补锂材料及其制备方法、正极极片和二次电池

By using lithium-rich compound core doping catalytic grains in lithium-ion batteries to form more grain boundaries and reduce decomposition voltage, the problem of irreversible capacity loss during the first charge and discharge of lithium-ion batteries is solved, thus improving the electrochemical performance and stability of the batteries.

CN116504933BActive Publication Date: 2026-07-17SHENZHEN DYNANONIC INNOVAZONE NEW ENERGY TECH CO LTD +2

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN DYNANONIC INNOVAZONE NEW ENERGY TECH CO LTD
Filing Date
2023-02-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

During the first charge and discharge cycle, existing lithium-ion batteries consume lithium ions due to the formation of a solid electrolyte interface film, resulting in irreversible capacity loss and reduced energy density. At the same time, commonly used lithium replenishment materials have high decomposition voltages and release oxygen, affecting battery stability and safety.

Method used

Using lithium-rich compounds as the core, and doping with catalytic grains such as LiI, LiF, LiCl, and LiBr, more grain boundaries are formed, reducing the lithium-ion decomposition voltage. The coating layer isolates redox reactions, thereby improving the lithium-ion transfer rate and battery stability.

Benefits of technology

It improves the electrochemical performance of lithium batteries, especially their specific capacity, reduces oxygen release, avoids irreversible structural changes, and enhances the structural stability and cycle stability of the batteries.

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Abstract

一种补锂材料及其制备方法、正极极片和二次电池,补锂材料包括内核和催化晶粒,内核由富锂化合物组成;至少部分催化晶粒与内核结合接触。催化晶粒能够提高富锂化合物的晶界数量,利于提高富锂化合物的锂离子传递速率,并且催化晶粒还能够催化富锂化合物在较低电位下分解产生锂离子,降低了补锂材料中锂离子的分解电压;同时,较低的分解电压,能够减少内核中氧气的释放,可以避免高活性原子氧与电解液发生氧化还原反应而产生CO、CO2等气体。
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