一种正极补锂添加剂及其制备方法和应用

By using high-entropy oxide materials to coat lithium-rich oxides in lithium-ion batteries, the problem of gas generation during charging and discharging is solved, improving battery stability and electrode material performance, making it suitable for industrial production of lithium-ion batteries.

CN116487591BActive Publication Date: 2026-07-17SHENZHEN DYNANONIC INNOVAZONE NEW ENERGY TECH CO LTD +2

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN DYNANONIC INNOVAZONE NEW ENERGY TECH CO LTD
Filing Date
2023-02-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing lithium-ion batteries, the low initial coulombic efficiency of the negative electrode material leads to a reduction in the reversible capacity and energy density of the battery, and the gas generated by lithium-rich oxides during charging and discharging affects large-scale industrial production.

Method used

High-entropy oxide materials are mixed or bonded to the surface of lithium-rich oxides to form a coating layer, thereby reducing gas generation during charging and discharging and improving the migration performance of electrons and ions.

Benefits of technology

It effectively reduces gas generation during the charging and discharging of lithium-rich oxides, improves the stability and rate performance of electrode materials, enhances corrosion resistance, and is suitable for industrial production.

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Abstract

本申请提出一种正极补锂添加剂及其制备方法和应用,其中正极补锂添加剂,包括:富锂氧化物和高熵氧化物,所述高熵氧化物以以下三种方式中的任意一种存在于所述正极补锂添加剂中:(1)所述高熵氧化物全部掺混于所述富锂氧化物中;(2)所述高熵氧化物全部结合于所述富锂氧化物的外表层;(3)所述高熵氧化物部分掺混于所述富锂氧化物中,部分结合于所述富锂氧化物的外表层。本申请所述正极补锂添加剂,采用高熵氧化物材料掺混和 / 或结合于富锂氧化物表面,可以减少富锂氧化物充电时产生的气体,有利于电极材料电子和离子的迁移,提高倍率性能、稳定性和抗腐蚀性。
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