一种硒化物基超结构纳米阵列材料及其制备方法和应用

By selenizing Co-MOF rod array materials and forming Ni3Se4 and Ni(OH)2 coating layers, a hollow, layered core-shell superstructure selenide-based nanoarray material was prepared, which solved the problems of small specific surface area and poor cycle stability of existing selenide-based electrode materials, and realized the preparation of high-performance alkaline zinc-ion battery electrode materials.

CN116646498BActive Publication Date: 2026-07-17NINGBO INST OF NORTHWESTERN POLYTECHNICAL UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NINGBO INST OF NORTHWESTERN POLYTECHNICAL UNIV
Filing Date
2023-06-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing selenide-based electrode materials suffer from problems such as small specific surface area, low actual specific capacity, poor rate performance and cycle stability, and complex preparation process, which is not conducive to large-scale application.

Method used

Using Co-MOF rod array material as a precursor, hollow CoSe2 material is formed through selenization treatment, and Ni3Se4 and Ni(OH)2 coating layers are formed in solvothermal reaction to prepare selenide-based superstructured nanoarray material with hollow and layered core-shell superstructure.

Benefits of technology

This improves the specific surface area and electrochemical activity of the material, providing excellent electrochemical performance. It can be directly used as the working electrode of alkaline zinc-ion batteries in large-scale preparation, thereby enhancing the energy density and stability of the battery.

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Abstract

本发明属于碱性锌离子电池电极材料技术领域,公开一种硒化物基超结构纳米阵列材料及其制备方法和应用,所述制备方法为:以Co‑MOF棒状阵列材料为前驱体,硒化后,获得具有中空结构的CoSe2材料;将对苯二甲酸与镍盐分散于有机溶剂中,随后加入乙醇水溶液,搅拌处理,获得混合溶液;将CoSe2材料浸于混合溶液中浸渍8~12h,随后进行溶剂热反应,洗涤、干燥后即获得所述硒化物基超结构纳米阵列材料。本发明以Co‑MOF为前驱体,将其硒化后,包覆Ni3Se4@Ni(OH)2,获得硒化物基超结构阵列材料;且制备方法简单、原料易得、操作简单、拥有独特的结构优势,同时制备的材料具备良好的电化学性能。
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