高含氮碳骨架材料制备方法及其在钠金属电池阳极保护中的应用

The high-nitrogen-content carbon framework material prepared by freeze-drying and secondary carbonization processes solves the problems of uneven deposition and dendrite growth in sodium metal anodes, achieving high energy density and safety in sodium metal batteries, and is suitable for anode protection in sodium metal batteries.

CN116639677BActive Publication Date: 2026-07-17HUAZHONG UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUAZHONG UNIV OF SCI & TECH
Filing Date
2023-05-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sodium metal anode materials suffer from problems such as uneven sodium ion deposition, sodium dendrite growth, and short circuits and thermal runaway caused by the reaction of metallic sodium with organic electrolytes during battery operation, making it difficult to meet the requirements for high energy density and safety.

Method used

A method for preparing high-nitrogen-content carbon framework materials was adopted, which involves freeze-drying and secondary carbonization processes to form a high-nitrogen-content carbon framework material with rich microstructure and self-support. This material is used for anode protection of sodium metal batteries and is combined with conductive agents and binders to form a composite electrode.

Benefits of technology

It achieves uniform deposition of sodium metal, avoids the formation of sodium dendrites, improves coulombic efficiency and cycle life, and has good conductivity and stability, making it suitable for large-scale industrial production.

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Abstract

本发明涉及高含氮碳骨架材料的制备方法,对高含氮有机前驱体依次经过冻干以及二次碳化,得到高含氮碳骨架材料。一种高含氮碳骨架材料在钠金属电池中的应用。本发明的有益效果为:利用冰模板法设计高含氮碳骨架材料,具有比表面积和自支撑空间增大的效果,其丰富而疏松的微结构以及亲钠位点,有利于金属钠的均匀沉积,避免钠枝晶的形成和钠负极的体积效应;再采用两步热解碳化法,使其完整保留冰模板法中所形成的特征微观形貌,高含氮碳骨架与磷酸钒钠组装的钠金属全电池,在2.2~3.8V电压区间内,在1C较大电流密度下可逆充放电比容量高达109mAh / g,以此电流密度循环150圈后容量保持率高达96.3%。
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