一种十字形银纳米颗粒及其制备方法与应用

Cross-shaped silver nanoparticles with exposed (100) crystal planes were prepared by electrodeposition at room temperature and pressure, which solved the problems of complex electroplating solutions, environmental pollution and high energy consumption in the prior art. This method realizes the preparation of low-energy, green and environmentally friendly silver nanoparticles, which can be used to catalyze the oxidation of ethylene and promote the production of ethylene glycol.

CN116555807BActive Publication Date: 2026-07-17INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES
Filing Date
2022-01-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing silver nanoparticles suffer from problems such as complex electroplating solution composition, environmental pollution, high energy consumption, and inability to control the crystal form of the product.

Method used

Cross-shaped silver nanoparticles were prepared by electrodeposition at room temperature and pressure using a simple silver salt and electrolyte solution, without the need for surfactants and stabilizers. The cross-shaped silver nanoparticles with exposed (100) crystal planes were prepared by using a rotating disk electrode and controlling the applied potential.

Benefits of technology

A green, environmentally friendly, and low-energy-consumption silver nanoparticle preparation method has been achieved, which is suitable for catalyzing the oxidation of ethylene and promoting the direct generation of ethylene glycol.

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Abstract

本发明提供了一种十字形银纳米颗粒及其制备方法与应用,所述制备方法包括:以旋转的工作电极作为阴极,以惰性电极为阳极,在银电镀液中通过电沉积得到十字形银纳米颗粒;所述银电镀液包括银盐、电解质与水。本发明在常温常压下通过电沉积制备银纳米颗粒,电镀液成分简单、制备过程无有机大分子添加、绿色环保且能耗低,所制备的银纳米颗粒为暴露(100)晶面的十字形结构,在催化领域,具有(100)晶面的银颗粒用于电催化乙烯氧化,有利于乙二醇直接生成。
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