一种多污染物协同去除的三效催化剂制备方法及应用

By introducing multiple transition metals or rare earth metals onto molecular sieves, combined with acid treatment and impregnation methods, the problem of synergistic removal of N2O, NH3, and CO in ammonia-coal co-fired boilers was solved, achieving a highly efficient purification effect for multiple pollutants.

CN116618085BActive Publication Date: 2026-07-17SHANDONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG UNIV
Filing Date
2023-07-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for the efficient and synergistic removal of N2O, NH3 and CO in ammonia-coal co-fired boilers. Traditional catalysts have insufficient activity at low temperatures and are costly, while molecular sieves have insufficient redox capacity and cannot meet stringent environmental emission requirements.

Method used

A combination of acid treatment and ion exchange impregnation is used to introduce various transition metals or rare earth metals into molecular sieves to form a multi-active-site catalyst. Metal nanoparticles are uniformly distributed in the molecular sieve channels through ion exchange and impregnation, thereby enhancing the redox capacity and acidity and achieving the synergistic removal of multiple pollutants.

Benefits of technology

The decomposition of N2O, oxidation of NH3, and oxidation of CO were achieved in the same process, which improved the reaction activity and selectivity of the catalyst, significantly reduced competitive adsorption, and realized the deep synergistic treatment of multiple pollutants.

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Abstract

本发明属于氨煤混燃锅炉烟气气体污染物脱除与催化剂材料领域,涉及一种多污染物协同去除的三效催化剂制备方法及应用,包括:将分子筛进行酸性处理,脱除非骨架铝,之后将其浸入金属前驱体中,利用离子交换法,获得改性分子筛。再利用浸渍法结合粘合剂将金属纳米颗粒均匀分散在分子筛孔道内。本发明结合离子交换和浸渍法特点,基于分子筛限域效应,实现多金属活性位点同时出现在分子筛孔道,保证分子筛酸性的同时提升氧化还原能力。同时多类型活性中心,可保证N2O、NH3、CO等反应物分子可定向吸附活化,竞争吸附效果削弱。实现N2O分解、NH3‑CO氧化、NH3 / CO选择性催化还原N2O等多种反应路径协同进行,展现出良好的反应活性与无害化产物选择性。
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