一种NiMo复合电催化剂及其制备方法与应用

An array-structured NiMo composite electrocatalyst was prepared by hydrothermal synthesis, which solved the problem of low catalytic activity of existing electrocatalysts and achieved the effect of highly efficient electrocatalytic degradation of hexavalent chromium.

CN116586074BActive Publication Date: 2026-07-17ZHEJIANG TIANKUN ECOLOGICAL ENVIRONMENT TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHEJIANG TIANKUN ECOLOGICAL ENVIRONMENT TECH CO LTD
Filing Date
2023-05-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing electrocatalysts exhibit low catalytic activity in the degradation of hexavalent chromium, with low surface adsorption rates and difficulty in recovery. Supported electrocatalytic reaction systems also show low catalytic activity.

Method used

NiMo composite electrocatalysts with an array network structure were prepared by hydrothermal synthesis. The nano-NiMo particles were uniformly distributed on the surface of nickel foam. The reaction temperature was controlled at 120~150℃ and the reaction time was controlled at 7~10h to form a high specific surface area and stable catalytic active center.

Benefits of technology

It improves the electrocatalytic ability of the catalyst, enhances the transport efficiency and stability of hexavalent chromium ions, avoids particle aggregation and stacking, and extends the service life of the catalyst.

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Abstract

本发明涉及催化材料技术领域,公开了一种NiMo复合电催化剂及其制备方法与应用。本发明提供制备方法通过将含Ni2+的溶液与含Mo6+的溶液混合,插入泡沫镍在120~150℃下进行水热反应7~10h,可得到高比表面积和纳米NiMo颗粒均匀分布在泡沫镍表面的具阵列网状结构的NiMo复合电催化剂,将之应用于降解六价铬离子中具有优异的催化活性,两小时的催化降解率可达90%。
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