由ZIF-67衍生的二硫化钴与钯纳米颗粒析氢催化剂

By loading nano-Pd particles onto the surface of CoS2 to form a core-shell structure ZIF-67 derived catalyst, the problems of high cost of palladium-based catalysts and easy aggregation of CoS2 are solved, realizing efficient and low-cost water electrolysis for hydrogen production, which is suitable for large-scale industrial applications.

CN116641095BActive Publication Date: 2026-07-17FUZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
FUZHOU UNIV
Filing Date
2023-06-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing palladium-based catalysts are expensive, scarce, and have poor durability. Transition metal sulfides such as CoS2 are prone to aggregation and are unstable, affecting the efficiency and sustainability of hydrogen production through water electrolysis.

Method used

The Pd@CoS2 nanocatalyst derived from ZIF-67 was used. By loading nano-Pd particles onto the surface of CoS2 to form a core-shell structure, the catalytic activity and stability were improved by utilizing the porous framework structure of ZIF-67 and the electronic modification effect of Pd.

Benefits of technology

The Pd@CoS2 catalyst achieves efficient and low-cost hydrogen production through water electrolysis. It exhibits excellent hydrogen evolution performance and stability in acidic solutions, making it suitable for large-scale industrial applications.

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Abstract

本发明公开了一种由ZIF‑67衍生的Pd@CoS2析氢催化剂及其制备方法,属于电解水产氢制备技术领域。其是先将硝酸钴与2‑甲基咪唑混合反应制得ZIF‑67;然后将所得ZIF‑67与过量硫粉在惰性气氛保护下进行煅烧,得到ZIF纳米框架衍生的CoS2;再以乙二醇为还原剂,将所得CoS2与乙二醇、甲醇搅拌混合后加入氯钯酸钠浸渍,再调pH后,采用溶剂热法还原氯钯酸钠,制备出所述Pd@CoS2析氢催化剂。本发明制备过程简单,制得的Pd@CoS2析氢催化剂直径为450‑600纳米,其中Pd和CoS2可发生电子转移,产生协同增强效应,因此将其应用于电解水产氢可表现出较低的水分解能垒、较高催化活性及良好的稳定性。
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