不饱和烃基的磷酸酯化合物、含硼锂盐型添加剂和第二添加剂,所述第二添加剂包括三腈化合物和环状羧酸酐中的至少一种;所述高电压锂离子电池满足以下条件:1≤[(p+q)×E] / b≤26,且0.05≤b<1,0.2≤p≤1.5,0.01≤q≤1.5,2.6≤E≤3.3;所述高电压锂离子电池的充电截止电压≥4.6V。本发明提供的锂离子电池通过对于添加剂和保液系数的控制,对于高电压的锂离子电池的循环寿命具有较大的提升作用,同时有效抑制了高电压的锂离子电池在高温下的产气。
Need to check novelty before this filing date? Find Prior Art