金属掺杂硫化铟催化剂及其制备方法与应用

By preparing metal-doped indium sulfide catalysts, the problems of low selectivity and catalyst instability in the electrocatalytic coupling reaction of aldehydes were solved, achieving highly efficient reductive coupling of aldehydes with a Faraday efficiency of over 90%, significantly improving the performance and selectivity of the catalyst.

CN116555824BActive Publication Date: 2026-07-17BEIJING UNIV OF CHEM TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING UNIV OF CHEM TECH
Filing Date
2023-03-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing catalysts exhibit low selectivity and require stringent conditions in the electrocatalytic coupling reaction of aldehydes. Indium sulfide is unstable and difficult to maintain its activity under electrocatalytic conditions.

Method used

A metal-doped indium sulfide catalyst was prepared on a conductive substrate via a hydrothermal reaction. This catalyst is used for the electrocatalytic reduction coupling of aldehydes, inhibiting the hydrogen evolution reaction and improving the stability and selectivity of the catalyst.

Benefits of technology

This study achieved highly efficient electrocatalytic reduction coupling of aldehydes, with a Faraday efficiency of over 90%, significantly improving the performance and selectivity of the catalyst and inhibiting the formation of alcohol products.

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Abstract

本发明公开了一种金属掺杂硫化铟催化剂及其制备方法与应用,通过将常用于光催化剂中的硫化铟通过水热法掺杂金属元素进行改性,得到在电催化条件下性能稳定的金属掺杂硫化铟,并在电催化条件下将该催化剂应用于高效催化醛类化合物还原制备偶联产物。本发明将具有高选择性的金属掺杂硫化铟催化剂运用到电催化条件中,使还原偶联反应在高选择性的基础上,同时具有极高的法拉第效率,以获得更多的醛类化合物偶联产物。
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