生物基热塑性聚醚酯弹性体及其制备方法和应用

By combining specific molecular structures and using specific preparation methods, the problems of low transparency, poor mechanical properties, and poor heat resistance of bio-based thermoplastic polyether ester elastomers have been solved, resulting in the preparation of bio-based thermoplastic polyether ester elastomers with high transparency, excellent mechanical properties, and heat resistance.

CN116655900BActive Publication Date: 2026-07-17NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI
Filing Date
2023-05-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional bio-based thermoplastic polyether ester elastomers suffer from problems such as low transparency, poor mechanical properties, and poor heat resistance.

Method used

Bio-based thermoplastic polyether ester elastomers are prepared by the interaction of specific molecular structures, including esterification or transesterification reactions under a protective atmosphere, followed by polycondensation reactions under vacuum conditions, forming microphase separation of crystalline and amorphous regions, thereby improving transparency, mechanical properties and heat resistance.

Benefits of technology

The prepared bio-based thermoplastic polyether ester elastomer has excellent transparency, mechanical properties and heat resistance. Its melting point reaches above 130℃, transmittance reaches above 80%, initial deformation recovery rate reaches above 58%, tensile modulus reaches above 35MPa, and elongation at break reaches above 500%.

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Abstract

本发明涉及一种生物基热塑性聚醚酯弹性体及其制备方法和应用。所述生物基热塑性聚醚酯弹性体的结构式如式(1)所示,其中,R选自分子量为250g / mol‑3000g / mol的聚醚二元醇的结构单元,x、y、m均为整数,x=1‑12,y=1‑10,m=2‑60。本发明提供的生物基热塑性聚醚酯弹性体透明度高,且力学性能和耐热性能优异。
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