A method for preventing swelling of a polymer electrolyte membrane electrode
CN116646537BActive Publication Date: 2026-08-28DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Patent Information
- Application Number
- CN202310643499.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-06-01
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2043-06-01
AI Technical Summary
Technical Problem
然而传统的膜电极结构仍然不能满足电化学反应器的成本和安全的需求:一是膜电极空白聚合物边缘极易折皱,影响电化学反应器的密封性能;二是由于聚合物电解质膜与传统边框材料的弹性模量、硬度不匹配,电解质膜在水的作用下具有溶胀和收缩的反复应力,边框材料容易使聚合物电解质膜开裂破损,影响电化学反应器的可靠性和安全性;三是边框材料需要搭配胶层粘结使用,常见的燃料电池使用的胶黏剂易水解失效,导致密封边框与质子膜分离
Benefits of technology
[0019](1)本发明利用聚合物电解质膜本身树脂具有流动性的特点,采用微孔膜作为边框材料,当电解质膜与微孔薄膜热压合时,树脂会流动进入微孔薄膜的孔隙内,结合牢固,不会水解,解决了现有技术中,边框与胶层粘结时,长时间运行胶层发生水解造成的剥离、开胶等问题。
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Abstract
The present application belongs to the technical field of fuel cell, and particularly relates to a kind of anti-swelling sealing edge method of polymer electrolyte membrane electrode. The edge of membrane electrode is cut, and two layers of microporous film are used to cover the upper and lower sides of the non-reaction area of membrane electrode respectively; a mold is used to position the membrane electrode, to ensure that the catalytic layer is located at the inner center position of the microporous film closed area, the first layer of microporous film is fixed on the blank edge of polymer electrolyte membrane on one side of the membrane electrode, and then the second layer of microporous film is fixed on the blank edge of polymer electrolyte membrane on the other side of the membrane electrode, and the two layers of microporous film are overlapped symmetrically; finally, the assembly is implanted into two layers of metal sheets, and hot pressing is performed. The microporous film has strong bonding force with the polymer film, good sealing property, simple production process and low cost.
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Citation Information
Patent Citations
Membrane electrode assembly, preparation method, and fuel monocell
CN110444790A
Membrane electrode sealing structure, fuel cell and CCM structure
CN217788457U