含氟聚合物及其制造方法

By controlling the oxygen concentration and temperature in an aqueous medium to polymerize fluoropolymers, the manufacturing challenges of high molecular weight and uniformly coated films have been solved, enabling the production of high molecular weight fluoropolymers and the formation of uniformly coated films.

CN116457377BActive Publication Date: 2026-07-17DAIKIN INDUSTRIES LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
DAIKIN INDUSTRIES LTD
Filing Date
2021-11-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to manufacture high molecular weight fluoropolymers by introducing monomer units with specific structures into fluoropolymers in large quantities, and it is also difficult to form a uniform coating film.

Method used

Polymerization of general formula (I) monomers is carried out in an aqueous medium, with the oxygen concentration in the polymerization reaction system controlled below 500 ppm by volume, preferably at a temperature of 20°C to 59°C, using persulfate as the polymerization initiator, and the polymer is treated by ultrafiltration, microfiltration, dialysis membrane treatment and other methods.

Benefits of technology

It has been achieved that high molecular weight fluoropolymers can be manufactured by introducing a large number of monomer units with specific structures, and a uniform coating film can be formed.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供一种含氟聚合物的制造方法,其为通过在水性介质中进行通式(I)所示的单体(I)的聚合而制造单体(I)的含氟聚合物的方法,其中,将上述聚合的反应体系中的氧浓度维持在500体积ppm以下。通式(I):CX2=CY‑CF2‑O‑Rf‑A(式中,X和Y独立地为H、F、CH3或CF3,X和Y中的至少1个为F。Rf为碳原子数1~40的含氟亚烷基、或碳原子数2~100的具有醚键的含氟亚烷基。A为‑COOM、‑SO3M、‑OSO3M或‑C(CF3)2OM(M为H、金属原子、NR74、具有或不具有取代基的咪唑鎓、具有或不具有取代基的吡啶鎓或者具有或不具有取代基的磷鎓,R7为H或有机基团)。)。
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