一种易面型Sm2(Fe1-xMnx)14B合金粉末及其制备方法和应用

The preparation of easily shaped Sm2(Fe1-xMnx)14B alloy powder by reduction diffusion method solves the problem of limited temperature range of magnetic refrigeration materials, achieves wide-temperature cooling effect and high-efficiency refrigeration, and has advantages in industrial production.

CN116673483BActive Publication Date: 2026-07-17LANZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LANZHOU UNIV
Filing Date
2023-06-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing magnetic refrigeration materials have limited application range in temperature, exhibiting large magnetic entropy only near a fixed phase transition temperature, and the preparation process and application of the easy-faceted Sm2(Fe1-xMnx)14B compound have not been reported.

Method used

Easy-faceted Sm2(Fe1-xMnx)14B alloy powder was prepared by reduction diffusion method. The Mn doping amount was controlled to regulate the Curie temperature through mixing, pressing, high-temperature reduction and high-temperature alloying steps, so as to achieve a cooling effect over a wide temperature range.

Benefits of technology

The prepared Sm2(Fe1-xMnx)14B alloy powder has a cooling effect in the range of 339℃ to -40℃, providing an energy efficiency improvement of about 30% in room temperature cooling compared with traditional materials. It is also environmentally friendly, low in cost, and suitable for mass production.

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Abstract

本发明提供一种易面型Sm2(Fe1‑xMnx)14B合金粉末及其制备方法和应用,涉及磁性材料领域。先将各原料混匀后压饼,再将料饼进行高温还原,使Sm2O3被还原为单质Sm,使MnO2、Mn2O3被还原为单质Mn,然后对高温还原后的料饼继续升温进行高温合金化,使单质Sm与Fe、FeB和Mn充分扩散成相,多余的Sm在高温处理过程中挥发掉,最后将高温合金化后的料饼依次破碎、脱钙和烘干,得到Sm2(Fe1‑xMnx)14B合金粉末,x=0~0.3。该方法制备的材料与具有珀耳帖效应的传统技术相比更加节能,环保且生产成本低,生产周期短,产物尺寸易于控制、可调,有望用作磁制冷材料。
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